131146-91-3

Basic information

• Product Name: (+/-)-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol
• CAS NO: 131146-91-3
• Molecular Weight: 490.596
• Mol File: 131146-91-3.mol

Chemical Properties

• CAS DataBase Reference: (+/-)-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol(131146-91-3)
• EPA Substance Registry System: (+/-)-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol(131146-91-3)

Safety Data

• Hazardous Substances Data: 131146-91-3(Hazardous Substances Data)

Upstream product

• 87-89-8 D-myo-inositol 
• 34361-60-9 1,2:4,5-dicyclohexylidene-myo-inositol 
• 129879-49-8 6-O-allyl-3-O-benzyl-1,2:4,5-di-O-cyclohexylidene-myo-inositol 
• 58706-24-4 (±)-3-O-benzyl-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 131146-87-7 (±)-4-O-allyl-1-O-benzyl-2,3;5,6-di-O-isopropylidene-myo-inositol 
• 131146-88-8 (±)-4-O-allyl-1-O-benzyl-2,3-O-isopropylidene-myo-inositol 
• 100-39-0 benzyl bromide 
• 136282-32-1 6-O-allyl-3-O-benzyl-1,2-O-cyclohexylidene-myo-inositol 
• 23393-20-6 (+/-)-3-O-benzyl-1,2:4,5-di-O,O-cyclohexylidene-myo-inositol 
• 131147-11-0 (±)-2,3-O-isopropylidene-1,5,6-tri-O-benzyl-4-O-allyl-myo-inositol 

Downstream Products

• 136282-33-2 4-O-allyl-1,5,6-tri-O-benzyl-3-O-tert-butyldimethylsilyl-myo-inositol 
• 1323371-30-7 6-O-allyl-3,4,5-tri-O-benzyl-1,2-O-{(+)-1,7,7-trimethyl[2,2,1]bicyclohepta-6-ylidene}-D-myo-inositol 
• 133076-45-6 O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->6)-2,3,4,5-tetra-O-benzyl-D-myo-inositol 
• 133076-44-5 (2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1-6)-1-O-4-methoxybenzyl-2,3,4,5-tetra-O-benzyl-D-myo-inositol 
• 380366-31-4 (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->6)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-D-myo-inositol 
• 154459-82-2 1-D-6-O-allyl-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 
• 154459-85-5 1L-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol 
• 154459-84-4 1L-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol 
• 154372-20-0 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol 
• 154459-81-1 (-)-6-O-allyl-3,4,5-tri-O-benzyl-myo-inositol 
• 131233-71-1 1D-4-O-allyl-1,5,6-tri-O-benzyl-myo-inositol 
• 129261-63-8 (+)-1D-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 
• 1323371-47-6 (3,4-di-O-benzyl-6-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-p-methoxybenzyl-2,3,4,5-tetra-O-benzyl-D-myo-inositol 
• 1323371-48-7 (3,4-di-O-benzyl-6-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->6)-1-O-p-methoxybenzyl-2,3,4,5-tetra-O-benzyl-L-myo-inositol 

Relevant articles and documents

Synthesis of racemic 3-methylphosphonate analogues of myo-inositol 3,4-bis- and 1,3,4-trisphosphate

The partially benzyl protected myo-inositol derivatives 11a and 11b, the C-4 and C-1,4 hydroxyl function(s) of which are protected with temporary trans-prop-1-enyl protecting group(s), were readily converted into the respective title compounds 18a and 18b by sequential methylphosphonylation, mild cleavage of the trans-prop-1-enyl group(s), phosphorylation and removal of all permanent benzyl protecting groups.

The synthesis and resolution of (+/-)-1,5,6-tri-O-benzyl-myo-inositol

Racemic 1,5,6-O-benzyl-myo-inositol was prepared by five routes and converted into 1,5,6-tri-O-benzyl-2,3-O-isopropylidene-myo-inositol, the camphanates of which were readily separated by chromatography.The absolute configurations of the chiral derivative