86001-88-9Relevant academic research and scientific papers
Direct synthesis of α-acyl methylenetriphenylarsoranes from readily available arsonium salts
Deng, Gui-Sheng,Huang, Zhi-Zhen,Yu, Xiao-Chun,Huang, Xian
, p. 2487 - 2495 (2007/10/03)
α-Acyl arsoranes can be synthesized by the acylation of readily available salts in the presence of triethylamine in moderate to good yields.
THE EFFECTS OF DIFFERENT COPPER (AND SOME OTHER) CATALYSTS ON THE CONVERSION OF TRIPHENYL- AND TETRAPHENYL-DIAZOCYCLOPENTADIENES AND OF SOME PHENYLIODONIUM αα'-DICARBONYLYLIDES INTO ARSONIUM AND OTHER YLIDES
Hood, J. Nicholas C.,Lloyd, Douglas,MacDonald, William A.,Shepherd, T. Maurice
, p. 3355 - 3358 (2007/10/02)
Diazo-compounds or iodonium ylides may be converted into arsonium and other ylides when heated in solution with triphenylarsine or other suitable carbene (or carbenoid) acceptor, and with a suitable Cu derivative present.The effects of using different copper complexes and salts are described and discussed.Other metal derivatives were for the most part ineffetive as catalysts.
