111807-81-9

Upstream product

• 100-83-4 meta-hydroxybenzaldehyde 
• 700-58-3 2-Adamantanone 
• 120687-94-7 3-t-butyldimethylsilyloxybenzoic acid methyl ester 
• 96013-95-5 3-(tert-butyl-dimethyl-sylanyloxy)benzaldehyde 
• 24396-25-6 m-hydroxybenzaldehyde dimethyl acetal 
• 19438-10-9 methyl 3-hydroxybenzoate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 134518-89-1 3-pivaloyloxybenzaldehyde 
• 134518-91-5 C₂₃H₃₀O₃ 
• 134518-90-4 3-[(diethoxyphosphoryl)(methoxy)methyl]phenyl pivalate 
• 134519-01-0 3-(dimethoxymethyl)phenyl pivalate 
• 121445-45-2 [(3-hydroxyphenyl)methoxymethylene]tricyclo[3.3.1.13.7]-decane 

Downstream Products

• 121445-45-2 [(3-hydroxyphenyl)methoxymethylene]tricyclo[3.3.1.13.7]-decane 
• 111807-83-1 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane> 

Relevant academic research and scientific papers

Stable dioxetane precursors as selective trap-and-trigger chemiluminescent probes for singlet oxygen

A set of highly selective chemiluminescent probes has been developed for the detection and quantitation of singlet oxygen (1O2), a reactive oxygen species that is known to transform organic pollutants in the aquatic environment and e

Probing Force with Mechanobase-Induced Chemiluminescence

Mechanophores capable of releasing N-heterocyclic carbene (NHC), a strong base, are combined with triggerable chemiluminescent substrates to give a novel system for mechanically induced chemiluminescence. The mechanophores are palladium bis-NHC complexes,

Synthesis process of AMPPD

The invention relates to the technical field of organic synthesis, in particular to a synthesis process of AMPPD. The synthesis process of AMPPD comprises the following steps: reacting an intermediate with molybdate in an organic solvent to form a product

MOLECULAR RENAL PROBES FOR DETECTING ACUTE KIDNEY INJURY

Disclosed herein are compounds or salts and/or solvates of formula I, II and III, where the compounds or salts and/or solvates have the following structures: (X)a-Y-(Z)b I; II; or X'-Y' III; where X, Y, Z, X', Y', a, b, R4

A novel chemiluminescent probe for hydrazine detection in water and HeLa cells

Hydrazine is a substance harmful to humans and the environment, necessitating the development of a sensitive and specific detection method. Herein, a novel chemiluminescent probe based on Schaap's adamantylidene-dioxetane (CL-HZ) for detecting hydrazine w

CHEMILUMINESCENT PROBES FOR DIAGNOSTICS AND IN VIVO IMAGING

The present invention provides dioxetane-based chemiluminescence probes, more specifically ?uorophore-tethered dioxetane-based chemiluminescence probes and π* acceptor group-containing dioxetane based chemiluminescence probes, and compositions thereof. Th

A chemiluminescence sensor with signal amplification based on a self-immolative reaction for the detection of fluoride ion at low concentrations

A sensory system incorporated with an amplification function was developed for the detection of trace-level fluoride ions. This sensory system comprises two steps: amplification and chemiluminescence. These steps were linked with chemical reactions and we

Comparison of convenient alternative synthetic approaches to 4-[(3-tert-butyldimethylsilyloxy)phenyl]-4-methoxyspiro[1,2-dioxetane-3, 2′-adamantane]

The preparation of 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro[1, 2-dioxetane-3,2′-adamantane] by two different approaches is described and the results are compared with previously reported data. The precursor olefin, 1-[3-(tert-butyldimethylsilyloxy)phenyl]-1-methoxy-2-spiroadamantylidene is obtained from 3-hydroxybenzaldehyde by both Horner-Wadsworth-Emmons and McMurry coupling reactions in 42% overall yield in both cases. 1,2-Dioxetane preparation by singlet oxygen addition, obtained through calcium peroxide diperoxohydrate thermolysis, is compared with conventional photooxygenation. Georg Thieme Verlag Stuttgart.

McMurry intermolecular cross-coupling between an ester and a ketone: Scope and limitations

In the course of our studies towards the synthesis of a dioxetane bearing chemiluminescent probe for the detection of thiols, we were faced with the synthesis of sterically hindered benzylic enol ethers. This issue was solved via the use of an intermolecular McMurry cross-coupling between an ester and a ketone. In this article, together with the synthesis of the chemiluminescent probe, the scope and limitations of this low valent titanium based carbon-carbon double bond formation are discussed.