10476-85-4Relevant academic research and scientific papers
Theoretical and Experimental Study of the Crystal Structures, Lattice Vibrations, and Band Structures of Monazite-Type PbCrO4, PbSeO4, SrCrO4, and SrSeO4
Errandonea, Daniel,Muoz, Alfonso,Rodrguez-Hernndez, Placida,Proctor, John E.,Sapia, Fernando,Bettinelli, Marco
, p. 7524 - 7535 (2015)
The crystal structures, lattice vibrations, and electronic band structures of PbCrO4, PbSeO4, SrCrO4, and SrSeO4 were studied by ab initio calculations, Raman spectroscopy, X-ray diffraction, and optical-absorpt
A group of new selenite-chlorides of strontium and d-metals (Co,Ni): Synthesis, thermal behavior and crystal chemistry
Berdonosov, Peter S.,Olenev, Andrey V.,Kuznetsov, Alexei N.,Dolgikh, Valery A.
, p. 77 - 82 (2009)
The new selenite-chlorides with composition Sr3(SeO3)2Cl2 (I) and Sr2M(SeO3)2Cl2 (M=Co, Ni (II and III)) were obtained. They crystallize in monoclinic system I: space
Novel alkali earth borohydride Sr(BH4)2 and borohydride-chloride Sr(BH4)Cl
Ravnsbaek,Nickels,Cerny,Olesen,David,Edwards,Filinchuk,Jensen
, p. 10877 - 10885 (2013)
Two novel alkali earth borohydrides, Sr(BH4)2 and Sr(BH4)Cl, have been synthesized and investigated by in-situ synchrotron radiation powder X-ray diffraction (SR-PXD) and Raman spectroscopy. Strontium borohydride, Sr(BH4)2, was synthesized via a metathesis reaction between LiBH4 and SrCl2 by two complementary methods, i.e., solvent-mediated and mechanochemical synthesis, while Sr(BH4)Cl was obtained from mechanochemical synthesis, i.e., ball milling. Sr(BH4)2 crystallizes in the orthorhombic crystal system, a = 6.97833(9) A, b = 8.39651(11) A, and c = 7.55931(10) A (V = 442.927(10) A3) at RT with space group symmetry Pbcn. The compound crystallizes in α-PbO2 structure type and is built from half-occupied brucite-like layers of slightly distorted [Sr(BH4)6] octahedra stacked in the a-axis direction. Strontium borohydride chloride, Sr(BH4)Cl, is a stoichiometric, ordered compound, which also crystallizes in the orthorhombic crystal system, a = 10.8873(8) A, b = 4.6035(3) A, and c = 7.4398(6) A (V = 372.91(3) A3) at RT, with space group symmetry Pnma and structure type Sr(OH)2. Sr(BH4)Cl dissociates into Sr(BH4)2 and SrCl2 at ~170 C, while Sr(BH4)2 is found to decompose in multiple steps between 270 and 465 C with formation of several decomposition products, e.g., SrB 6. Furthermore, partly characterized new compounds are also reported here, e.g., a solvate of Sr(BH4)2 and two Li-Sr-BH 4 compounds.
Hydration of strontium chloride and rare-earth element oxychlorides
Basiev,Batyrev,Voronov,Konyushkin,Kuznetsov,Osiko,Samartsev,Samoilova,Fedorov
, p. 1035 - 1037 (2005)
Hydration and dehydration (on calcination) of SrCl2, YOCl, and HoOCl powders were studied.
Enthalpies of formation of strontium dichloride and of the strontium ion (Sr2+) in water and in 1 mol * dm-3 HCl, and an assessment of enthalpies of formation of alkaline-earth dichlorides
Morss, Lester R.,Williams, Clayton W.
, p. 279 - 286 (1983)
Measurements of the enthalpy of solution of SrCl2 in water and in 1 mol * dm-3 HCl solution lead to ΔHf0 (SrCl2, c, 298.15 K) = -(832.7 +/- 0.9) kJ * mol-1, and to ΔHf0 (Sr2+, aq, 298.15 K)
The standard enthalpies of formation of MO(s), MCl2(s), and M2+(aq,) (M = Ba, Sr)
Cordfunke, E. H. P.,Konings, R. J. M.,Ouweltjes, W.
