111807-83-1

Basic information

• Product Name: 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane>
• Synonyms: 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane>
• CAS NO: 111807-83-1
• Molecular Weight: 416.633
• Mol File: 111807-83-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane>(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane>(111807-83-1)
• EPA Substance Registry System: 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro<1,2-dioxetane-3,2'-adamantane>(111807-83-1)

Safety Data

• Hazardous Substances Data: 111807-83-1(Hazardous Substances Data)

Upstream product

• 134518-89-1 3-pivaloyloxybenzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 121445-45-2 [(3-hydroxyphenyl)methoxymethylene]tricyclo[3.3.1.13.7]-decane 
• 19438-10-9 methyl 3-hydroxybenzoate 
• 134518-91-5 C₂₃H₃₀O₃ 
• 134518-90-4 3-[(diethoxyphosphoryl)(methoxy)methyl]phenyl pivalate 
• 134519-01-0 3-(dimethoxymethyl)phenyl pivalate 
• 111807-81-9 {3-[methoxy(tricyclo[3.3.1.13,7]dec-2-ylidene)methyl]phenoxy}(dimethyl)(2-methyl-2-propanyl)silane 
• 100-83-4 meta-hydroxybenzaldehyde 
• 120687-94-7 3-t-butyldimethylsilyloxybenzoic acid methyl ester 
• 700-58-3 2-Adamantanone 

Downstream Products

• 700-58-3 2-Adamantanone 
• 150-60-7 dibenzyl disulphide 
• 16096-98-3 trans-1,2-dithiane-4,5-diol 
• 1892-29-1 bis(2-hydroxyethyl) disulfide 
• 32381-28-5 N,N'-diacetyl-L-cystine dimethyl ester 
• 1069-29-0 L-cystine dimethyl ester 
• 16359-16-3 (2R,2R’)-3,3’-disulfanediyl bis(2 acetamidopropanamide) 
• 638-44-8 N,N'-(dithiodiethylene)bisacetamide 
• 37886-90-1 bis(2-acetoxyethyl) disulfide 
• 19438-10-9 methyl 3-hydroxybenzoate 
• 120687-94-7 3-t-butyldimethylsilyloxybenzoic acid methyl ester 
• 111756-00-4 tetrabutylammonium m-carbomethoxyphenolate 

Relevant articles and documents

Quantification of singlet oxygen production in the reaction of superoxide with hydrogen peroxide using a selective chemiluminescent probe

A sensitive chemiluminescent probe that selectively reacts with singlet oxygen in the presence of superoxide and hydrogen peroxide has been used to quantify the production of singlet oxygen in the reaction of superoxide with hydrogen peroxide. The yield o

Comparison of convenient alternative synthetic approaches to 4-[(3-tert-butyldimethylsilyloxy)phenyl]-4-methoxyspiro[1,2-dioxetane-3, 2′-adamantane]

The preparation of 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro[1, 2-dioxetane-3,2′-adamantane] by two different approaches is described and the results are compared with previously reported data. The precursor olefin, 1-[3-(tert-butyldimethylsilyloxy)phenyl]-1-methoxy-2-spiroadamantylidene is obtained from 3-hydroxybenzaldehyde by both Horner-Wadsworth-Emmons and McMurry coupling reactions in 42% overall yield in both cases. 1,2-Dioxetane preparation by singlet oxygen addition, obtained through calcium peroxide diperoxohydrate thermolysis, is compared with conventional photooxygenation. Georg Thieme Verlag Stuttgart.

CHEMICAL AND ENZYMATIC TRIGGERING OF 1,2-DIOXETANES. 2:FLUORIDE-INDUCED CHEMILUMINESCENCE FROM TERT-BUTYLDIMETHYLSILYLOXY-SUBSTITUTED DIOXETANES

Thermally stable 1,2-dioxetanes bearing tert-butyldimethylsilyloxyaryl groups have been prepared.Reaction of these dioxetanes with fluoride ion at ambient temperature in MeCN and DMSO generates chemiluminescence with efficiencies up to 25percent.