107536-32-3

Upstream product

• 532-32-1 sodium benzoate 
• 6729-64-2 tri(p-tolyl)bismuth dichloride 
• 301-04-2 lead acetate 
• 532-31-0 silver benzoate 
• 121882-74-4 tris(p‐tolyl)bismuth dibromide 
• 858520-14-6 p-Tol₃Bi(OSO₂C₆H₃Me₂-2,4)2 
• 5142-75-6 tri(p-tolyl)bismuth 
• 858520-08-8 μ-oxobis[(2,4-dimethylbenzenesulfonato)tri-p-tolylbismuth] 
• 127-09-3 sodium acetate 

Downstream Products

• 73791-19-2 4-hydroxy-3-(p-tolyl)-1-benzopyran-2-one 
• 121884-66-0 4-hydroxy-7-methoxy-3-p-tolylcoumarin 
• 620-84-8 4-methyldiphenylamine 
• 104-93-8 p-methylanizole 
• 64-19-7 acetic acid 
• 108-88-3 toluene 
• 10519-06-9 1-butoxy-4-methylbenzene 
• 17113-32-5 2-(4-methylphenyl)furan 
• 16939-04-1 2-p-tolylthiophene 
• 155890-16-7 (C₆H₄CH₃)3Bi(CF₃COO)2 
• 192327-41-6 di(O,O-tropolonato)tri(p-tolyl)bismuth(V) 
• 5142-75-6 tri(p-tolyl)bismuth 
• 1370712-59-6 C₁₈H₂₀O₃ 
• 773893-07-5 tert-butyl 2-(4-methylphenyl)azocarboxylate 

Relevant academic research and scientific papers

Synthesis, structure and reactions of μ- oxobis(arenesulfonatotriarylbismuth)

Hydrolysis of triarylbismuth bis(arenesulfonates) in acetone gives bismuth derivatives of the general formula [Ar3Bi(OSO2Ar')] 2O (Ar = Ph, p-Tol; Ar' = Ph, C6H4Me-4, C 6H3Me2-2,4, C6H3Me 2-3,4). The structure of μ-oxobis[(3,4-dimethylbenzenesulfonato) triphenylbismuth] was established by means of X-ray diffraction. The molecule has a linear centrosymmetric structure with the bridging oxygen atom in the inversion center. The bismuth atom has a distorted trigonal bipyramidal coordination with the bridging oxygen atom and the arenesulfonate group in axial positions. The Bi-C and Bi-Oterm distances are 2.200(2), 2.204(3), and 2.442(2) A, and the Bi-Obr distances are 2.067(1) A. 2004 MAIK "Nauka/Interperiodica".

Unexpected Formation of Triarylbismuth Diformates in the Oxidation of Triarylbismuthines with Ozone at Low Temperatures

Oxidation of triphenylbismuthine 1 with ozone in toluene at -78 deg C gave, unexpectedly, a high yield of triphenylbismuth diformate 3, which was also obtainable as a minor product by a similar oxidation in ethyl acetate and acetone.An X-ray crystallographic study revealed that compound 3 has C2 symmetry, the geometry around the bismuth atom being best described as a distorted trigonal bipyramid as a result of strong intramolecular interaction between the bismuth and carbonyl oxygen atoms.Treatment of compound 3 with aqueous sodium acetate or halides readily converted it into the corresponding triphenylbismuth diacetate 5 or dihalides 7 - 9.