10419-85-9Relevant articles and documents
[(Diphenoxyphosphinyl)methylidene]triphenylphosphorane - The double P +-stabilised carbanion: A crystallographic, computational and solution NMR comparative study on the ylidic bonding
Ch?cińska, Lilianna,Kudzin, Zbigniew H.,Ma?ecka, Magdalena,Nazarski, Ryszard B.,Okruszek, Andrzej
, p. 7681 - 7693 (2003)
The crystal and molecular structure of the title compound (1) was established by an X-ray diffraction analysis. Some geometrical parameters including a slightly pyramidal shape around its ylidic Cβ-atom were determined (trans-bent type conformation), providing evidence for a strong electron delocalisation in the PαCβP γOδ backbone. The charge density redistribution within this molecular unit and its other fully optimised geometries was evaluated in ab initio MO calculations using both the HF and DFT (B3LYP) formalism, which supported such a concept. As a result, the double zwitterionic form (structure C) was suggested as the best description of 1. The absence of an experimentally NMR observable 2JPα-Cβ -Hβ coupling was tentatively rationalised in terms of fast pyramidalisation of the Cβ-anionic site. Crystallographic and solution NMR data for ylide 1 were compared with those reported for the other mesomerically stabilised Wittig-type reagents and structurally related anionic species. It was concluded that all aforementioned systems have almost identical P-ylidic bonding most likely governed mainly by very strong electrostatic interactions, with a small contribution of negative hyperconjugation.
The molecular structure of chloromethylphosphine, CClH2PH2, as determined by gas-phase electron diffraction and ab initio computations
Brain, Paul T.,Rankin, David W. H.,Robertson, Heather E.,Downs, Anthony J.,Greene, Tim M.,et al.
, p. 135 - 144 (1995)
The gas-phase structure of chloromethylphosphine, CClH2PH2, has been determined by electron diffraction employing constraints derived from ab initio computations at the CISD(fc)/6-31+G** level.At 293 K, the compound exists in two conformations, anti and gauche (phosphorus lone pair relative to the C-Cl bond); the mole fraction of the gauche conformer is 0.22(5).Important experimental structural parameters (rg/pm, /deg) for the anti and gauche conformers, respectively, are (values without e.s.d.s. indicate that the difference between the parameters for the two conformers was fixed at the theoretical value): r(C-P) = 186.3(3), 187.4; r(C-Cl) = 179.1(5), 179.0; r(P-H) = 141.5(4), 142.9; PCCl = 115.7(1), 107.8(5) .The large difference between the PCCl angles in the conformers can be rationalised on the basis of overlaps between non-bonding and antibonding molecular orbitals.
Reaction of chloromethyliso(thio)cyanato(thio)phosphonates(-phosphinates) with phenol, ethanol, and thiols
Khailova,Bagautdinova,Shaimardanova,Krepysheva,Pudovik,Chmutova,Azancheev,Musin,Pudovik
, p. 1335 - 1340 (2007/10/03)
(Chloromethyl)isocyanatophosphonates(-phosphinates) take up phenol to form carbamates whose β-cleavage gives rise to phenyl (chloromethyl) phosphonates(-phosphinates). (Chloromethyl)(thio)phosphinic-(phosphonic) isothiocyanates react with phenol at 20°C in the absence of catalyst to afford phenyl phosphinates(-phosphonates). (Alkylsulfanyl)carbamates formed by addition of thiols to (chloromethyl)iso(thio)cyanastophosphonates(-phosphinates) under the action of an equimolar amount of triethylamine undergo cyclization into 1,3,4-oxaza(thiaza)phospholines. 2004 MAIK "Nauka/ Interperiodica".