103474-64-2Relevant academic research and scientific papers
Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. the First Evidence of CO2 Insertion into the O-O Bond of Rh(η2-O2) Complexes
Aresta, Michele,Tommasi, Immacolata,Quaranta, Eugenie,Fragale, Carlo,Mascetti, Joelle,Tranquille, Michel,Galan, Florence,Fouassier, Monique
, p. 4254 - 4260 (2008/10/09)
Extended labeling experiments have shown that formation of rhodium peroxocarbonate from CO2 and [RhCl(η2-O2(P)3] (P is PEt2Ph or PEtPh2) proceeds through O-O bond cleavage and CO2 insertion. O-transfer to ancillary phosphine ligand to give R3P=O selectively (>85%) involves the Rh-linked O atom of the peroxo group of RhCl(CO4)(P)3.
