115130-39-7

Basic information

• Product Name: 1,3,5-tri-O-benzyl-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene
• Synonyms: 1,3,5-tri-O-benzyl-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene
• CAS NO: 115130-39-7
• Molecular Weight: 919.127
• Mol File: 115130-39-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3,5-tri-O-benzyl-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tri-O-benzyl-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene(115130-39-7)
• EPA Substance Registry System: 1,3,5-tri-O-benzyl-2-C-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)benzene(115130-39-7)

Safety Data

• Hazardous Substances Data: 115130-39-7(Hazardous Substances Data)

Upstream product

• 131531-76-5 p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside 
• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 28244-94-2 p-tolyl-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 80300-30-7 1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 59434-20-7 1,3,5-tri-O-benzylphloroglucinol 
• 604-69-3 β-D-glucose pentaacetate 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 100-39-0 benzyl bromide 
• 108-73-6 3,5-dihydroxyphenol 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 

Downstream Products

• 4773-96-0 mangiferin 

Relevant articles and documents

Total synthesis of mangiferin, homomangiferin, and neomangiferin

Total synthesis of mangiferin, homomangiferin, and neomangiferin, three C-glycosyl xanthone natural products with a wide spectrum of pharmacological effects, has been achieved starting from 2,3,4,6-tetra-O-benzyl-α/β-d-glucopyranose. The key steps involve a stereoselective Lewis acid promoted C-glycosylation of protected phloroglucinol with tetrabenzylglucopyranosyl acetate and a highly regioselective base-induced cyclization for the construction of the core xanthone skeleton.

C-GLUCOSYLARENES FROM O-α-D-GLUCOSYL-TRICHLOROACETIMIDATES. STRUCTURE OF BERGENIN DERIVATIVES

C-Glucosylation of oxysubstituted benzene derivatives with O-α-D-glucopyranosyl trichloroacetimidate gave mainly β-D-glucopyranosylarenes.The most efficient catalysts were diethyl ether*boron trifluoride, diethyl ether*zinc chloride and zinc chloride.The