130694-58-5

Upstream product

• 6153-05-5 (Z)-3-methylpent-2-en-4-ynol 
• 60046-49-3 (6R)-levodione 
• 130583-95-8 (4R,6R)-4-[(tert-butyldimethylsilyl)oxy]-2,2,6-trimethylcyclohexan-1-one 
• 108-24-7 acetic anhydride 
• 49846-56-2 2-cis-5-(1'-hydroxy-2',2',6'-trimethyl-4'-oxocyclohexyl)-3-methylpent-2-en-4-yn-1-ol 
• 95307-31-6 2-cis-5-(4',4'-ethylenedioxy-1'-hydroxy-2',2',6'-trimethylcyclohexyl)-3-methylpent-2-en-4-yn-1-ol 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 95307-31-6 2-trans-5-(4',4'-ethylenedioxy-1'-hydroxy-2',2',6'-trimethylcyclohexyl)-3-methylpent-2-en-4-yn-1-ol 
• 130583-96-9 Acetic acid (Z)-5-[(4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-2,2,6-trimethyl-cyclohexyl]-3-methyl-pent-2-en-4-ynyl ester 
• 130584-04-2 (4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-1-((Z)-5-hydroxy-3-methyl-pent-3-en-1-ynyl)-2,2,6-trimethyl-cyclohexanol 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 
• 130646-72-9 (-)-1(Z)-(1S,4R,6R)-1-(5-acetoxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexan-1,4-diol 
• 130646-73-0 (-)-1(Z)-(1R,4R,6R)-1-(5-acetoxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexan-1,4-diol 

Downstream Products

• 11048-74-1 9-cis-9'-cis-3,3'-diacetoxy-7,8,7',8'-tetradehydro-β,β-carotene 
• 26666-93-3 (3RS, 3'RS)-manixanthin 
• 95343-66-1 C₄₀H₅₂O₂ 
• 21284-10-6 9-cis-7,8-didehydro-β,ε-caroten-3-ol 
• 70905-70-3 Acetic acid (1R,4S,5R)-4-((Z)-5-acetoxy-3-methyl-pent-3-en-1-ynyl)-4-hydroxy-3,3,5-trimethyl-cyclohexyl ester 
• 26533-78-8 9-cis-3-hydroxy-7,8-didehydro-12'-apo-β-caroten-12'-al 
• 95343-51-4 2-cis-1-acetoxy-5-(4'-acetoxy-2',2',6'-trimethylcyclohex-1'-enyl)-3-methylpent-2-en-4-yne 
• 95307-33-8 2-cis-5-(4'-hydroxy-2',2',6'-trimethylclohex-1'-enyl)-3-methylpent-2-en-4-yn-1-ol 
• 95343-52-5 2-cis-5-(4'-hydroxy-2',2',6'-trimethylclohex-1'-enyl)-3-methylpent-2-en-4-yn-1-yltriphenylphosphonium bromide 
• 95307-35-0 [(Z)-5-((1S,4R,6R)-1,4-Dihydroxy-2,2,6-trimethyl-cyclohexyl)-3-methyl-pent-2-en-4-ynyl]-triphenyl-phosphonium; bromide 
• 95343-56-9 Acetic acid (1R,4S,5R)-4-[(3Z,5E,7E,9E,11E,13E,15Z)-18-((1S,4R,6R)-4-acetoxy-1-hydroxy-2,2,6-trimethyl-cyclohexyl)-3,7,12,16-tetramethyl-octadeca-3,5,7,9,11,13,15-heptaene-1,17-diynyl]-4-hydroxy-3,3,5-trimethyl-cyclohexyl ester 
• 95343-59-2 Acetic acid (1R,4S,5R)-4-hydroxy-3,3,5-trimethyl-4-[(3Z,5E,7E,9E,11E,13E,15E,17E)-3,7,12,16-tetramethyl-18-(2,6,6-trimethyl-cyclohex-1-enyl)-octadeca-3,5,7,9,11,13,15,17-octaen-1-ynyl]-cyclohexyl ester 
• 95307-36-1 9-cis-3-acetoxy-7,8-didehydro-β,ε-carotene 
• 95343-55-8 9-cis-9'-cis-7,8,7',8'-tetradehydro-5,6,5',6'-tetrahydro-β,β-carotene-3,6,3',6'-tetraol 

Relevant academic research and scientific papers

Synthesis of optically active cyclohexanone analogs of the plant hormone abscisic acid

The abscisic acid analogs (-)-(4R,5R)-, (+)-(4S,5S)-, and (-)-(4S,5R)-4(1E,3Z)-4-(4-carboxy-3-methyl-1,3-butadienyl)-4-hydroxy-3,3,5-trimethylcyclohexanones (dihydroabscisic acids), and (-)-(4S,5R)-, (+)-(4R,5S)-, and (-)-(4R,5R)-4(Z)-4-hydroxy-4-(5-hydroxy-3-methylpent-3-en-1-ynyl)-3,3,5-trimethylcyclohexanones were synthesized from a common precursor, (-)-(6R)-2,2,6-trimethylcyclohexan-1,4-dione, which was readily prepared by the fermentation of oxoisophorone with bakers' yeast.

Carotenoids and Related Compounds. Part 38. Synthesis of (3RS,3'RS)-Alloxanthin and Other Acetylenes

The all-trans, 9-cis, and 9,9'-di-cis forms of (3RS,3'RS)-alloxanthin have been synthesized, also the 9-cis-isomer of (3RS,6'RS)-crocoxanthin.Perhydrogenation of alloxanthin gives a product with the same optical properties as perhydrozeaxanthin.These resu