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Diethyleneglycolmonohexylether Manufacturer/High quality/Best price/In stock
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USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Factory Supply 2-(2-hexyloxyethoxy)ethanol
Cas No: 112-59-4
No Data 1 1 Ality Chemical Corporation Contact Supplier
Diethylene glycol monohexyl ether
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No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Diethyleneglycol monohexyl ether
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Wholesale price CAS 112-59-4 with best price
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USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
Diethyleneglycolmonohexylether 112-59-4
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No Data 1 Kilogram 10000 Metric Ton/Month Shanghai Upbio Tech Co.,Ltd Contact Supplier
2-(2-HEXYLOXYETHOXY)ETHANOL CAS NO.112-59-4
Cas No: 112-59-4
No Data 10 Gram 500 Kilogram/Month Changchun Artel lmport and Export trade company Contact Supplier
Diethyleneglycolmonohexylether
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Top sale 112-59-4 Diethylene glycol monohexyl ether/2-(2-HEXYLOXYETHOXY)ETHANOL with best price
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USD $ 1000.0-1500.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
2-(2-HEXYLOXYETHOXY)ETHANOL CAS NO.112-59-4
Cas No: 112-59-4
No Data 100 Gram 500 Metric Ton/Month Changchun JuShengyuan Import and Export Trading Co.,Ltd Contact Supplier

112-59-4 Usage

Chemical Properties

Clear colorless liquid

Reactivity Profile

Ethers, such as 2-(2-HEXYLOXYETHOXY)ETHANOL can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.

General Description

Water-white liquid.

Air & Water Reactions

Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid.

Health Hazard

Exposure can cause irritation of eyes, nose and throat.
InChI:InChI=1/C10H22O3/c1-2-3-4-5-7-12-9-10-13-8-6-11/h11H,2-10H2,1H3

112-59-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (B20774)  Diethylene glycol mono-n-hexyl ether, 97%    112-59-4 500ml 358.0CNY Detail
Alfa Aesar (B20774)  Diethylene glycol mono-n-hexyl ether, 97%    112-59-4 2500ml 1432.0CNY Detail
Alfa Aesar (B20774)  Diethylene glycol mono-n-hexyl ether, 97%    112-59-4 10000ml 4446.0CNY Detail
Aldrich (449393)  Di(ethyleneglycol)hexylether  95% 112-59-4 449393-1L 806.13CNY Detail
Aldrich (449393)  Di(ethyleneglycol)hexylether  95% 112-59-4 449393-4L 2,320.11CNY Detail
Aldrich (449393)  Di(ethyleneglycol)hexylether  95% 112-59-4 449393-18L 7,856.55CNY Detail
Aldrich (300284)  Di(ethyleneglycol)hexylether  97% 112-59-4 300284-25ML 512.46CNY Detail

112-59-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name Diethylene Glycol Monohexyl Ether

1.2 Other means of identification

Product number -
Other names Ethanol, 2-[2-(hexyloxy)ethoxy]-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Solvents (for cleaning or degreasing)
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:112-59-4 SDS

112-59-4Synthetic route

1-bromo-hexane
111-25-1

1-bromo-hexane

diethylene glycol
111-46-6

diethylene glycol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With potassium hydroxide In 1,4-dioxane at 100 - 105℃;68%
With sodium hydride
oxirane
75-21-8

oxirane

2-hexyloxyethanol
112-25-4

2-hexyloxyethanol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With borontrifluoride acetic acid
oxirane
75-21-8

oxirane

hexan-1-ol
111-27-3

hexan-1-ol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 50℃;
1-bromo-hexane
111-25-1

1-bromo-hexane

sodium diethylene glycolate

sodium diethylene glycolate

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With diethylene glycol at 200℃;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-(2'-n-hexyloxyethoxy)ethyl p-toluenesulfonate
187748-60-3

