Products Categories
Basic Information
| CAS No.: | 97-36-9 |
|---|---|
| Name: | 2',4'-Dimethylacetoacetanilide |
| Molecular Structure: | |
|
|
|
| Formula: | C12H15NO2 |
| Molecular Weight: | 205.257 |
| Synonyms: | 2',4'-Acetoacetoxylidide(6CI,7CI,8CI);1-Acetoacetylamino-2,4-dimethylbenzene;2,4-Acetoacetoxylidide;Acetoacetic acid m-xylidide;Acetoaceto-m-xylidide;Acetoacetyl-m-xylidide;N-(2,4-Dimethylphenyl)-3-oxobutanamide;N-Acetoacetyl-2,4-xylidine;NSC 8398;o,p-Dimethylacetoacetanilide; |
| EINECS: | 202-576-0 |
| Density: | 1.108 g/cm3 |
| Melting Point: | 88-91 °C(lit.) |
| Boiling Point: | 365.4 °C at 760 mmHg |
| Flash Point: | 148.6 °C |
| Appearance: | White to off white powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 22 |
| Safety: | 24/25 |
| PSA: | 46.17000 |
| LogP: | 2.29400 |
Related products
- 99170-93-1N-Methyl-2-oxazolamine
- 97730-31-9(S)-4'-(2-Methylbutyl)Biphenyl-4-Carbonitrile
- 98020-47-46-Amino-5-nitro-2-thio-uracil
- 97484-76-91-(prop-2-ynyl)-1H-pyrido[2,3-d][1,3]oxazine-2,4-dione
- 97484-75-81-allyl-1H-pyrido[2,3-d][1,3]oxazine-2,4-dione
- 98025-62-8(5-METHYL-[1,3,4]THIADIAZOL-2-YL)-HYDRAZINE
- 99724-17-1Dimethyl-pyrrolidin-3-ylmethyl-amine
- 97484-82-71-allyl-7-methyl-1H-pyrido[2,3-d][1,3]oxazine-2,4-dione
- 98084-25-4CESIUM TITANATE 99.9+%
- 98296-48-1GANODERIC ACID C2(SH)
Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| In ethanol at 23 - 40℃; for 4.5h; Temperature; Solvent; Inert atmosphere; Autoclave; Large scale; | 98% |
| With benzene | |
| In water at 73 - 81℃; under 18.7519 - 277.528 Torr; Product distribution / selectivity; Heating / reflux; | |
| In benzene Heating; |
Conditions
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water; toluene for 12h; Reflux; | 78% |
- 1352630-25-1
3-(2,4-dimethylphenylamino)-2-[(2,4-dimethylphenylimino)methyl]-acrylonitrile
- 5394-63-8
2,2,6-trimethyl-4H-1,3-dioxin-4-one
A
- 97-36-9
m-acetoacetoxylidide
B
- 1352630-37-5
5-acetyl-1-(2,4-dimethylphenyl)-6-oxo-1,6-dihydropyridine-3-carbonitrile
Conditions
| Conditions | Yield |
|---|---|
| In toluene at 110℃; for 0.333333h; Inert atmosphere; | A n/a B 78% |
...Expand
- 97-36-9
m-acetoacetoxylidide
- 1371607-83-8
N-(2,4-dimethylphenyl)-2-fluoro-3-oxobutanamide
Conditions
| Conditions | Yield |
|---|---|
| With Selectfluor In PEG-400 at 60℃; for 5h; | 99% |
| With Selectfluor In water; acetonitrile at 20℃; for 4h; Schlenk technique; Sealed tube; chemoselective reaction; | 90% |
- 97-36-9
m-acetoacetoxylidide
- 1439365-70-4
N-(2,4-dimethylphenyl)-2,2-difluoro-3-oxobutanamide
Conditions
| Conditions | Yield |
|---|---|
| With 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2 2 2]octane bis(tetrafluoroborate); potassium carbonate In water at 20℃; for 29h; | 99% |
| With Selectfluor In water; acetonitrile at 20℃; for 16h; Schlenk technique; Sealed tube; chemoselective reaction; | 88% |
Conditions
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium nitrite In water at 20℃; for 0.333333h; Green chemistry; | 99% |
Conditions
| Conditions | Yield |
|---|---|
| With potassium carbonate In N,N-dimethyl-formamide | 96% |
| With potassium carbonate In N,N-dimethyl-formamide at 20℃; | |
| Stage #1: m-acetoacetoxylidide With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 1h; Stage #2: 1,4-dibromo-butane In N,N-dimethyl-formamide at 20℃; |
