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CAS No.: | 7397-93-5 |
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Name: | 6-BroMochrysene |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C18H11Br |
Molecular Weight: | 307.189 |
Synonyms: | Chrysene,6-bromo;6-bromo-chrysene;6-Brom-chrysen; |
Density: | 1.477g/cm3 |
Melting Point: | 152-154 °C(Solv: benzene (71-43-2)) |
Boiling Point: | 482.9°Cat760mmHg |
Flash Point: | 244.7°C |
PSA: | 0.00000 |
LogP: | 5.90870 |
Conditions | Yield |
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With N-Bromosuccinimide In water at 60℃; for 20h; | 77% |
With bromine; nitrobenzene at 120℃; | |
With tetrachloromethane; N-Bromosuccinimide |
chrysene
acetic acid
A
6-bromochrysene
trans-5-acetoxy-6-bromo-5,6-dihydrochrysene
Conditions | Yield |
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With N-bromoacetamide for 24h; Ambient temperature; | A n/a B 68% |
trans-5-acetoxy-6-bromo-5,6-dihydrochrysene
6-bromochrysene
Conditions | Yield |
---|---|
With trifluoroacetic acid |
Conditions | Yield |
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Stage #1: 6-bromochrysene With n-butyllithium In tetrahydrofuran at -78℃; for 2h; Stage #2: Triphenylsilyl chloride In tetrahydrofuran at 20℃; for 1h; | 60% |
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane at 100 - 110℃; for 2h; Inert atmosphere; | 38% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 50℃; for 1h; Suzuki Coupling; Inert atmosphere; Reflux; | 35% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 0.666667h; Inert atmosphere; Reflux; | 15% |
6-bromochrysene
chrysene-6-boronic acid
Conditions | Yield |
---|---|
With n-butyllithium; Triisopropyl borate In hexane at -78 - 20℃; for 1.5h; | 77% |