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78-99-9

Basic Information
CAS No.: 78-99-9
Name: 1,1-Dichloropropane
Molecular Structure:
Molecular Structure of 78-99-9 (1,1-Dichloropropane)
Formula: C3H6Cl2
Molecular Weight: 112.987
Synonyms: Propane, 1,1-dichloro-;PROPYLIDENE CHLORIDE;propylidenchlorid;dichloro-1,1propane;1,1-Dichlorpropan;r270fb;Propylidene dichloride;dichloro acid ethyl ester;1,1-dichloro-propan;dichloropropane;propane,1,1-dichloro;1,1-dichloro-propane;
Density: 1.13 g/mL at 25 °C(lit.)
Boiling Point: 88 °C(lit.)
Flash Point: 45 °F
Hazard Symbols: F,Xn
Risk Codes: R20/21/22; R36/37/38; R40; R11
Safety: Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC.
PSA: 0.00000
LogP: 2.20010
Synthetic route
74-98-6

propane

78-99-9

1,1-dichloropropane

Conditions
ConditionsYield
at 400℃; bei der Chlorierung;
74-98-6

propane

A

26198-63-0, 78-87-5

1,2-Dichloropropane

B

594-20-7

2,2-dichloropropane

C

78-99-9

1,1-dichloropropane

D

142-28-9

1,3-Dichloropropane

Conditions
ConditionsYield
at 400℃; Product distribution; thermische Chlorierung;
at 400℃; Product distribution; thermische Chlorierung;
123-38-6

propionaldehyde

78-99-9

1,1-dichloropropane

Conditions
ConditionsYield
With phosphorus pentachloride
590-21-6

propenyl chloride

78-99-9

1,1-dichloropropane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 25℃; im Dunkeln;
75-27-4

bromodichloromethane

74-85-1

ethene

78-99-9

1,1-dichloropropane

Conditions
ConditionsYield
Irradiation;
540-54-5

1-Chloropropane

A

26198-63-0, 78-87-5

1,2-Dichloropropane

B

78-99-9

1,1-dichloropropane

C

142-28-9

1,3-Dichloropropane

Conditions
ConditionsYield
With chlorine In 1,2-dichloro-benzene at 0℃; Product distribution; oth. temperatures;
With N-chloropiperidine; 2,2'-azobis(isobutyronitrile) In trifluoroacetic acid at 30℃; Product distribution; Rate constant; Irradiation; relative rate constants, position selectivity, substrate selectivity;
With chlorine In benzene at -10.1℃; Product distribution; dependence of the selectivity of chlorination on the conc. of benzene;
With sulfuryl dichloride; dibenzoyl peroxide
With chlorine Ambient temperature; Irradiation;
123-38-6

propionaldehyde

A

78-99-9

1,1-dichloropropane

B

26551-86-0

N-chlorocarbonyl-carbonimidic acid dichloride

Conditions
ConditionsYield
With iron(III) chloride; perchloro-2-aza-1-propene
540-54-5

1-Chloropropane

A

78-99-9

1,1-dichloropropane

B

1,2-dichloro-propane and 1,3-dichloro-propane

1,2-dichloro-propane and 1,3-dichloro-propane

Conditions
ConditionsYield
With chlorine at 305℃;
74-98-6

propane

7782-50-5

chlorine

78-00-2

tetraethyllead(IV)

A

540-54-5

1-Chloropropane

B

75-29-6

isopropyl chloride

C

78-99-9

1,1-dichloropropane

Conditions
ConditionsYield
at 136 - 140℃; Product distribution;
at 136 - 140℃; Product distribution;
74-98-6

propane

7782-50-5

chlorine

A

540-54-5

1-Chloropropane

B

78-99-9

1,1-dichloropropane

C

7789-89-1

1,1,1-trichloropropane

D

812-03-3

1,1,1,2-tetrachloropropane

Conditions
ConditionsYield
at 360 - 395℃;
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Chemistry

IUPAC Name: 1,1-Dichloropropane
The MF of 1,1-Dichloropropane (78-99-9) is C3H6Cl2.

                               
The MW of 1,1-Dichloropropane (78-99-9) is 112.99.
Synonyms of 1,1-Dichloropropane (78-99-9): Dichloropropane ; 1,1-Dichloropropane ; alpha,alpha-Dichloropropane ; alpha,alpha-Propylene dichloride ; Propane, 1,1-dichloro- ; Propylidene chloride 
Product Categories: Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Form: Colorless watery liquid with a sweet odor
Index of Refraction: 1.419 
EINECS: 201-165-3
Density: 1.116 g/ml 
Flash Point: 7.2 °C
Boiling Point: 85.2 °C
Merck: 13,7953

Production

Halogenated aliphatic compounds, such as 1,1-DICHLOROPROPANE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Toxicity Data With Reference

1.    

eye-rbt 500 mg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
2.    

eye-rbt 500 mg open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

orl-rat LD50:6500 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.    

ihl-rat LCLo:4000 ppm/4H

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.    

skn-rbt LD50:14 g/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Safety Profile

Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC.Safety information of 1,1-Dichloropropane (78-99-9):
Hazard Codes  F,Xn
Risk Statements 
20/21/22  Harmful by inhalation, in contact with skin and if swallowed
36/37/38  Irritating to eyes, respiratory system and skin
40  Limited evidence of a carcinogenic effect
11  Highly Flammable
Safety Statements 
16  Keep away from sources of ignition - No smoking
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39  Wear suitable protective clothing, gloves and eye/face protection
45  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  TX9450000
HazardClass  3.1
PackingGroup  II