Products Categories
Basic Information
| CAS No.: | 623-47-2 |
|---|---|
| Name: | Ethyl propiolate |
| Molecular Structure: | |
|
|
|
| Formula: | C5H6O2 |
| Molecular Weight: | 98.1014 |
| Synonyms: | Propiolicacid, ethyl ester (6CI,7CI,8CI);(Ethoxycarbonyl)acetylene;Carboethoxyacetylene;Ethyl 2-propynoate;Ethyl acetylenecarboxylate;Ethylacetylenemonocarboxylate;Ethyl propargylate;Ethylpropynoate;NSC 60551;Propynoic acid ethyl ester; |
| EINECS: | 210-795-8 |
| Density: | 0.998 g/cm3 |
| Melting Point: | 9 °C |
| Boiling Point: | 119.999 °C at 760 mmHg |
| Flash Point: | 23.333 °C |
| Solubility: | miscible with water |
| Appearance: | clear colorless to pale yellow liquid |
| Hazard Symbols: |
 Xi, F
|
| Risk Codes: | 10-36/37/38-36-11 |
| Safety: | 26-36-37/39-16-33-29-24-23 |
| Transport Information: | UN 3272 3/PG 3 |
| PSA: | 26.30000 |
| LogP: | 0.18270 |
Related products
- 81281-59-67-Benzylideneaminotheophylline
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
- 717878-06-31-(4-fluorophenyl)-4-nitro-1H-imidazole
- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With sulfuric acid; trimethyl orthoformate In dichloromethane at 40℃; for 24h; Reagent/catalyst; | 86.7% |
| boron trifluoride diethyl etherate 1.) reflux, 1.5 h; 2.) rt., 4 h.; | 60% |
| With sulfuric acid for 24h; Reflux; | 36% |
- 38391-86-5
Ethyl half ester of acetylenedicarboxylic acid
- 108-88-3
toluene
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| at 100℃; Zeitlicher Verlauf der thermischen Zersetzung; |
- 119930-16-4
(E)-4-(Triphenyl-λ5-phosphanylidene)-pent-2-enedioic acid diethyl ester
A
- 1099-45-2
ethyl (triphenylphosphoranylidene)acetate
B
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| equil. react.; |
- 38391-86-5
Ethyl half ester of acetylenedicarboxylic acid
- 7732-18-5
water
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| at 100℃; Zeitlicher Verlauf der thermischen Zersetzung; |
- 527-60-6
Mesitol
- 541-41-3
chloroformic acid ethyl ester
- 471-25-0
Propiolic acid
A
- 1737-55-9
Trifluoressigsaeure-(2,4,6-trimethyl-phenylester)
B
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: Propiolic acid With lithium hydride In tetrahydrofuran at 20℃; for 18h; Metallation; Stage #2: chloroformic acid ethyl ester In tetrahydrofuran at -10 - 20℃; Acylation; Stage #3: Mesitol In tetrahydrofuran at 20 - 45℃; Substitution; |
...Expand
- 541-41-3
chloroformic acid ethyl ester
- 51114-00-2
sodium 2,4,6-trimethylphenoxide
- 471-25-0
Propiolic acid
A
- 1737-55-9
Trifluoressigsaeure-(2,4,6-trimethyl-phenylester)
D
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: Propiolic acid With lithium hydride In tetrahydrofuran at 20℃; for 18h; Metallation; Stage #2: chloroformic acid ethyl ester In tetrahydrofuran at -10 - 20℃; Acylation; Stage #3: sodium 2,4,6-trimethylphenoxide In tetrahydrofuran at 20 - 45℃; Substitution; |
...Expand
- 764-01-2
methyl propargyl alcohol
- 1972-28-7
diethylazodicarboxylate
- 108-95-2
phenol
A
- 13610-09-8
but-2-ynyloxybenzene
B
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| With triphenylphosphine In tetrahydrofuran; benzene | A 2.18 g (70%) B n/a |
...Expand
- 107-19-7
propargyl alcohol
- 1972-28-7
diethylazodicarboxylate
- 287108-60-5
5-bromo-2-[(4-hydroxy-benzenesulfonyl)-methyl-amino]-3-methyl-benzoic acid methyl ester
A
- 623-47-2
propynoic acid ethyl ester
B
- 287108-61-6
5-bromo-3-methyl-2-[methyl-(4-prop-2-ynyloxy-benzenesulfonyl)-amino]-benzoic acid methyl ester