2-(2'-n-hexyloxyethoxy)ethyl p-toluenesulfonate

Conditions
ConditionsYield
Stage #1: diethylene glycol monohexyl ether; p-toluenesulfonyl chloride With dmap In dichloromethane at 20℃; for 0.166667h;
Stage #2: With triethylamine In dichloromethane at 20℃; for 3.25h;
100%
With triethylamine In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;92%
With pyridine In dichloromethane at 20℃; for 3h;71%
With dmap; triethylamine In dichloromethane for 3h;
2-chloromethyl-3-chloroprop-1-ene
1871-57-4

2-chloromethyl-3-chloroprop-1-ene

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

C24H48O6

C24H48O6

Conditions
ConditionsYield
Stage #1: diethylene glycol monohexyl ether With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 0.333333h; Inert atmosphere;
Stage #2: 2-chloromethyl-3-chloroprop-1-ene In tetrahydrofuran; mineral oil at 65℃; for 5.5h; Inert atmosphere;
88%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1,2-Diiodobenzene
615-42-9

1,2-Diiodobenzene

1,2-bis-(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

1,2-bis-(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 72h; Inert atmosphere;85%
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 72h; Inert atmosphere;85%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1-[2-(2-chloroethoxy)ethoxy]hexane
72510-64-6

1-[2-(2-chloroethoxy)ethoxy]hexane

Conditions
ConditionsYield
With pyridine; thionyl chloride In toluene at -5 - 100℃; for 2h;84%
With pyridine; thionyl chloride
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1,3-Diiodobenzene
626-00-6

1,3-Diiodobenzene

1,3-bis(2-(2-hexylethoxy)ethoxy)benzene

1,3-bis(2-(2-hexylethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene for 20h; Reflux; Inert atmosphere;82%
iodobenzene
591-50-4

iodobenzene

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

(2-(2-(hexyloxy)ethoxy)ethoxy)benzene
928346-61-6

(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 120℃; for 24h; Inert atmosphere;77%
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 120℃; for 24h; Inert atmosphere;77%
1-bromo-hexane
111-25-1

1-bromo-hexane

diethylene glycol
111-46-6

diethylene glycol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With potassium hydroxide In 1,4-dioxane at 100 - 105℃;68%
With sodium hydride
oxirane
75-21-8

oxirane

2-hexyloxyethanol
112-25-4

2-hexyloxyethanol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With borontrifluoride acetic acid
oxirane
75-21-8

oxirane

hexan-1-ol
111-27-3

hexan-1-ol

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 50℃;
1-bromo-hexane
111-25-1

1-bromo-hexane

sodium diethylene glycolate

sodium diethylene glycolate

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Conditions
ConditionsYield
With diethylene glycol at 200℃;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-(2'-n-hexyloxyethoxy)ethyl p-toluenesulfonate
187748-60-3

2-(2'-n-hexyloxyethoxy)ethyl p-toluenesulfonate

Conditions
ConditionsYield
Stage #1: diethylene glycol monohexyl ether; p-toluenesulfonyl chloride With dmap In dichloromethane at 20℃; for 0.166667h;
Stage #2: With triethylamine In dichloromethane at 20℃; for 3.25h;
100%
With triethylamine In dichloromethane at 0 - 20℃; for 18h; Inert atmosphere;92%
With pyridine In dichloromethane at 20℃; for 3h;71%
With dmap; triethylamine In dichloromethane for 3h;
2-chloromethyl-3-chloroprop-1-ene
1871-57-4

2-chloromethyl-3-chloroprop-1-ene

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

C24H48O6

C24H48O6

Conditions
ConditionsYield
Stage #1: diethylene glycol monohexyl ether With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 0.333333h; Inert atmosphere;
Stage #2: 2-chloromethyl-3-chloroprop-1-ene In tetrahydrofuran; mineral oil at 65℃; for 5.5h; Inert atmosphere;
88%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1,2-Diiodobenzene
615-42-9

1,2-Diiodobenzene

1,2-bis-(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

1,2-bis-(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 72h; Inert atmosphere;85%
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 72h; Inert atmosphere;85%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1-[2-(2-chloroethoxy)ethoxy]hexane
72510-64-6

