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676-75-5

Basic Information
CAS No.: 676-75-5
Name: DIMETHYLARSENIC IODIDE
Article Data: 32
Molecular Structure:
Molecular Structure of 676-75-5 (DIMETHYLARSENIC IODIDE)
Formula: C2H6 As I
Molecular Weight: 231.896
Synonyms: Arsine,iododimethyl- (6CI,7CI,8CI); Dimethylarsine iodide; Dimethylarsinous iodide;Dimethyliodoarsine; Iododimethylarsine
EINECS: 211-630-2
Boiling Point: 133.4 °C at 760 mmHg
Flash Point: 45.1 °C
PSA: 0.00000
LogP: 1.67250
Synthetic route
75-60-5

Dimethylarsinic acid

676-75-5

dimethyliodoarsine

Conditions
ConditionsYield
With sulfuric acid; sulfur dioxide; potassium iodide In water for 3h;76%
With sulfuric acid; sulfur dioxide; potassium iodide
With hydrogenchloride; sulfur dioxide; potassium iodide
Multistep reaction;
With sulfuric acid; sulfur dioxide; potassium iodide In water
124-65-2

sodium cacodylate

676-75-5

dimethyliodoarsine

Conditions
ConditionsYield
With hydrogenchloride; sulfur dioxide; potassium iodide In water for 2h;54%
101-02-0

triphenyl phosphite

dimethylarsinosulfenyl iodide

A

676-75-5

dimethyliodoarsine

B

597-82-0

O,O,O-triphenyl phosphorothioate

Conditions
ConditionsYield
In chloroform-d1 for 6h;A 22%
B n/a
593-57-7

dimethylarsine

507-02-8

acetyl iodide

A

676-75-5

dimethyliodoarsine

B

75-07-0

acetaldehyde

557-89-1

Dimethylchloroarsine

676-75-5

dimethyliodoarsine

Conditions
ConditionsYield
With ethanol; potassium iodide unter Luftausschluss;
With acetone; sodium iodide unter Luftausschluss;
503-80-0

bis-{dimethylarsenic}-oxide

676-75-5

dimethyliodoarsine

Conditions
ConditionsYield
With hydrogen iodide bei der Destillation;
5814-21-1

tetramethyl-arsonium; triiodide

A

676-75-5

dimethyliodoarsine

B

74-88-4

methyl iodide

Conditions
ConditionsYield
Zersetzt sich beim Erhitzen;
471-35-2

tetramethyldiarsine

74-88-4

methyl iodide

676-75-5

dimethyliodoarsine

471-35-2

tetramethyldiarsine

74-88-4

methyl iodide

A

676-75-5

dimethyliodoarsine

B

5814-20-0

tetramethylarsonium iodide

Conditions
ConditionsYield
analog reagiert Aethyljodid;
74-88-4

methyl iodide

7207-97-8

methyldiiodoarsine

676-75-5

dimethyliodoarsine

Conditions
ConditionsYield
With sodium hydroxide; ethanol und reduziert das Reaktionsprodukt in salzsaurer Loesung mit Schwefeldioxyd;
With sodium hydroxide anschliessend mit wss.HCl und SO2;
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Chemistry

IUPAC Name: Iodo(dimethyl)arsane
Synonyms of Iododimethylarsine (CAS NO.676-75-5) : Arsinous iodide, As,As-dimethyl- ; Dimethylarsinous iodide ; Arsine, iododimethyl- ; Dimethylarsenic iodide ; Iododimethylarsine
CAS NO:676-75-5
Molecular Formula:C2H6AsI
Molecular Weight :231.8951
Molecular Structure :
EINECS: 211-630-2
Flash Point: 45.1 °C
Enthalpy of Vaporization: 35.56 kJ/mol
Boiling Point: 133.4 °C at 760 mmHg
Vapour Pressure: 10.4 mmHg at 25°C
 

Consensus Reports

Arsenic and its compounds are on the Community Right-To-Know List.

Safety Profile

 Iododimethylarsine (CAS NO.676-75-5) is incompatible with air. Residue from distillation explodes at 72°C. When Iododimethylarsine (CAS NO.676-75-5) is heated to decomposition, it emits toxic fumes of As and I. See also ARSENIC COMPOUNDS, IODIDES, and ACETYLENE COMPOUNDS and ALKYNES.