13122-34-4

Basic information

• Product Name: CHLOROBENZENE-4-D1
• Synonyms: CHLOROBENZENE-4-D1
• CAS NO: 13122-34-4
• Molecular Formula: C₆H₅Cl
• Molecular Weight: 113.56
• Mol File: 13122-34-4.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 131.7 °C at 760 mmHg
• Flash Point: 23.9 °C
• Appearance: /
• Density: 1.12 g/cm³
• CAS DataBase Reference: CHLOROBENZENE-4-D1(CAS DataBase Reference)
• NIST Chemistry Reference: CHLOROBENZENE-4-D1(13122-34-4)
• EPA Substance Registry System: CHLOROBENZENE-4-D1(13122-34-4)

Safety Data

• Hazardous Substances Data: 13122-34-4(Hazardous Substances Data)

Usage

Uses

Chlorobenzene-4-d1 (CAS# 13122-34-4) is a useful isotopically labeled research compound.

Upstream product

• 108-90-7 chlorobenzene 
• 1679-18-1 4-Chlorophenylboronic acid 
• 637-87-6 1-Chloro-4-iodobenzene 
• 56075-36-6 1-(4-chlorophenyl)-2-(methylsulfonyl)diazene 
• 811-98-3 d⁽⁴⁾-methanol 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 758-12-3 deuteroacetic acid 
• 2396-00-1 4-chlorophenyl radical 
• 106-39-8 bromochlorobenzene 

Downstream Products

• 6120-99-6 4,4'-dideuterio-biphenyl 
• 2005-08-5 4-chlorophenyl benzoate 
• 1003-66-3 phenol-d1 
• 65750-22-3 3-chloro-O-deuterio-phenol 
• 14915-23-2 p-Chlorophenol-OD 
• 116467-75-5 2-(2H)-4-chlorophenol 
• 74383-28-1 C₆H₄⁽²⁾HClO 
• 106-48-9 4-chloro-phenol 
• 108-43-0 3-monochlorophenol 
• 116467-74-4 C₆H₄⁽²⁾HClO 
• 876-27-7 4-chlorophenyl acetate 

Relevant articles and documents

Photoinduced catalyst-free deborylation-deuteration of arylboronic acids with D2O

Herein, novel photoinduced catalyst-free deborylation-deuteration of arylboronic acids with D2O is reported. The protocol was compatible with a variety of functionalities, including halogen, alkoxy, cyano, sulfonyl, trimethylsilyl, trifluoromethoxy, alkyl, hydroxyl, free acid, amide, and heteroaromatic rings. A wide range of deuterated products were obtained in good yields with a high level of deuteration. This method provides a green and practical pathway to synthesize deuterium labelled compounds under mild conditions.

Hydro/deutero deamination of arylazo sulfones under metal and (photo)catalyst-free conditions

Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d8 or in THF-d8/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents.