100514-75-8

Basic information

• Product Name: RuH(OCOPh)(CO)(PPh₃)2
• Synonyms: RuH(OCOPh)(CO)(PPh₃)2
• CAS NO: 100514-75-8
• Molecular Weight: 775.786
• Mol File: 100514-75-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: RuH(OCOPh)(CO)(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: RuH(OCOPh)(CO)(PPh₃)2(100514-75-8)
• EPA Substance Registry System: RuH(OCOPh)(CO)(PPh₃)2(100514-75-8)

Safety Data

• Hazardous Substances Data: 100514-75-8(Hazardous Substances Data)

Upstream product

• 532-32-1 sodium benzoate 
• 132751-57-6 {hydridobis(acetonitrile)bis(triphenylphosphine)carbonylruthenium(II)}BF₄ 
• 25360-32-1 carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 120-51-4 benzoic acid benzyl ester 
• 17849-38-6 2-Chlorobenzyl alcohol 
• 873-75-6 4-bromobenzenemethanol 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 65-85-0 benzoic acid 

Relevant articles and documents

Bidentate Ru(ii)-NC complexes as catalysts for the dehydrogenative reaction from primary alcohols to carboxylic acids

Four Ru(ii)-NC complexes were synthesized by one-step processes from the corresponding NC ligands with RuHCl(CO)(PPh3)3. These complexes were tested as catalysts for alcohol dehydrogenative reactions, and complex {(C5H4N)-(C6H4)}RuCl(CO)(PPh3)2 (1) showed the highest activity. With KOH as the nucleophile and 0.5 mol% catalyst loading, a series of carboxylic acids were synthesized in toluene without any oxidant. Catalyst 1 could be transformed to complex {(C5H4N)-(C6H4)}RuH(CO)(PPh3)2 (6) when treated with KOH and benzyl alcohol. Complex 6 further reacted with PhCHO and H2O to generate product {(C5H4N)-(C6H4)}Ru(OCOPh)(CO)(PPh3)2 (7). Complexes 6 and 7 exhibited similar efficiency to complex 1, suggesting that they can be regarded as the catalytic intermediates of 1.

METAL HYDRIDE COMPLEX, METHOD OF HYDROGENATING RING-OPENING POLYMERIZATION POLYMER OF CYCLOOLEFIN, AND PROCESS FOR PRODUCING PRODUCT OF HYDROGENATION OF RING-OPENING POLYMERIZATION POLYMER OF CYCLOOLEFIN

A metal hydride complex of the invention is a hydride complex of a metal selected from the group consisting of ruthenium, rhodium, osmium and iridium and has one or more aromatic carboxylic acid residues. According to the invention, there is provided a ne