127657-97-0

Usage

Uses

Used in Fragrance and Flavor Industry:
BENZYLOXYACETALDEHYDE DIMETHYL ACETAL is employed as a fragrance and flavoring agent, adding pleasant scents and tastes to a variety of consumer products. Its use is particularly prevalent in perfumes, soaps, and cosmetics, where it enhances the sensory experience for consumers.
Used in Organic Synthesis:
In the realm of organic synthesis, BENZYLOXYACETALDEHYDE DIMETHYL ACETAL serves as a solvent, facilitating chemical reactions that lead to the creation of other compounds. Its properties make it a reliable component in the synthesis process.
Used in Chemical Production:
Furthermore, BENZYLOXYACETALDEHYDE DIMETHYL ACETAL is utilized as a starting material in the production of other chemicals. Its versatility and stability contribute to its value in the chemical industry, where it plays a role in the manufacturing of a range of end products.

InChI:InChI=1/C11H16O3/c1-12-11(13-2)9-14-8-10-6-4-3-5-7-10/h3-7,11H,8-9H2,1-2H3

Upstream product

• 60656-87-3 benzyloxyacetoaldehyde 
• 149-73-5 trimethyl orthoformate 
• 97-97-2 chloroacetaldehyde dimethyl acetal 
• 30934-97-5 2,2-dimethoxyethanol 
• 100-39-0 benzyl bromide 
• 67-56-1 methanol 
• 14593-43-2 benzyl allyl ether 

Downstream Products

• 154371-93-4 (1S,2S)-1,2-Bis-((R)-2-benzyloxymethyl-[1,3]dioxolan-4-yl)-ethane-1,2-diol 
• 133625-44-2 (1'RS)-1-(2'-Benzyloxy-1'-methoxyethyl)uracil 
• 1203891-08-0 2-benzyloxymethyl[1,3]dithiane 
• 471246-98-7 2-Benzyloxymethyl-[1,3]dioxolane-4-carboxylic acid methyl ester 
• 30934-97-5 2,2-dimethoxyethanol 
• 192581-99-0 (2S)-2-((benzyloxy)methyl)-1,3-dioxolan-4-yl acetate 
• 145985-68-8 (2S,4S)-2-((benzyloxy)methyl)-1,3-dioxolane-4-carboxylic acid 
• 145985-69-9 (2S,4S)-2-((benzyloxy)methyl)-1,3-dioxolane-4-carboxylic acid 
• 1334306-29-4 6-benzyloxymethyl-2-isopropoxycarbonyl-7,10-dimethoxy-2,3,6,11-tetrahydropyrazino[1,2-b]isoquinoline-4-one 
• 1334306-30-7 6-benzyloxymethyl-2-isopropoxycarbonyl-7,10-dimethoxy-1,2,3,6-tetrahydropyrazino[1,2-b]isoquinolin-4-one 
• 1124308-84-4 C₁₉H₂₇NO₃S₂ 
• 918972-68-6 C₁₃H₁₈O₂ 
• 406950-20-7 C₂₁H₂₂N₂O₃ 
• 127658-05-3 1-((2S,4S)-2-Benzyloxymethyl-[1,3]dioxolan-4-yl)-5-methyl-1H-pyrimidine-2,4-dione 

Relevant academic research and scientific papers

DIOXOLANE ANALOGUES OF URIDINE FOR THE TREATMENT OF CANCER

The invention provides compounds of formula (I), wherein: R1 is OR11, or NR5R5'; R2 is H or F; R5 is H, C1-C6alkyl, OH, C(=O)R6, O(C=O)R6 or O(C=O)OR6; R5′ is H or C1-C6alkyl; R6 is C1-C6alkyl or C3-C7cycloalkyl; R13 is H, phenyl, pyridyl, benzyl, indolyl or naphthyl wherein the phenyl, pyridyl, benzyl, indolyl and naphthyl is optionally substituted with 1, 2 or 3 R22; and the other variables are as defined in the claims, which are of use in the treatment of cancer, and related aspects.

1,2-H shift in copper-chlorocarbenoid intermediate during CuCl/bpy-promoted stereoselective dechlorination of 2,2,2-trichloroethyl alkyl ethers to (Z)-1-alkoxy-2-chloroethenes

(Chemical Equation Presented) Reaction of 2,2,2-trichloroethyl alkyl ethers with 2 molar equiv of CuCl/bpy in refluxing DCE yielded (Z)-1-alkoxy-2- chloroethenes stereoselectively as the major product via 1,2-H shift in copper-chlorocarbenoid intermediate. 2,2,2-Trichloroethyl carboxylates undergo a radical 1,2-acyloxy shift under similar conditions.

Chemical compounds

Compounds of the general structural formula (I), and use of the compounds and salts and solvates thereof, as therapeutic agents.

Process for preparing alkyl- or aryloxyacetaldehydes

A process for preparing alkyl- or aryloxyacetaldehydes of the formula where R can be an unsubstituted or mono- or polysubstituted alkyl, aryl, heteroaryl, alkaryl, alkylheteroaryl or aralkyl radical or an unsubstituted or mono- or polysubstituted heterocycle or alkyl heterocycle, which comprises reacting a compound of the formula R—OM??(II) where R is as defined above and M can be an alkali metal atom or an alkaline earth metal atom, with a compound of the formula where R1 and R2 independently of one another are a C1-C6-alkyl radical or together are a C2-C6-alkylene radical and X is a halogen atom, to form the corresponding dialkylacetal of the formula where R, R1 and R2 are as defined above, whereupon acetal cleavage is carried out to give the desired alkyl- or aryloxyacetaldehydes of the formula (I).

Remote Asymmetric Induction in Diastereoface Selective Addition Reactions of Optically Active α-Substituted-β-silyl (E)-Hexenoates with Achiral α-Alkoxy and β-Alkoxy Acetals

Optically active and diastereomerically pure (E)-crotylsilanes 1 function as effective chiral carbon nucleophiles in trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed asymmetric addition reactions of achiral, α-alkoxy and β-alkoxy acetals 2, res