12640-40-3Relevant articles and documents
Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route
Ghosh, Sushmita,Dasgupta, Subrata,Sen, Amarnath,Maiti, Himadri Sekhar
, p. 1349 - 1352 (2005)
The present research describes a simple low-temperature synthesis route of preparing bismuth ferrite nanopowders through soft chemical route using nitrates of Bismuth and Iron. Tartaric acid is used as a template material and nitric acid as an oxidizing agent. The synthesized powders are characterized by X-ray diffractometry, thermogravimetry and differential thermal analysis, infrared spectroscopy, and scanning electron microscopy. The particle size of the powder lies between 3 and 16 nm. In the process, phase pure bismuth ferrite can be obtained at a temperature as low as 400°C, in contrast to 550°C for coprecipitation route. On the other hand, we find that, like solid state reaction route, Pechini's autocombustion method of synthesis generates a lot of impurity phases along with bismuth ferrite.
Nonadditive linearity in the chemostimulating effect of activator oxides + dlient compositions on GaAs thermal oxidation
Penskoi,Pshestanchik,Kostryukov,Kuznetsova,Agapov,Mittova
, p. 186 - 191 (2008/10/09)
The chemostimulation efficiency of the activators Sb2O 3 and Bi2O3 in compositions with a diluent (Al2O3) is a linear function of activator percentage over a wide range of temperatures. This function is not, however, additive to the thicknesses achieved in the presence of individual components. The percentage of the activator elements in the resulting oxide layers coincides with that in the initial compositions in the linear region and differs from it in the nonadditivity region. Thermal analysis in combination with X-ray powder diffraction showed that Al2O3 alters the temperature range and character of the intrinsic transformations of activator oxides.