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99-10-5

Basic Information
CAS No.: 99-10-5
Name: Benzoic acid,3,5-dihydroxy-
Article Data: 33
Cas Database
Molecular Structure:
Molecular Structure of 99-10-5 (Benzoic acid,3,5-dihydroxy-)
Formula: C7H6O4
Molecular Weight: 154.122
Synonyms: a-Resorcylic acid (8CI);5-Carboxyresorcinol;NSC 22948;
EINECS: 202-730-7
Density: 1.559 g/cm3
Melting Point: 236-238 °C (dec.)(lit.)
Boiling Point: 411.5 °C at 760 mmHg
Flash Point: 216.8 °C
Solubility: Water: 84 g/L (20 °C)
Appearance: white to off-white crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-37/39
Transport Information: N/A
PSA: 77.76000
LogP: 0.79600
Synthetic route
1132-21-4

3,5-dimethoxybenzoic acid

99-10-5

3,5-Dihydroxybenzoic acid

Conditions
ConditionsYield
With Cyclohexyl iodide In N,N-dimethyl-formamide for 3h; Heating;92%
501-36-0

(E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol

A

99-10-5

3,5-Dihydroxybenzoic acid

B

123-08-0

4-hydroxy-benzaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide In water; acetone at 40℃; for 1h; Reagent/catalyst;A 46%
B 73%
618-58-6

3,5-dibromobenzoic acid

99-10-5

3,5-Dihydroxybenzoic acid

Conditions
ConditionsYield
With calcium hydroxide; water; copper at 160 - 170℃;
16110-99-9

3,6-dichlorophthalic acid

99-10-5

3,5-Dihydroxybenzoic acid

Conditions
ConditionsYield
With copper at 310℃; bei der Kalischmelze;
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    Product Name: 3,5-Dihydroxybenzoic acid CAS: 99-10-5 MF: C7H6O4 MW: 154.12 EINECS: 202-730-7 Mol File: 99-10-5.mol 3,5-Dihydroxybenzoic acid Structure 3,5-Dihydroxybenzoic acid Chemical Properties Melting point 236-238 °C

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Chemistry

IUPAC Name: 3,5-Dihydroxybenzoic acid 
Following is the structure of Benzoic acid,3,5-dihydroxy- (CAS NO.99-10-5):
             
Molecular Formula: C7H6O4
Molecular Weight: 154.12 g/mol
EINECS: 202-730-7
Density: 1.559 g/cm3
Melting Point: 235 - 237 °C
Flash Point: 216.8 °C
Freely Rotating Bonds: 3  
Index of Refraction: 1.67
Molar Volume: 98.8 cm3 
Molar Refractivity: 36.94 cm3
Polarizability: 14.64 10-24 cm3
Surface Tension: 84.2 dyne/cm
Water Solubility: 84 g/L (20 °C)
Boiling Point: 411.5 °C at 760 mmHg 
Enthalpy of Vaporization: 70.01 kJ/mol 
Vapour Pressure: 1.64E-07 mmHg at 25 °C
Solubility: slightly soluble (soluble in hot alcohol, ether)
Appearance of Benzoic acid,3,5-dihydroxy- (CAS NO.99-10-5): white to off-white crystalline powder
Product Categories: Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts; Benzoic acid; Organic acids; Building Blocks for Dendrimers; Functional Materials
Canonical SMILES: C1=C(C=C(C=C1O)O)C(=O)O
InChI: InChI=1S/C7H6O4/c8-5-1-4(7(10)11)2-6(9)3-5/h1-3,8-9H,(H,10,11)
InChIKey: UYEMGAFJOZZIFP-UHFFFAOYSA-N

Uses

α-resorcylic acid(99-10-5) is used in organic synthesis and as intermediate  for the pharmaceutical.

Toxicity Data With Reference

1.    

ivn-mus LD50:2000 mg/kg

    PMDCAY    Progress in Medical Chemistry. 5 (1967),59.

 Benzoic acid,3,5-dihydroxy- (CAS NO.99-10-5) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by intravenous route. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes:  Xi.
Xi:  Irritant.
Risk Statements:  36/37/38.
36/37/38:  Irritating to eyes, respiratory system and skin.
Safety Statements:  26-36-37/39.
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36:  Wear suitable protective clothing.  
37/39:  Wear suitable gloves and eye/face protection.
WGK Germany: 1
RTECS: VH3708000
Hazard Note: Irritant
HS Code: 29182990

Specification

 Benzoic acid,3,5-dihydroxy- , its cas register number 99-10-5. It also can be called 3,5-Dihydroxybenzoic acid ; Acide 3,5-dihydroxybenzoïque ; and 5-Carboxyresorcinol . Benzoic acid,3,5-dihydroxy- (CAS NO.99-10-5) should avoid the condition like incompatible materials, excess heat, exposure to moist air or water. It is not compatible with strong oxidizing agents, strong bases. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, carbon dioxide. However, its hazardous polymerization has not been reported.