104046-99-3

Upstream product

• 74785-32-3 (E)-cinnamyl(tributyl)tin 
• 78-84-2 isobutyraldehyde 
• 100009-29-8 (E)-1-tert-butyldimethylsilyloxy-3-phenyl-2-propene 
• 960-16-7 tributylphenylstannane 
• 673-32-5 1-Phenylprop-1-yne 
• 78-83-1 2-methyl-propan-1-ol 
• 4392-24-9 Cinnamyl bromide 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 40596-17-6 (3RS,4RS)-2-methyl-4-phenyl-5-hexen-3-ol 
• 4392-24-9 (Z)-cinnamyl bromide 

Downstream Products

• 40596-17-6 (3R,4S)-2-Methyl-4-phenyl-hex-5-en-3-ol 

Relevant academic research and scientific papers

Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides

The steric course of the [2,3]-rearrangement of several unstabilized nitrogen ylides has been investigated. The reactions proceed cleanly through an anti transition state, affording modest to good yields of a single diastereomer of the product. In two exa

Indium Triiodide (InI3)-Catalyzed Allylation of Carbonyl Compounds by Allylic Tins

Indium triiodide is an effective catalyst for the allylation of aldehydes via the transmetallation with allylic tin compounds. Moreover, the chelation-controlled allylation of α-alkoxyketones proceeded with a catalytic amount of indium triiodide.

Synthesis of Enantiomerically Enriched anti-Homoallyl Alcohols Mediated by Crude Chicken Liver Esterase (CCLE)

Enantiomerically enriched anti-homoallyl alcohols were synthesized in 6799percent enantiomeric purities via enantioselective hydrolysis of the corresponding racemic acetates mediated by Crude Chicken Liver Esterase (CCLE).

Controllable Stereoselective Synthesis of (Z)- and (E)-Homoallylic Alcohols Using a Palladium-Catalyzed Three-Component Reaction

Diastereoselective synthesis of (Z)- and (E)-homoallylic alcohols using a Pd-catalyzed three-component reaction of 3-(pinacolatoboryl)allyl benzoates, aldehydes, and aryl stannanes was developed, which provides an alternative method for the allylboration of aldehydes using α, γ-diaryl-substituted allylboronates. Both sets of reaction conditions enable access to either (Z)- or (E)-homoallylic alcohols with good to high alkene stereocontrol. The present method showed good functional group compatibility and generality. Efficient chirality transfer reactions to afford enantioenriched (Z)- and (E)-homoallylic alcohols were also achieved.

Indium Mediated Coupling of Aldehydes with Allyl Bromides in Aqueous Media. The Issue of Regio- and Diastereo-selectivity

The regio- and diastereo-selectivity in the coupling of γ-substituted allyl bromides with aldehydes mediated by indium in water were found to be dependent on the steric effect of the substituents on both allyl bromides and the aldehydes.

Iridium-catalyzed coupling reaction of primary alcohols with 1-aryl-1-propynes leading to secondary homoallylic alcohols

We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products. This reaction involves an iridium-catalyzed novel catalytic transformation of 2-alkynes and primary al

Allylic tin(IV)-tin(II) chloride-acetonitrile as a novel system for allylation of carbonyls or imines

Effective allylation of aldehydes, ketones and imines was accomplished by allylic tributyltins 1 in the presence of SnCl2 in an acetonitrile solution. In this reaction system, Sn(IV)-Sn(II) transmetallation must play a key role, generating the

DIASTEREOSELECTIVITY, DIASTEREOFACIAL SELECTIVITY AND REGIOSELECTIVITY IN THE REACTIONS OF CYNNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM

The reaction of cinnamyl chlorie with a series of aryl and alkyl aldehydes mediated by tin and aluminium has been shown to be regioselective and threo diastereoselective.For aldehydes with chirality adjacent to the carbonyl function some diastereofacial s

REDUCTIVE GENERATION OF ACTIVE ZERO-VALENT TIN IN SnCl2-Al SYSTEM AND ITS USE FOR HIGHLY DIASTEREOSELECTIVE REACTION OF CINNAMYL CHLORIDE AND ALDEHYDES.

Highly diastereoselective reaction of cinnamyl chloride with aldehydes was achieved by the use of active zero-valent tin generated in SnCl2-Al system.

HIGHLY DIASTEREOSELECTIVE REACTIONS OF (E)-CINNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM

The reactions of (E)-cinnamyl chloride with aldehydes in H2O:THF:HBr in the presence of tin and aluminium powders proceed with very high stereoselectivity.