10387-93-6

Basic information

• Product Name: Benzamide, N-(methoxyphenylmethyl)-
• CAS NO: 10387-93-6
• Molecular Formula: C15H15NO2
• Molecular Weight: 241.29
• Mol File: 10387-93-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzamide, N-(methoxyphenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-(methoxyphenylmethyl)-(10387-93-6)
• EPA Substance Registry System: Benzamide, N-(methoxyphenylmethyl)-(10387-93-6)

Safety Data

• Hazardous Substances Data: 10387-93-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 14328-15-5 N,N'-benzylidene bisbenzamide 
• 1353682-85-5 C₁₅H₁₅NO₂ 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 7471-86-5 methyl benzimidate 
• 98-88-4 benzoyl chloride 
• 100-52-7 benzaldehyde 
• 55-21-0 benzamide 
• 124-41-4 sodium methylate 
• 117067-48-8 1-benzotriazolyl-N-benzoyl-1-phenylmethylamine 

Downstream Products

• 51608-62-9 (E)-N-benzylidenebenzamide 
• 263239-91-4 (R)-3-((4R,6S)-2,4-Diphenyl-5,6-dihydro-4H-[1,3]oxazin-6-yloxy)-4,4-dimethyl-dihydro-furan-2-one 
• 263239-93-6 (R)-3-((4R,6R)-2,4-Diphenyl-5,6-dihydro-4H-[1,3]oxazin-6-yloxy)-4,4-dimethyl-dihydro-furan-2-one 
• 263239-95-8 (R)-N-(3-oxo-1-phenylpropyl)benzamide 
• 1026880-66-9 (R)-phenyl 3-(benzamido)-3-phenylpropanoate 
• 91875-49-9 (S)-N-(3-oxo-1,3-diphenylpropyl)benzamide 
• 91875-49-9 (R)-N-(3-oxo-1,3-diphenylpropyl)benzamide 
• 144494-74-6 (R)-3-benzamido-3-phenylpropanoic acid methyl ester 
• 1312310-28-3 ethyl 4-benzamido-2-hydroxylimino-4-phenylbutanoate 
• 1312310-24-9 ethyl 4-benzamido-2-oxo-4-phenylbutanoate 
• 1000681-04-8 (R)-N-(1-phenylbut-3-en-1-yl)benzamide 
• 14328-15-5 N,N'-benzylidene bisbenzamide 
• 55-21-0 benzamide 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Diastereoselective One-Pot Synthesis of Oxazolines Using Sulfur Ylides and Acyl Imines

This work describes an extended version of the Corey-Chaykovsky reaction to access oxazolines using sulfur ylides and stable precursors of acyl imines. The reaction proceeds through a mixture of aziridines and oxazolines, which provides the trans-oxazolines following in situ Heine-type aziridine ring expansion upon treatment with BF3·OEt2. Following the same one-pot procedure, amidine imides react with the sulfur ylides to provide imidazolines.

Catalytic syntheses of γ-functionalized α-keto esters from thioacetals and N,O-acetals

Ethyl 2-(trimethylsilyloxy)acrylic ester (1a) reacts with thioacetals providing the corresponding α-keto-γ-thio esters in good to satisfactory yields. Whereas aminals do not react, N,O-acetals lead to γ-amino-α-keto esters in good to excellent yields. All reactions proceed under mild reaction conditions, and no additional work up is required. Subsequent transformations of the obtained products to the corresponding α-oximes have been demonstrated.

Asymmetric Sulfur Ylide Mediated Aziridination: Application in the Synthesis of the Side Chain of Taxol

(Formula presented). Sulfur ylide methodology has been used to construct the Taxol side chain with a high degree of enantioselectivity via a trans-aziridine followed by stereospecific rearrangement of the trans-benzoylaziridine into a trans-oxazoline.