1-[2-(2-chloroethoxy)ethoxy]hexane

Conditions
ConditionsYield
With pyridine; thionyl chloride In toluene at -5 - 100℃; for 2h;84%
With pyridine; thionyl chloride
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1,3-Diiodobenzene
626-00-6

1,3-Diiodobenzene

1,3-bis(2-(2-hexylethoxy)ethoxy)benzene

1,3-bis(2-(2-hexylethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene for 20h; Reflux; Inert atmosphere;82%
iodobenzene
591-50-4

iodobenzene

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

(2-(2-(hexyloxy)ethoxy)ethoxy)benzene
928346-61-6

(2-(2-(hexyloxy)ethoxy)ethoxy)benzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 120℃; for 24h; Inert atmosphere;77%
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 120℃; for 24h; Inert atmosphere;77%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

hexafluoropropene-diethylamine adduct
309-88-6

hexafluoropropene-diethylamine adduct

A

N,N-diethyl 2,3,3,3-tetrafluoropropionamide

N,N-diethyl 2,3,3,3-tetrafluoropropionamide

B

1-[2-(2-Fluoro-ethoxy)-ethoxy]-hexane

1-[2-(2-Fluoro-ethoxy)-ethoxy]-hexane

C

2,3,3,3-Tetrafluoro-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester

2,3,3,3-Tetrafluoro-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester

Conditions
ConditionsYield
In dichloromethane for 3h; Ambient temperature;A n/a
B 70%
C 15%
In dichloromethane for 3h; Ambient temperature;A n/a
B 70%
C 15%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

2-methyl-2-octyldodecanoic acid

2-methyl-2-octyldodecanoic acid

C31H62O4

C31H62O4

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 18h; Dean-Stark; Reflux;70%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1-Iodonaphthalene
90-14-2

1-Iodonaphthalene

1-(2-(2-(hexyloxy)ethoxy)ethoxy)naphthalene

1-(2-(2-(hexyloxy)ethoxy)ethoxy)naphthalene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 24h; Inert atmosphere;67%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

(5,10,15,20-tetraphenylporphinato)dichlorophosphorus(V) chloride

(5,10,15,20-tetraphenylporphinato)dichlorophosphorus(V) chloride

di(3,6-dioxadodecyloxo)tetraphenylporphyrinatophosphorus(V) chloride

di(3,6-dioxadodecyloxo)tetraphenylporphyrinatophosphorus(V) chloride

Conditions
ConditionsYield
With pyridine In acetonitrile for 24h; Reflux;66%
With pyridine In acetonitrile for 24h; Reflux;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

4-tolyl iodide
624-31-7

4-tolyl iodide

1-(2-(2-(hexyloxy)ethoxy)ethoxy)-4-methylbenzene

1-(2-(2-(hexyloxy)ethoxy)ethoxy)-4-methylbenzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 24h; Inert atmosphere;63%
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

C13H21Cl2N3O3
928346-63-8

C13H21Cl2N3O3

Conditions
ConditionsYield
With potassium carbonate In ethyl acetate at 20 - 50℃; for 20h; Product distribution / selectivity;60%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

3,4-dimethyliodobenzene
31599-61-8

3,4-dimethyliodobenzene

4-(2-(2-(hexyloxy)ethoxy)ethoxy)-1,2-dimethylbenzene

4-(2-(2-(hexyloxy)ethoxy)ethoxy)-1,2-dimethylbenzene

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 24h; Inert atmosphere;60%
1,2,3,4-tetra-O-acetyl-D-xylopyranose
62446-93-9

