111012-66-9

Usage

Type of compound

Organic compound

Structure

Contains four oxygen atoms

Derived from

Dithiane (a six-membered heterocyclic compound with two sulfur atoms and four carbon atoms)

Modification

Addition of a phenyl group to the dithiane molecule

Properties

Aromatic due to the phenyl group

Applications

Organic synthesis, pharmaceuticals, agrochemicals, and material science

Role

Versatile building block for constructing complex organic molecules

Reactivity

Valuable reagent for chemical transformations (introduction of new functional groups or modification of existing ones)

Safety

Should be handled with caution due to potential reactivity and toxicity

Upstream product

• 80934-80-1 5-phenyl-4,6-bis(methoxycarbonyl)-1,3-dithiane 1,1,3,3-tetroxide 
• 111012-65-8 5-phenyl-2,6-dicarboxy-1,3-dithiane 1,1,3,3-tetroxide 
• 100-52-7 benzaldehyde 
• 125231-52-9 2-ethoxymethylene-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide 
• 109-89-7 diethylamine 

Downstream Products

• 121215-69-8 2-phenylthiocarbamoyl-5-phenyl-1,3-dithiane 1,1,3,3-tetroxide 
• 134836-04-7 2-(N-piperidinomethylene)-5-phenyl-1,3-dithiane-1,1,3,3-tetraoxide 
• 145577-61-3 2,2-bis(2-ethoxycarbonylethyl)-5-phenyl-1,3-dithiane 1,1,3,3-tetroxide 
• 145577-60-2 2,2-bis(2-carboxyethyl)-5-phenyl-1,3-dithiane 1,1,3,3-tetroxide 
• 125231-67-6 2-(2,4-dinitrophenylhydrazonomethylene)-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide 
• 125231-59-6 Octadecyl-(1,1,3,3-tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-amine 
• 125231-66-5 Benzothiazol-2-yl-(1,1,3,3-tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-amine 
• 125231-56-3 2-(N-phenylthiocarbamoyl)aminomethylene-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide 
• 125231-55-2 2-(N-phenylcarbamoyl)aminomethylene-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide 
• 125231-60-9 Cyclohexyl-(1,1,3,3-tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-amine 
• 125231-54-1 2-benzoylaminomethylene-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide 
• 125231-65-4 (1,1,3,3-Tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-thiazol-2-yl-amine 
• 125231-62-1 Benzyl-(1,1,3,3-tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-amine 
• 125231-64-3 Pyridin-2-yl-(1,1,3,3-tetraoxo-5-phenyl-1λ⁶,3λ⁶-[1,3]dithian-2-ylidenemethyl)-amine 

Relevant academic research and scientific papers

2-ETHOXYMETHYLENE-5-PHENYL-1,3-DITHIANE 1,1,3,3-TETRAOXIDE AND ITS TRANSFORMATIONS

2-Ethoxymethylene-5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide was obtained by the reaction of 5-phenyl-1,3-dithiane 1,1,3,3-tetraoxide with ethyl orthoformate in the presence of zinc chloride and acetic anhydride.The reactions of the product with nucleophili

HYDROLYTIC CLEAVAGE OF 5-ARYL-4,6-BIS(METHOXYCARBONYL)-1,3-DITHIANE 1,1,3,3-TETROXIDES

The brief heating of 5-aryl-4,6-bis(methoxycarbonyl)-1,3-dithiane 1,1,3,3-tetroxides in an alkyline medium leads to 5-aryl-4,6-dicarboxy-1,3-dithane 1,1,3,3-tetroxides, which are decarboxylated when heated in an acidic medium with the formation of 5-aryl-1,3-dithiane 1,1,3,3-tetroxides.The prolonged action of heat on 5-aryl-4,6-bis(methoxycarbonyl)-1,3-dithiane 1,1,3,3-tetroxides in an alkaline medium leads to their cleavage into benzaldehyde, acetophenone, bis(methylsulfonyl)methane, dimethylsulfone, and 1-methylsulfonyl-2-arylvinylacetic acids.Their formation is due to the various reactions which take place simultaneously during extensive hydrolysis.