, p. 991 - 996 (1990)
The enthalpies of solution of the oxides and chlorides and barium and strontium in 1.0 mol*dm-3 HCl(aq) and of the chlorides in H2O are reported.From these results the standard enthalpies of formation of BaO(s), SrO(s), BaCl2(s), SrCl2(s), Bas
Strontium-copper selenite-chlorides: Synthesis and structural investigation
Berdonosov, Peter S.,Olenev, Andrei V.,Dolgikh, Valery A.
, p. 2368 - 2373 (2009)
Two new complex selenite-chlorides of strontium and copper Sr2Cu(SeO3)2Cl2 (I) and SrCu2(SeO3)2Cl2 (II) were obtained and characterized by X-ray diffraction technique,
Ion-Ion-Solvent Interactions in Solution. XI Spectroscopic Studies of Group 2 Perchlorates in Acetone
James, David W.,Cutler, Paul G.
, p. 149 - 158 (1986)
Solutions of Mg(ClO4)2 and Sr(ClO4)2 in acetone have been studied at various concentrations up to saturation by using infrared absorption, Raman scattering and multinuclear n.m.r. (1H, 13C, 17O, 25Mg, 35Cl).Solvation numbers of c. 4.5 (Mg2+) and c. 5.5 (Sr2+) were determined from component band analysis of the c. 800 cm-1 acetone band in the Raman spectra.The solvent shell about the Mg2+ had a high level of steric crowding.There was a small amount of solvent-shared ion-pair formation at all concentrations in solutions of Mg(ClO4)2 which showed little concentration dependence.In solutions of Sr(ClO4)2 there was evidence for the formation of both solvent-shared associated-ion species and ion-contact species.The solvent-shared species appeared to have two alternative configurations in one of which the anion was both polarized and highly hindered.There was a salt-promoted reaction in which the perchlorate was reduced to chloride and the solution darkened.This reaction prevented the use of Raman spectra to quantify the association equilibria.
Synthesis and structural characterization of new phases in the cubic M 3Te2O6X2 (M = Sr, Ba; X = Cl, Br) structure family
Stoeger, Berthold,Weil, Matthias,Silich, Konstantin A.,Olenev, Andrey V.,Berdonosov, Peter S.,Dolgikh, Valery A.
, p. 1322 - 1329 (2011/11/05)
Four alkaline earth oxotellurate(IV) halides with common formula M 3Te2O6X2 (M = Sr, Ba; X = Cl, Br) have been prepared as polycrystalline powders and/or in the form of single crystals. All compounds crystallize in the cubic space group Fd (3) m with cell parameters a = 15.9351(4) A for Sr3Te2O 6Cl2 (single-crystal X-ray data), 16.052(5) A for Sr3Te2O6Br2 (powder X-ray data), 16.688(2) A for Ba3Te2O6Cl2 (single-crystal X-ray data) and 16.8072(3) A for Ba3Te 2O6Br1.64Cl0.36 (single-crystal X-ray data). The results of the crystal structure analyses reveal a rigid (3)[M3Te2O6]2+ framework which can be described as being composed of regular octahedra of two types of chemically non-bonded M6 octahedra that are capped by trigonal pyramidal [TeO3] anions located above every second face of one of the M 6 octahedra. The halide X- anions are situated in the voids of the [M3Te2O6]2+ framework. Dependent on the nature of the halogen, the anions show various kinds of occupational disorder which eventually led to a revision of the previous structure model of Ba3Te2O6Cl2. A comparative discussion with other structures of general formula M 3Ch2O6X2 (M = divalent metal; Ch = Te, Se; X = Cl, Br) is presented. Copyright
On the chemical vapor transport of ternary transition metal- and earth
Steiner, Udo
, p. 1706 - 1714 (2008/10/09)
The chemical vapor transport of transition metal tungstates MWO4 (M=Mn, Co, Ni, Cu, Zn, Cd) was investigated in dependence on mean transport temperature (923 K to 1223 K) and amount of transport agent Cl2. All tungstates migrate in a temperature gradient ΕT = 100 K from the region of higher temperature to the lower temperature with migration rates of 0.5 to 8 mg/h depending on experimental conditions. The transport behaviour was determined by continuous measurement of mass change during the transport experiments. The results were compared to thermo chemical calculations and the influence of moisture content discussed in detail. MgWO4 migrates under the influence of Cl2 in a temperature gradient 1273 K to 1173 K (migration rate 0.7 mg/h), CaWO4 and SrWO4 in a temperature gradient 1423 K to 1323 K (migration rate 0.1 mg/h).
