1113-31-1

Basic information

• Product Name: Dichloro(dimethylamino)borane
• Synonyms: Dichloro(dimethylamino)borane;Dimethylaminoboron dichloride;Dimethylaminodichloroborane;borane, dichloro(dimethyl-amino)
• CAS NO: 1113-31-1
• Molecular Formula: C₂H₆BCl₂N
• Molecular Weight: 125.7927
• Mol File: 1113-31-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 114.52°C (estimate)
• Flash Point: 7.3°C
• Appearance: /
• Density: 1.108g/cm³
• Vapor Pressure: 61.1mmHg at 25°C
• Refractive Index: 1.41
• CAS DataBase Reference: Dichloro(dimethylamino)borane(CAS DataBase Reference)
• NIST Chemistry Reference: Dichloro(dimethylamino)borane(1113-31-1)
• EPA Substance Registry System: Dichloro(dimethylamino)borane(1113-31-1)

Safety Data

• Hazardous Substances Data: 1113-31-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 74, p. 1219, 1952 DOI: 10.1021/ja01125a024

InChI:InChI=1/C2H6BCl2N/c1-6(2)3(4)5/h1-2H3

Upstream product

• 124-40-3 dimethyl amine 
• 1585-74-6 dimethylchloroamine 
• 13701-67-2 diboron tetrachloride 
• 13931-04-9 (Cl₂B{NH(CH₃)2}2)⁽¹⁺⁾*Cl^(1-)=(Cl₂B{NH(CH₃)2}2)Cl 
• 10294-34-5 boron trichloride 
• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 31012-32-5 dichloro-dimethylamino-arsine 
• 856314-21-1 dimethyl-amine; compound with boron chloride 
• 1113-30-0 Tetramethylborazen 

Downstream Products

• 69737-41-3 C₆H₁₂BCl₂NO 
• 11113-50-1 boric acid 
• 124-40-3 dimethyl amine 
• 41924-95-2 1-dimethylamino-2,2,3,3,4,4,5,5-octaphenyl-1-boracyclopentasilane 
• 4375-83-1 tris(dimethylamino)borane 
• 359-18-2 (dimethylamino)difluoroborane 
• 10025-91-9 antimony(III) chloride 
• 75-15-0 carbon disulfide 
• 6562-41-0 chloro-bis(dimethylamino)borane 
• 122501-55-7 1,3-di-tert-butyl-2,4-bis(dimethylamino)-1,2,3,4-diphosphadiboretane 
• 2501-94-2 tert-butylphosphine 
• 867-97-0 tris(diethylamino)borane 
• 557-66-4 ethanamine hydrochloride 
• 100709-06-6 (4-BrC₆H₄)2B-N(CH₃)2 

Relevant articles and documents

Low-spin binuclear titanium complexes. III. The preparation and characterization of heptachlorodititanate(VI) salts

Treatment of bis(dimethylamino)chloroboranehexachlorodititanium(VI), [(CH3)2N]2BCl·Ti2Cl 6, with HCl affords bis(dimethylamine)dichloroboronium heptachlorodititanate(VI), {[(CH3)2/sub

Oxidation of Diborane(4) Molecules by Chloramines

The boron-boron bonds in the diborane(4) molecules (Me2N)2B-B(NMe2)2 (1), (Me2N)ClB-BCl(NMe2) (5) and Cl2B-BCl2 (8) as in B4Cl4 are cleaved by the chloramines Me2NCl (2), MeNCl2 and EtNCl2 (9).As oxydation products BCl3 or the corresponding aminoborane and diborylamines can be isolated.The interaction of 8 and 2 leads to the formation of Me2NH*BCl3 as additional product. - Elementary chlorine does not only cleave the B-B but also the B-N bond in 1, giving Me2NCl as one of the reaction products. - The properties of the N-ethylbis(dichloroboryl)amine (11) are discussed.