10409-07-1Relevant articles and documents
Corson,Pews
, p. 1654,1655,1656,1658,1659 (1971)
Bromonitromethane, a Versatile Electrophile: Reactions with Feebly Basic Nucleophiles
Fishwick, Brian R.,Rowles, David K.,Stirling, Charles J. M.
, p. 835 - 836 (1983)
Bromonitromethane reacts with feebly basic sulphur, phosphorus, and halogen nucleophiles at bromine or at carbon; the anion of bromonitromethane reacts with tributylboron to give 1-nitropentane.
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Kunieda,N.,Oae,S.
, p. 233 - 234 (1968)
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N,N′-Disulfonylhydrazines: New sulfonylating reagents for highly efficient synthesis of (E)-vinyl sulfones at room temperature
Hu, Yuefei,Luo, Dongping,Min, Lin,Shan, Lidong,Wang, Xinyan,Zheng, Weiping
, (2020/02/18)
N,N′-Disulfonylhydrazines have been proven to be the most reactive precursors of sulfonyl radicals in all types of sulfonyl substituted hydrazines as early as a half century ago. But such function has not been applied in organic synthesis except the formation of disulfones by self-dimerization of sulfonyl radicals. In this article, they were introduced as new sulfonylating reagents and their combinations with NIS and Et3N were established as excellent iodosulfonylating reagents for alkenes. Finally, a highly efficient method for the synthesis of (E)-vinyl sulfones was developed by mixing an alkene, a N,N′-disulfonylhydrazine, NIS and Et3N in THF at room temperature for 5 min.
Electrochemical oxidation of sulfinic acids: Efficient oxidative synthesis of diaryl disulfones
Nematollahi, Davood,Joudaki, Mahsa,Khazalpour, Sadegh,Pouladi, Firozeh
, p. G65 - G70 (2017/08/26)
Electrochemical oxidation of sulfinic acids has been studied in aqueous solutions using cyclic voltammetry, controlled-potential coulometry, chronoamperometry and chronocoulometry methods. The results indicate that the oxidation of sulfinic acids is an ir