Conditions
| Conditions | Yield |
|---|---|
| With triphenylphosphine In tetrahydrofuran; benzene | A n/a B 0.389 g (71%) |
...Expand
- 461695-81-8
(hydrotris(3,5-diisopropylpyrazolyl)borato)CoCCC(O)OCH2CH3
- 7732-18-5
water
B
- 623-47-2
propynoic acid ethyl ester
Conditions
| Conditions | Yield |
|---|---|
| In not given |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: acetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere; Stage #2: chloroformic acid ethyl ester In tetrahydrofuran; hexane at -78℃; for 8h; Inert atmosphere; | |
| Stage #1: acetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; Stage #2: chloroformic acid ethyl ester In tetrahydrofuran; hexane at -78 - 20℃; for 1.5h; Inert atmosphere; |
Downstream Products
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 623-47-2
Ethyl propiolate
Chemistry
The Molecular formula of Ethyl propiolate(623-47-2): C5H6O2
The Molecular Weight of Ethyl propiolate(623-47-2): 98.1
Molecular Structure :
EINECS: 210-795-8
Boiling Point: 120 °C at 760 mmHg
Flash Point: 23.3 °C
Water Solubility miscible
Index of Refraction: 1.418
Molar Refractivity: 24.81 cm3
Molar Volume: 98.3 cm3
Polarizability: 9.83 10-24 cm3
Surface Tension: 32.5 dyne/cm
Density: 0.997 g/cm3
Enthalpy of Vaporization: 35.81 kJ/mol
Vapour Pressure: 15.5 mmHg at 25°C
storage temp.: 2-8°C
IUPAC Name: ethyl prop-2-ynoate
Synonyms: ACETYLENECARBOXYLIC ACID ETHYL ESTER;ETHYL PROPIOLATE;2-Propynoic acid, ethyl ester;Ethyl 2-propynoate;Ethyl propynoate;ETHYL ACETYLENECARBOXYLATE;EPL;(Ethoxycarbonyl)acetylene;
The Molecular Weight of Ethyl propiolate(623-47-2): 98.1
Molecular Structure :
EINECS: 210-795-8
Boiling Point: 120 °C at 760 mmHg
Flash Point: 23.3 °C
Water Solubility miscible
Index of Refraction: 1.418
Molar Refractivity: 24.81 cm3
Molar Volume: 98.3 cm3
Polarizability: 9.83 10-24 cm3
Surface Tension: 32.5 dyne/cm
Density: 0.997 g/cm3
Enthalpy of Vaporization: 35.81 kJ/mol
Vapour Pressure: 15.5 mmHg at 25°C
storage temp.: 2-8°C
IUPAC Name: ethyl prop-2-ynoate
Synonyms: ACETYLENECARBOXYLIC ACID ETHYL ESTER;ETHYL PROPIOLATE;2-Propynoic acid, ethyl ester;Ethyl 2-propynoate;Ethyl propynoate;ETHYL ACETYLENECARBOXYLATE;EPL;(Ethoxycarbonyl)acetylene;
Uses
Ethyl propiolate(623-47-2) is a kind of reagents for Organic Synthesis.
Safety Profile
The Hazard Codes of Ethyl propiolate(623-47-2): 
Xi, 
F
Hazard Note: Irritant
HazardClass: 3
The Risk Statements information of Ethyl propiolate(623-47-2):
10: Flammable
11: Highly Flammable
36: Irritating to the eyes
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of Ethyl propiolate(623-47-2):
16: Keep away from sources of ignition - No smoking
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24: Avoid contact with skin
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37/39: Wear suitable gloves and eye/face protection
RIDADR: UN 3272 3/PG 3
WGK Germany: 3
PackingGroup: II
Xi, F Hazard Note: Irritant
HazardClass: 3
The Risk Statements information of Ethyl propiolate(623-47-2):
10: Flammable
11: Highly Flammable
36: Irritating to the eyes
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements information of Ethyl propiolate(623-47-2):
16: Keep away from sources of ignition - No smoking
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24: Avoid contact with skin
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37/39: Wear suitable gloves and eye/face protection
RIDADR: UN 3272 3/PG 3
WGK Germany: 3
PackingGroup: II