1,2,3,4-tetra-O-acetyl-D-xylopyranose

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

triacetylhexyl bis(oxyethyl)-α-D-xyloside

triacetylhexyl bis(oxyethyl)-α-D-xyloside

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at 0℃; for 24h; Molecular sieve;54%
With tin(IV) chloride Helferich Method; stereoselective reaction;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

chloranil
118-75-2

chloranil

A

2,3,5-trichloro-[6-(2-(2-hexyloxy)ethoxy)ethoxy]cyclohexa-2,5-diene-1,4-dione

2,3,5-trichloro-[6-(2-(2-hexyloxy)ethoxy)ethoxy]cyclohexa-2,5-diene-1,4-dione

B

C26H42Cl2O8

C26H42Cl2O8

C

C26H42Cl2O8

C26H42Cl2O8

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃;A 38%
B 4%
C 17%
2,3-Dichloro-1,4-naphthoquinone
117-80-6

2,3-Dichloro-1,4-naphthoquinone

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

2-(2-(2-(hexyloxy)ethoxy)ethoxy)-3-chloro-1,4-naphthoquinone

2-(2-(2-(hexyloxy)ethoxy)ethoxy)-3-chloro-1,4-naphthoquinone

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 12h;25%
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

C64H86O43

C64H86O43

C72H104O44

C72H104O44

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at 45℃; for 5h; glycosidation;22%
oxirane
75-21-8

oxirane

diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

2-[2-(2-hexyloxy-ethoxy)-ethoxy]-ethanol
25961-89-1

2-[2-(2-hexyloxy-ethoxy)-ethoxy]-ethanol

Conditions
ConditionsYield
With borontrifluoride acetic acid
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Tetraethylene glycol monohexyl ether
39619-69-7

Tetraethylene glycol monohexyl ether

Conditions
ConditionsYield
With pyridine; p-toluenesulfonyl chloride Erhitzen des Reaktionsprodukts mit Natrium-diaethylenglykolat in Diaethylenglykol auf 130grad;
Multi-step reaction with 2 steps
1: pyridine; thionyl chloride
2: diethylene glycol
View Scheme
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

acrylonitrile
107-13-1

acrylonitrile

3-[2-(2-hexyloxy-ethoxy)-ethoxy]-propionitrile
102236-85-1

3-[2-(2-hexyloxy-ethoxy)-ethoxy]-propionitrile

Conditions
ConditionsYield
With potassium hydroxide
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

diclofop
40843-25-2

diclofop

2-[4-(2,4-Dichloro-phenoxy)-phenoxy]-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester
65634-01-7

2-[4-(2,4-Dichloro-phenoxy)-phenoxy]-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester

Conditions
ConditionsYield
(i) SOCl2, toluene, (ii) /BRN= 1743959/, Et3N; Multistep reaction;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

4-(4-chlorophenoxy)-α-phenoxy-propionic acid chloride

4-(4-chlorophenoxy)-α-phenoxy-propionic acid chloride

2-[4-(4-Chloro-phenoxy)-phenoxy]-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester
65634-00-6

2-[4-(4-Chloro-phenoxy)-phenoxy]-propionic acid 2-(2-hexyloxy-ethoxy)-ethyl ester

Conditions
ConditionsYield
With triethylamine In toluene
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

epichlorohydrin
106-89-8

epichlorohydrin

2-[2-(2-Hexyloxy-ethoxy)-ethoxymethyl]-oxirane
120439-33-0

2-[2-(2-Hexyloxy-ethoxy)-ethoxymethyl]-oxirane

Conditions
ConditionsYield
With sodium hydroxide at 70 - 90℃;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

β‐cyclodextrin
7585-39-9

β‐cyclodextrin

C42H70O35*C10H22O3

C42H70O35*C10H22O3

Conditions
ConditionsYield
In water at 80℃; for 24h;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

Methacryloyl chloride
920-46-7

Methacryloyl chloride

C14H26O4
183317-57-9

C14H26O4

Conditions
ConditionsYield
With triethylamine In benzene at 20℃;
diethylene glycol monohexyl ether
112-59-4

diethylene glycol monohexyl ether

1,3-bis<2-(n-hexyloxyethoxy)ethoxy>propane-2-ol

1,3-bis<2-(n-hexyloxyethoxy)ethoxy>propane-2-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 50percent aq. NaOH / 70 - 90 °C
2: 50percent aq. NaOH / 1 h / 70 - 80 °C
View Scheme

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