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13033-84-6 Usage


D-Phenylalanine methyl ester hydrochloride is an organic compound that serves as an essential building block in the synthesis of various pharmaceuticals and chemical compounds. It is a white solid with unique chemical properties that make it suitable for a range of applications in different industries.


Used in Pharmaceutical Industry:
D-Phenylalanine methyl ester hydrochloride is used as a key intermediate in the synthesis of pharmaceuticals for various therapeutic applications. Its ability to form amidines through copper-catalyzed three-component coupling with sulfonyl azides and alkynes makes it a valuable compound in the development of new drugs.
Used in Organic Synthesis:
In the field of organic chemistry, D-Phenylalanine methyl ester hydrochloride is used as a versatile reagent for the preparation of a wide range of chemical compounds. Its unique chemical properties allow it to be employed in various synthetic pathways, contributing to the development of novel molecules with potential applications in various industries.
Used in Research and Development:
D-Phenylalanine methyl ester hydrochloride is also utilized in research and development laboratories for the exploration of new chemical reactions and the synthesis of innovative compounds. Its role in the preparation of amidines and other complex molecules makes it an essential tool for scientists working on the cutting edge of chemical research.

Check Digit Verification of cas no

The CAS Registry Mumber 13033-84-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,3 and 3 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 13033-84:
66 % 10 = 6
So 13033-84-6 is a valid CAS Registry Number.

13033-84-6 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Detail
  • TCI America

  • (P1725)  D-Phenylalanine Methyl Ester Hydrochloride  >98.0%(HPLC)(T)

  • 13033-84-6

  • 5g

  • 390.00CNY

  • Detail
  • TCI America

  • (P1725)  D-Phenylalanine Methyl Ester Hydrochloride  >98.0%(HPLC)(T)

  • 13033-84-6

  • 25g

  • 1,200.00CNY

  • Detail
  • Alfa Aesar

  • (H25920)  D-Phenylalanine methyl ester hydrochloride, 99%   

  • 13033-84-6

  • 5g

  • 417.0CNY

  • Detail
  • Alfa Aesar

  • (H25920)  D-Phenylalanine methyl ester hydrochloride, 99%   

  • 13033-84-6

  • 25g

  • 1264.0CNY

  • Detail
  • Aldrich

  • (525472)  D-Phenylalaninemethylesterhydrochloride  98%

  • 13033-84-6

  • 525472-5G

  • 590.85CNY

  • Detail
  • Aldrich

  • (525472)  D-Phenylalaninemethylesterhydrochloride  98%

  • 13033-84-6

  • 525472-10G

  • 1,084.59CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017


1.1 GHS Product identifier

Product name D-Phenylalanine methyl ester hydrochloride

1.2 Other means of identification

Product number -
Other names H-D-Phe-OMe·HCl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13033-84-6 SDS

13033-84-6Relevant articles and documents

Synthesis and antiviral activity of novel glycyrrhizic acid conjugates with D-amino acid esters

Fayrushina,Baltina,Baltina,Konovalova,Petrova,Eropkin, M. Yu.

, p. 456 - 462 (2017)

Glycyrrhizic acid (GA) conjugates with methyl and ethyl esters of D-amino acids (D-Trp, D-Phe, D-Tyr, D-Val, D-Leu) have been synthesized by the activated esters method using mixtures of N-hydroxybenzotriazole or N-hydroxysuccinimide with N,N′-dicyclohexylcarbodiimide. GA conjugate with D-Trp ethyl ester exhibited antiviral activity against influenza viruses A/H3N2, A/H1N1/pdm09, A/H5N1, B (SI > 10–29), and HRSV (SI > 25). GA conjugate with D-Trp methyl ester inhibited influenza virus A/H1N1/pdm09 (SI > 30).

