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| CAS No.: | 65946-56-7 |
|---|---|
| Name: | Trimethylsilylketene Ethyl Trimethylsilyl Acetal (mixture of isomers) |
| Article Data: | 4 |
| Molecular Structure: | |
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| Formula: | C10H24O2Si2 |
| Molecular Weight: | 232.47 |
| Synonyms: | 1-Ethoxy-1-trimethylsiloxy-2-(trimethylsilyl)ethen;1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene;ethyl C,O-bis(trimethylsilyl)ketene acetal;O-ethyl-C,O-bis(trimethylsilyl)ketene acetal;Trimethylsilylketene Ethyl Trimethylsilyl Acetal;Silane,[[1-ethoxy-2-(trimethylsilyl)ethenyl]oxy]trimethyl; |
| Density: | 0.857g/cm3 |
| Boiling Point: | 194.679oC at 760 mmHg |
| Flash Point: | 61.373oC |
| PSA: | 18.46000 |
| LogP: | 3.59320 |
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- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
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- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
- 4071-88-9
trimethylsilanyl-acetic acid ethyl ester
- 18162-48-6
tert-butyldimethylsilyl chloride
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
| Conditions | Yield |
|---|---|
| Stage #1: trimethylsilanyl-acetic acid ethyl ester With lithium diisopropyl amide In tetrahydrofuran at -78℃; Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran at -78℃; Further stages.; | 93% |
- 75-77-4
chloro-trimethyl-silane
- 4071-88-9
trimethylsilanyl-acetic acid ethyl ester
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
| Conditions | Yield |
|---|---|
| With lithium diisopropyl amide 1.) -78 deg C, 3 h; 2.) RT, 1.5 h; | 85% |
| With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; | 60% |
- 27607-77-8
trimethylsilyl trifluoromethanesulfonate
- 141-78-6
ethyl acetate
A
- 4071-88-9
trimethylsilanyl-acetic acid ethyl ester
B
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
C
- 65946-55-6
2,2-Bis(trimethylsilyl)ethansaeure-ethylester
| Conditions | Yield |
|---|---|
| With triethylamine In diethyl ether for 2h; Ambient temperature; Yields of byproduct given; | A 44% B n/a C n/a |
| With triethylamine In diethyl ether for 1h; Ambient temperature; Yield given. Yields of byproduct given; |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 123-11-5
4-methoxy-benzaldehyde
- 24393-56-4
ethyl (E)-3-(4-methoxyphenyl)prop-2-enoate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 100% |
| With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; Peterson Olefination; stereoselective reaction; | 82% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 89-98-5
2-chloro-benzaldehyde
- 24393-51-9
(E)-ethyl 2-chlorocinnamate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 98% |
| With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; Peterson Olefination; stereoselective reaction; | 91% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 104-88-1
4-chlorobenzaldehyde
- 24393-52-0
ethyl (E)-3-(4-chlorophenyl)prop-2-enoate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 96% |
| With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; for 8h; Solvent; Reagent/catalyst; Peterson Olefination; stereoselective reaction; | 85% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 587-04-2
3-Chlorobenzaldehyde
- 2373-88-8, 118315-76-7, 62174-98-5
ethyl (E)-3-(3-chlorophenyl)prop-2-enoate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 94% |
| With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; Peterson Olefination; stereoselective reaction; | 88% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 1571-08-0
methyl 4-formylbenzoate
- 81069-42-3
methyl 4-[(1E)-3-ethoxy-3-oxoprop-1-en-1-yl]benzoate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 94% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 66-99-9
β-naphthaldehyde
- 114833-06-6
ethyl (E)-3-(naphthalene-2-yl)acrylate
| Conditions | Yield |
|---|---|
| With 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene In acetonitrile at 0 - 20℃; Peterson Olefination; stereoselective reaction; | 93% |
- 65946-56-7
1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene
- 100-10-7
4-dimethylamino-benzaldehyde
- 1552-97-2, 39806-13-8
ethyl (E)-3-(4-(dimethylamino)phenyl)acrylate
| Conditions | Yield |
|---|---|
| With tetrabutylammonium acetate In dichloromethane at 0℃; for 1h; | 92% |
- Total:18 Page 1 of 1 1
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