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10484-56-7

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10484-56-7 Usage

General Description

2-Butoxynaphthalene is a chemical compound with the formula C14H14O. It is a colorless to pale yellow liquid that is insoluble in water but soluble in organic solvents. 2-Butoxynaphthalene is mainly used as a plasticizer in polymers and as a solvent in various industrial applications. It is also used as a pesticide in the control of termites and other wood-damaging insects. This chemical is considered to have low toxicity to humans, but prolonged exposure may cause irritation to the skin and respiratory system. Additionally, it may have harmful effects on aquatic organisms.

Check Digit Verification of cas no

The CAS Registry Mumber 10484-56-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,8 and 4 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 10484-56:
(7*1)+(6*0)+(5*4)+(4*8)+(3*4)+(2*5)+(1*6)=87
87 % 10 = 7
So 10484-56-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H16O/c1-2-3-10-15-14-9-8-12-6-4-5-7-13(12)11-14/h4-9,11H,2-3,10H2,1H3

10484-56-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Butoxynaphthalene

1.2 Other means of identification

Product number -
Other names 2-BUTOXYNAPHTHALENE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10484-56-7 SDS

10484-56-7Synthetic route

1-bromo-butane
109-65-9

1-bromo-butane

β-naphthol
135-19-3

β-naphthol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With potassium hydroxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate Ambient temperature;98%
With potassium carbonate In acetonitrile at 125℃; for 1h; Microwave irradiation;95%
2-Methoxynaphthalene
93-04-9

2-Methoxynaphthalene

butan-1-ol
71-36-3

butan-1-ol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In water; 1,2-dichloro-ethane at 110℃; for 24h; Schlenk technique; Inert atmosphere;98%
2-(but-3-en-1-yloxy)naphthalene
463934-14-7

2-(but-3-en-1-yloxy)naphthalene

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With iron(III) chloride; lithium aluminium tetrahydride; hydrogen In tetrahydrofuran at 18℃; under 750.075 Torr; for 20h; Inert atmosphere; Sealed tube;65%
β-naphthol
135-19-3

β-naphthol

butan-1-ol
71-36-3

butan-1-ol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With Nafion NR50 at 115℃; for 35h; Inert atmosphere; Large scale reaction;97%
With sulfuric acid
β-naphthol
135-19-3

β-naphthol

n-butyl halide

n-butyl halide

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃;
n-Butyl chloride
109-69-3

n-Butyl chloride

β-naphthol
135-19-3

β-naphthol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With 2,6-dimethylpyridine; tetrabutyl-ammonium chloride; potassium carbonate In water for 8h; Heating;97%
tetrabutyl-ammonium chloride
1112-67-0

tetrabutyl-ammonium chloride

β-naphthol
135-19-3

β-naphthol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With potassium carbonate at 150 - 160℃; for 6h;27%
β-naphthol
135-19-3

β-naphthol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 18 h / 20 °C / Inert atmosphere; Cooling with ice
2: hydrogen; iron(III) chloride; lithium aluminium tetrahydride / tetrahydrofuran / 20 h / 18 °C / 750.08 Torr / Inert atmosphere; Sealed tube
View Scheme
1-bromo-butane
109-65-9

1-bromo-butane

sodium 2-naphtholate
875-83-2

sodium 2-naphtholate

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With ethanol
1-bromo-butane
109-65-9

1-bromo-butane

β-naphthol
135-19-3

β-naphthol

1.) Amberlite IRA-900(Cl(1-))

1.) Amberlite IRA-900(Cl(1-))

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With sodium hydroxide 1.) EtOH; 2.) THF, 65 deg C; Multistep reaction;
1-bromo-butane
109-65-9

1-bromo-butane

potassium 2-naphthoxide
36294-21-0

potassium 2-naphthoxide

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With potassium hydroxide
butyl para-toluenesulfonate
778-28-9

butyl para-toluenesulfonate

potassium 2-naphthoxide
36294-21-0

potassium 2-naphthoxide

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With ethanol
1-bromo-2-naphthol
573-97-7

1-bromo-2-naphthol

butan-1-ol
71-36-3

butan-1-ol

2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

Conditions
ConditionsYield
With cerium triflate Inert atmosphere;
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

2-butoxy-6-nitronaphthalene
118806-85-2

2-butoxy-6-nitronaphthalene

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In acetic acid at 60 - 80℃; for 2.5h;98.1%
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

methylmagnesium bromide
75-16-1

methylmagnesium bromide

2-Methylnaphthalene
91-57-6

2-Methylnaphthalene

Conditions
ConditionsYield
bis(tricyclohexylphosphine)nickel(II) dichloride In diethyl ether; toluene at 80℃; for 0.333333h;96%
With tricyclohexylphosphine In toluene at 40℃; for 2h; Inert atmosphere;71 %Chromat.
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

benzyltrimethylazanium tribroman-2-uide

benzyltrimethylazanium tribroman-2-uide

1-bromo-2-butoxynaphthalene

1-bromo-2-butoxynaphthalene

Conditions
ConditionsYield
With cetyltrimethylammonim bromide In 1,2-dichloro-ethane at 20℃; for 1.5h; regioselective reaction;96%
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