Optical Resolution of Amino Acid Esters by N-Protected Aspartylphenylalanine Esters

Oyama, Kiyotaka,Itoh, Mikio,Nonaka, Yuji

, p. 1751 - 1754 (1992)

A new method was studied for optical resolution of racemic amino acids esters by using, as resolving agents, N-protected L-α-aspartyl-L-phenylalanine alkyl esters, typically, N-benzyloxycarbonyl-L-α-aspartyl-L-phenylalanine methyl ester, the precursor to the synthetic sweetener aspartame.Thus, when the dipeptide and racemic amino acid ester were mixed in solvents, precipitation took place by formation of salt preferentially with D-amino acid ester to effect the optical resolution.

Modular Fragment Synthesis and Bioinformatic Analysis Propose a Revised Vancoresmycin Stereoconfiguration

Adamek, Martina,Essig, Sebastian,Kurz, Michael,Menche, Dirk,Sch?nenbroicher, Max,Seul, Maximilian,Spindler, Stefanie,Wingen, Lukas M.,Ziemert, Nadine

supporting information, p. 1175 - 1180 (2021/01/13)

Elaborate fragments of the proposed stereostructure of the complex polyketide antibiotic vancoresmycin have been synthesized in a stereoselective fashion based on a modular and convergent approach. Significant nuclear magnetic resonance differences in one of these subunits compared with the natural product question the proposed stereoconfiguration. Consequently, an extensive bioinformatics analysis of the biosynthetic gene cluster was carried out, leading to a revised stereoconfigurational proposal for this highly potent antibiotic.

Mechanoresponsive, proteolytically stable and biocompatible supergelators from ultra short enantiomeric peptides with sustained drug release propensity

Basu, Anindya,Christman, Ryann M.,Duttkonar, Anita,Harjit, Jeena,Mehra, Radha Rani,Mishra, Anil K.,Tiwari, Amit K.

, p. 6346 - 6354 (2020/05/13)

Stimuli-responsive low molecular weight hydrogelators attract immense interest from diverse segments of biomedicine and biotechnology. Distinctly, herein we report newly synthesized enantiomeric ultrashort peptides of general formula Me-(CH2)8-CO-NH-CH(X)-COOH, where X = CH2Ph in hydrogelators I (l-Phe) and II (d-Phe) respectively, which display excellent self-assembling propensity in physiological buffer at room temperature. Interestingly these biomolecules were endowed with mechanoresponsiveness, injectability and high mechanical integrity as confirmed by rheological measurements. Importantly they revealed resistance towards proteolytic degradation. Indeed dose dependent cell viability studies using MTT assay in four different cell lines, namely PANC-1, S1, HCT-116 and MDAMB-231, further confirmed the biocompatibility of the hydrogelators in vitro. The structural aspect of β-sheets of the hydrogelators was concluded on the basis of temperature dependent NMR, IR, PXRD and computational studies. We developed a user friendly delivery system, hydrogel nanoparticles (HNPs), with our mechanoresponsive and biocompatible hydrogelators, as these particles exhibited promising influence due to their enhanced surface area. Also the HNPs revealed excellent drug release kinetics for the model drugs 5FU/doxorubicin under physiological conditions in a sustained manner depending on the physicochemical parameters of the drugs. Taking these results together we envision that our designed hydrogelators and the delivery vehicle generated therefrom might represent a promising tool for administration of significant drug concentrations at lesion sites for a prolonged period, thus providing a better strategy for quick pain relief, rapid recovery and reduced systemic side effects.

Rhodium-Catalyzed Enantioselective Synthesis of Oxazinones via an Asymmetric Ring Opening-Lactonization Cascade of Oxabicyclic Alkenes

Yen, Andy,Pham, Anh Hoang,Larin, Egor M.,Lautens, Mark

supporting information, p. 7549 - 7553 (2019/10/02)

The rhodium-catalyzed asymmetric ring opening reaction of oxabicyclic alkenes is shown to be an efficient method for synthesizing chiral heterocycles. We demonstrate that the pairwise combination of chiral catalyst with chiral amino-acid-derived pronucleophiles results in a stereodivergent synthesis of diastereomeric hydroxyesters. A favorable conformational preference induces the subsequent lactonization of one diastereomer leading to the highly enantioselective synthesis of oxazinones.

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