134518-91-5

Upstream product

• 134519-01-0 3-(dimethoxymethyl)phenyl pivalate 
• 134518-89-1 3-pivaloyloxybenzaldehyde 
• 134518-90-4 3-[(diethoxyphosphoryl)(methoxy)methyl]phenyl pivalate 
• 700-58-3 2-Adamantanone 
• 100-83-4 meta-hydroxybenzaldehyde 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 121445-45-2 [(3-hydroxyphenyl)methoxymethylene]tricyclo[3.3.1.13.7]-decane 
• 111807-81-9 {3-[methoxy(tricyclo[3.3.1.13,7]dec-2-ylidene)methyl]phenoxy}(dimethyl)(2-methyl-2-propanyl)silane 
• 111807-83-1 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane> 

Relevant academic research and scientific papers

Comparison of convenient alternative synthetic approaches to 4-[(3-tert-butyldimethylsilyloxy)phenyl]-4-methoxyspiro[1,2-dioxetane-3, 2′-adamantane]

The preparation of 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro[1, 2-dioxetane-3,2′-adamantane] by two different approaches is described and the results are compared with previously reported data. The precursor olefin, 1-[3-(tert-butyldimethylsilyloxy)phenyl]-1-methoxy-2-spiroadamantylidene is obtained from 3-hydroxybenzaldehyde by both Horner-Wadsworth-Emmons and McMurry coupling reactions in 42% overall yield in both cases. 1,2-Dioxetane preparation by singlet oxygen addition, obtained through calcium peroxide diperoxohydrate thermolysis, is compared with conventional photooxygenation. Georg Thieme Verlag Stuttgart.