100017-27-4

Basic information

• Product Name: (E)-1-phenylbut-2-en-1-yl acetate
• Synonyms: (E)-1-phenylbut-2-en-1-yl acetate
• CAS NO: 100017-27-4
• Molecular Weight: 190.242
• Mol File: 100017-27-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (E)-1-phenylbut-2-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenylbut-2-en-1-yl acetate(100017-27-4)
• EPA Substance Registry System: (E)-1-phenylbut-2-en-1-yl acetate(100017-27-4)

Safety Data

• Hazardous Substances Data: 100017-27-4(Hazardous Substances Data)

Upstream product

• 52755-38-1 (Z)-1-phenyl-but-2-en-1-ol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 108-86-1 bromobenzene 
• 100-52-7 benzaldehyde 
• 52755-39-2 (2E)-1-phenylbut-2-en-1-ol 
• 61550-02-5 (furan-2-yloxy)-trimethylsilane 
• 51801-01-5 (E)-1-acetoxy-1-phenyl-2-butene 
• 32398-66-6 1-phenylbut-2-yn-1-ol 
• 591-51-5 phenyllithium 
• 111-34-2 -butyl vinyl ether 
• 142-71-2 copper diacetate 

Downstream Products

• 106728-00-1 (E)-1,3-diphenyl-1-oxo-4-hexene 
• 106728-01-2 (E)-1,5-diphenyl-3-methyl-1-oxo-4-pentene 
• 97946-09-3 (+/-)-(E)-1-(dimethylphenylsilyl)-1-phenyl-2-butene 
• 97946-12-8 (E)-dimethyl(phenyl)(4-phenylbut-3-en-2-yl)silane 
• 79594-10-8 (E)-(3-methylhept-1-en-1-yl)benzene 
• 79594-11-9 ((Z)-3-Methyl-hept-1-enyl)-benzene 
• 79594-12-0 (2E)-4-phenyl-2-octene 
• 200191-40-8 (E)-dimethyl 2-(4-phenylbut-3-en-2-yl)malonate 
• 1112237-39-4 C₂₄H₂₂O₂ 
• 87246-94-4 (R)-(-)-α-Phenyl-γ-methylallyl acetate 
• 112528-98-0 (E)-(±)-2-methyl-4-phenylbut-3-enenitrile 
• 115404-72-3 dimethyl <1-phenyl-2(E)-butenyl>malonate 
• 100017-29-6 dimethyl (1R,2E)-(1-phenylbut-2-en-1-yl)malonate 
• 102882-04-2 3-phenylhexanoic methyl ester 

Relevant articles and documents

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

The reductive Ireland–Claisen rearrangement through borane-mediated hydrosilylation is reported. The method employs a borane catalyst with a special structural design and affords access to synthetically relevant products with high diastereoselectivity. Depending on electronic and structural parameters, the reaction can be coupled with a 1,3-allylic shift, thus the valence isomer of the Ireland–Claisen product is formed.

Stereoselective synthesis of furans by the Pd-catalyzed Oshima-Utimoto reaction

(Chemical Equation Presented) The Pd-catalyzed coupling of acyclic allylic alcohols with vinyl ethers was examined and found to proceed with 2.5-10 mol % of catalyst and to provide cyclic acetals with good stereoselection. The reaction is tolerant of a number of functional groups and can be used to generate quaternary centers in a stereoselective fashion.

Rhodium promoted isomerisation of allylic alkoxides: A new method for enolate anion formation

Transition metal mediated isomerisation of allylic alkoxides is presented as a new method for enolate anion generation. The scope and limitations of enolate formation with the catalysts [Rh(dppe)(THF)2]+ClO4- and (Ph3P)3RhCl are explored and the synthetic potential of the methodology demonstrated in the stereoselective formation and reactions of certain ketone and aldehyde enolates.