100971-72-0

Basic information

• Product Name: 1-(4-cyclohexylmercapto-phenyl)-ethanone
• Synonyms: 1-(4-cyclohexylmercapto-phenyl)-ethanone
• CAS NO: 100971-72-0
• Molecular Weight: 234.362
• Mol File: 100971-72-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(4-cyclohexylmercapto-phenyl)-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-cyclohexylmercapto-phenyl)-ethanone(100971-72-0)
• EPA Substance Registry System: 1-(4-cyclohexylmercapto-phenyl)-ethanone(100971-72-0)

Safety Data

• Hazardous Substances Data: 100971-72-0(Hazardous Substances Data)

Upstream product

• 7570-92-5 cyclohexyl phenyl sulphide 
• 75-36-5 acetyl chloride 
• 1569-69-3 Cyclohexanethiol 
• 13329-40-3 4-Iodoacetophenone 
• 403-42-9 1-(4-fluorophenyl)ethanone 
• 99-90-1 para-bromoacetophenone 

Relevant articles and documents

CuMoO4 Bimetallic Nanoparticles, An Efficient Catalyst for Room Temperature C?S Cross-Coupling of Thiols and Haloarenes

CuII catalyst is less efficient at room temperature for C?S cross-coupling. C?S cross-coupling by CuII catalyst at room temperature is not reported; however, doping of copper with molybdenum metal has been realized here to be more efficient for C?S cross-coupling in comparison to general CuII catalyst. The doped catalyst CuMoO4 nanoparticle is found to be more efficient than copper. The catalyst works under mild conditions without any ligand at room temperature and is recyclable and effective for a wide range of thiols and haloarenes (ArI, ArBr, ArF) from milligram to gram scale. The copper-based bimetallic catalyst is developed and recognized for C?S cross-coupling of haloarenes with alkyl and aryl thiols.

Bimetallic BaMoO4 nanoparticles for the C-S cross-coupling of thiols with haloarenes

We disclosed new bimetallic BaMoO4 nanoparticles for the C-S cross-coupling reaction. The C-S cross-coupling reaction of alkyl/aryl thiols with haloarenes was accomplished with high yields. The reaction has good functional group tolerance and selectivity. This is an efficient protocol for synthesizing the building blocks of pharmaceuticals containing C-S bonds. The catalyst is recyclable. The unactivated bromo- and 4-acetyl fluoro-arenes can well couple to afford thioethers in high yields. The reaction is believed to proceed by oxidative addition and reductive elimination.

Efficient nickel/N-heterocyclic carbene catalyzed C-S cross-coupling

The cross-coupling reaction of aryl halides with aliphatic and aromatic thiols catalyzed by readily available Ni(OAc)2 with N-heterocyclic carbene (NHC) is reported. Ni(OAc)2/NHC catalyst showed good activities toward various aryl halides in C-S coupling reaction, even with aryl chlorides. Reactions occurred in excellent yields, broad scope, and high tolerance of functional groups.