- 97-36-9
m-acetoacetoxylidide
- 109-64-8
1,3-dibromo-propane
- 958650-22-1
1-[6-(2,4-dimethylphenylamino)-3,4-dihydro-2H-pyran-5-yl]ethanone
Conditions
| Conditions | Yield |
|---|---|
| With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 7h; | 95% |
- 49619-82-1
3-bromo-4H-chromen-4-one
- 97-36-9
m-acetoacetoxylidide
Conditions
| Conditions | Yield |
|---|---|
| With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 20℃; regioselective reaction; | 93% |
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 97-36-9
2',4'-Dimethylacetoacetanilide
Chemistry
The Molecular formula of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9): C12H15NO2
The Molecular Weight of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9): 205.25
The Molecular Structure of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
EINECS: 202-576-0
Melting point: 88-91 °C(lit.)
Boiling Point: 365.4 °C at 760 mmHg
Flash Point: 148.6 °C
Index of Refraction: 1.555
Molar Refractivity: 59.47 cm3
Molar Volume: 185.1 cm3
Polarizability: 23.57 10-24 cm3
Surface Tension: 41.8 dyne/cm
Density: 1.108 g/cm3
Enthalpy of Vaporization: 61.17 kJ/mol
Vapour Pressure: 1.57E-05 mmHg at 25°C
IUPAC Name: N-(2,4-dimethylphenyl)-3-oxobutanamide
Synonyms: ACETO ACET M-XYLIDINE;ACETOACET-2,4-XYLIDIDE;2',4'-ACETOACETOXYLIDIDE;2',4'-DIMETHYLACETOACETANILIDE;LABOTEST-BB LT01274614;AAMX;ACETOACETIC ACID-M-XYLIDID-2,4;ACETOACET-M-XYLIDIDE;
The Molecular Weight of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9): 205.25
The Molecular Structure of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
EINECS: 202-576-0
Melting point: 88-91 °C(lit.)
Boiling Point: 365.4 °C at 760 mmHg
Flash Point: 148.6 °C
Index of Refraction: 1.555
Molar Refractivity: 59.47 cm3
Molar Volume: 185.1 cm3
Polarizability: 23.57 10-24 cm3
Surface Tension: 41.8 dyne/cm
Density: 1.108 g/cm3
Enthalpy of Vaporization: 61.17 kJ/mol
Vapour Pressure: 1.57E-05 mmHg at 25°C
IUPAC Name: N-(2,4-dimethylphenyl)-3-oxobutanamide
Synonyms: ACETO ACET M-XYLIDINE;ACETOACET-2,4-XYLIDIDE;2',4'-ACETOACETOXYLIDIDE;2',4'-DIMETHYLACETOACETANILIDE;LABOTEST-BB LT01274614;AAMX;ACETOACETIC ACID-M-XYLIDID-2,4;ACETOACET-M-XYLIDIDE;
Uses
3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9) is used as dyestuff, organic pigment, pesticide intermediates.
Toxicity Data With Reference
| 1. | orl-rat LD50:3000 mg/kg | LONZA# Personal Communication from LONZA Ltd., CH-4002, Basel, Switzerland, to NIOSH, Cincinnati, OH 45226 13JUL81 . |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx.
The Hazard Codes of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
Xn
The Risk Statements information of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
22: Harmful if swallowed
The Safety Statements information of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
24/25: Avoid contact with skin and eyes
WGK Germany: 1
RTECS: AK4585000
The Hazard Codes of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
Xn The Risk Statements information of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
22: Harmful if swallowed
The Safety Statements information of 3-OXO-N-(2,4-METHYLPHENYL)BUTANAMIDE(97-36-9):
24/25: Avoid contact with skin and eyes
WGK Germany: 1
RTECS: AK4585000