107951-80-4Relevant academic research and scientific papers
Reduction of Ketene Dithioacetal S,S-Dioxides with Sodium Borohydride and Its Application to a Convenient Synthesis of Alkyl Arylmethyl Ketones
Ogura, Katsuyuki,Ohtsuki, Kazuo,Takahashi, Kazumasa,Iida, Hirotada
, p. 1597 - 1598 (2007/10/02)
The C-C double bond of a ketene dithioacetal S,S-dioxide was found to undergo reduction with sodium borohydride.This fact provides an efficient synthetic route from an aromatic aldehyde to an alkyl arylmethyl ketone using methylthiomethyl p-totyl sulfone.
ALDEHYDE AND KETONE SYNTHESES USING METHYLTHIOMETHYL p-TOLYL SULFONE
Ogura, Katsuyuki,Ohtsuki, Kazuo,Nakamura, Masami,Yahata, Nobuhiro,Takahashi, Kazumasa,Iida, Hirotada
, p. 2455 - 2458 (2007/10/02)
Methylthiomethyl p-tolyl sulfone (1) was conveniently alkylated to give mono- and dialkylated products (2 and 4).Reaction conditions for the transformation of 2 and 4 into aldehydes (3) and ketones (5), respectively, were exploited.