A

2,2'-dibutoxy-1,1'-binaphthalene
21759-22-8

2,2'-dibutoxy-1,1'-binaphthalene

B

butyl-(1-chloro-[2]naphthyl)-ether

butyl-(1-chloro-[2]naphthyl)-ether

Conditions
ConditionsYield
With CuCl2-Al2O3 In benzene at 50℃; for 2h;A 10%
B 85%
With CuCl2-Al2O3 In benzene at 50℃; for 2h;A 10%
B 85 % Chromat.
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

potassium thioacyanate
333-20-0

potassium thioacyanate

2-butoxynaphthalene-1-carbonitrile

2-butoxynaphthalene-1-carbonitrile

Conditions
ConditionsYield
With silica sulfuric acid In neat (no solvent, solid phase) at 100℃; for 12h; regioselective reaction;74%
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

hexan-1-ol
111-27-3

hexan-1-ol

2-(n-hexyloxy)naphthalene
31059-20-8

2-(n-hexyloxy)naphthalene

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In water; 1,2-dichloro-ethane at 110℃; for 24h; Schlenk technique; Inert atmosphere;35%
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

A

2,2'-dibutoxy-1,1'-binaphthalene
21759-22-8

2,2'-dibutoxy-1,1'-binaphthalene

B

1-bromo-2-butoxynaphthalene

1-bromo-2-butoxynaphthalene

Conditions
ConditionsYield
With CuBr2-Kieselguhr In benzene at 50℃; for 2h;A 1%
B 86 % Chromat.
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

butyl-(1-nitro-[2]naphthyl)-ether
92961-44-9

butyl-(1-nitro-[2]naphthyl)-ether

Conditions
ConditionsYield
With nitric acid
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

2,4-dinitro-benzenediazonium-sulfate

2,4-dinitro-benzenediazonium-sulfate

C.I. pigment orange 5
3468-63-1

C.I. pigment orange 5

Conditions
ConditionsYield
With acetic acid
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

2-butoxy-[1]naphthylamine
107521-86-8

2-butoxy-[1]naphthylamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous HNO3
2: zinc; aq.-ethanolic HCl
View Scheme
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

2,2'-dibutoxy-1,1'-binaphthalene
21759-22-8

2,2'-dibutoxy-1,1'-binaphthalene

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; (S)-2-phenylglycine at 100℃; for 4h; Neat (no solvent); optical yield given as %ee;
2-butoxynaphthalene
10484-56-7

2-butoxynaphthalene

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-phenylnaphthalene
612-94-2

2-phenylnaphthalene

Conditions
ConditionsYield
With tricyclohexylphosphine In toluene at 80℃; for 2h; Inert atmosphere;70 %Chromat.

10484-56-7Relevant articles and documents

Bradshaw et al.

, p. 2051 (1972)

An efficient lutidine-assisted etherification of phenols with alkyl chloride in water

Aki, Shinji,Nishi, Takao,Minamikawa, Jun-Ichi

, p. 940 - 941 (2004)

An efficient etherification of phenol derivatives with alkyl chloride in water was achieved. The reactivity of the ether bond forming reaction was activated by addition of 2,6-lutidine.

Iron-catalyzed olefin hydrogenation at 1 bar H2 with a FeCl3-LiAlH4 catalyst

Gieshoff, Tim N.,Villa, Matteo,Welther, Alice,Plois, Markus,Chakraborty, Uttam,Wolf, Robert,Jacobi Von Wangelin, Axel

supporting information, p. 1408 - 1413 (2015/03/18)

The scope and mechanism of a practical protocol for the iron-catalyzed hydrogenation of alkenes and alkynes at 1 bar H2 pressure were studied. The catalyst is formed from cheap chemicals (5 mol% FeCl3-LiAlH4, THF). A homogeneous mechanism operates at early stages of the reaction while active nanoparticles form upon ageing of the catalyst solution. This journal is

O-Alkylation of phenol derivatives via a nucleophilic substitution

Cazorla, Clement,Pfordt, Emilie,Duclos, Marie-Christine,Metay, Estelle,Lemaire, Marc

experimental part, p. 2482 - 2488 (2011/10/31)

The alkylation of phenol derivatives can be achieved in good yield via Lewis or Bronsted acid. The only by-product of the reaction is water and the catalyst can be recycled when using Bronsted acid.

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