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| CAS No.: | 78-99-9 |
|---|---|
| Name: | 1,1-Dichloropropane |
| Molecular Structure: | |
|
|
|
| Formula: | C3H6Cl2 |
| Molecular Weight: | 112.987 |
| Synonyms: | Propane, 1,1-dichloro-;PROPYLIDENE CHLORIDE;propylidenchlorid;dichloro-1,1propane;1,1-Dichlorpropan;r270fb;Propylidene dichloride;dichloro acid ethyl ester;1,1-dichloro-propan;dichloropropane;propane,1,1-dichloro;1,1-dichloro-propane; |
| Density: | 1.13 g/mL at 25 °C(lit.) |
| Boiling Point: | 88 °C(lit.) |
| Flash Point: | 45 °F |
| Hazard Symbols: |
 F, Xn
|
| Risk Codes: | R20/21/22; R36/37/38; R40; R11 |
| Safety: | Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl−. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC. |
| PSA: | 0.00000 |
| LogP: | 2.20010 |
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| Conditions | Yield |
|---|---|
| at 400℃; bei der Chlorierung; |
- 74-98-6
propane
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 594-20-7
2,2-dichloropropane
C
- 78-99-9
1,1-dichloropropane
D
- 142-28-9
1,3-Dichloropropane
| Conditions | Yield |
|---|---|
| at 400℃; Product distribution; thermische Chlorierung; | |
| at 400℃; Product distribution; thermische Chlorierung; |
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; iron(III) chloride at 25℃; im Dunkeln; |
| Conditions | Yield |
|---|---|
| Irradiation; |
- 540-54-5
1-Chloropropane
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 78-99-9
1,1-dichloropropane
C
- 142-28-9
1,3-Dichloropropane
| Conditions | Yield |
|---|---|
| With chlorine In 1,2-dichloro-benzene at 0℃; Product distribution; oth. temperatures; | |
| With N-chloropiperidine; 2,2'-azobis(isobutyronitrile) In trifluoroacetic acid at 30℃; Product distribution; Rate constant; Irradiation; relative rate constants, position selectivity, substrate selectivity; | |
| With chlorine In benzene at -10.1℃; Product distribution; dependence of the selectivity of chlorination on the conc. of benzene; | |
| With sulfuryl dichloride; dibenzoyl peroxide | |
| With chlorine Ambient temperature; Irradiation; |
- 123-38-6
propionaldehyde
A
- 78-99-9
1,1-dichloropropane
B
- 26551-86-0
N-chlorocarbonyl-carbonimidic acid dichloride
| Conditions | Yield |
|---|---|
| With iron(III) chloride; perchloro-2-aza-1-propene |
| Conditions | Yield |
|---|---|
| With chlorine at 305℃; |
- Total:37 Page 1 of 1 1
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Chemistry
IUPAC Name: 1,1-Dichloropropane
The MF of 1,1-Dichloropropane (78-99-9) is C3H6Cl2.
The MW of 1,1-Dichloropropane (78-99-9) is 112.99.
Synonyms of 1,1-Dichloropropane (78-99-9): Dichloropropane ; 1,1-Dichloropropane ; alpha,alpha-Dichloropropane ; alpha,alpha-Propylene dichloride ; Propane, 1,1-dichloro- ; Propylidene chloride
Product Categories: Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Form: Colorless watery liquid with a sweet odor
Index of Refraction: 1.419
EINECS: 201-165-3
Density: 1.116 g/ml
Flash Point: 7.2 °C
Boiling Point: 85.2 °C
Merck: 13,7953
Production
Halogenated aliphatic compounds, such as 1,1-DICHLOROPROPANE, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Toxicity Data With Reference
| 1. | eye-rbt 500 mg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
| 2. | eye-rbt 500 mg open | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
| 3. | orl-rat LD50:6500 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
| 4. | ihl-rat LCLo:4000 ppm/4H | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
| 5. | skn-rbt LD50:14 g/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. |
Safety Profile
Mildly toxic by ingestion, inhalation, and skin contact. An eye irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl−. See also PROPYLENE DICHLORIDE; and CHLORINATED HYDROCARBONS, ALIPHATIC.Safety information of 1,1-Dichloropropane (78-99-9):
Hazard Codes .gif){kind=small}
F,.gif){kind=small}
Xn
Risk Statements
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
36/37/38 Irritating to eyes, respiratory system and skin
40 Limited evidence of a carcinogenic effect
11 Highly Flammable
Safety Statements
16 Keep away from sources of ignition - No smoking
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS TX9450000
HazardClass 3.1
PackingGroup II