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13235-07-9

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13235-07-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 13235-07-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,2,3 and 5 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13235-07:
(7*1)+(6*3)+(5*2)+(4*3)+(3*5)+(2*0)+(1*7)=69
69 % 10 = 9
So 13235-07-9 is a valid CAS Registry Number.
InChI:InChI=1/C15H12O3/c1-17-9-3-5-11-13(7-9)14-8-10(18-2)4-6-12(14)15(11)16/h3-8H,1-2H3

13235-07-9Relevant articles and documents

Synthesis of fluorenones by using Pd(ii)/Mg-La mixed oxide catalyst

Kishore, Ramineni,Shanthi Priya, Samudrala,Sudhakar, Medak,Venu, Boosa,Venugopal, Akula,Yadav, Jagjit,Kantam, Mannepalli Lakshmi

, p. 3363 - 3367 (2015)

Palladium(ii)/magnesium-lanthanum mixed oxide (Pd(ii)/Mg-La mixed oxide) catalyst was used in the dehydrogenative cyclization of benzophenones to afford fluorenones. This protocol represents a direct and facile approach to accessing a variety of fluorenone derivatives by means of C-H activation under heterogeneous conditions. The catalyst was recovered by centrifugation and used for three consecutive cycles with nearly consistent activity and selectivity.

Expeditious Assembly of Fluorenones through Domino Reactions of Benzoyl Chlorides with Arylboronic Acids Catalyzed by ONO Pincer-like Palladium(II) Complexes

Vignesh, Arumugam,Kaminsky, Werner,Dharmaraj, Nallasamy

, p. 3207 - 3212 (2016)

A new set of palladium(II) complexes featuring ONO pincer-type ligands were synthesized and utilized as efficient homogeneous catalysts for the domino reactions of benzoyl chlorides with arylboronic acids to yield a library of fluorenones. The titled reaction proceeded smoothly in H2O/MeOH media at a low catalyst loading (0.1 mol %) under mild reaction conditions in an open flask, and the catalyst could be reused over six consecutive runs. To validate the currently developed methodology for industrial-level applications, a gram-scale synthesis was done. Advantageously, the present protocol does not require any external oxidant, additives, or phase-transfer agents.

Tailoring Valence Tautomerism by Using Redox Potentials: Studies on Ferrocene-Based Triarylmethylium Dyes with Electron-Poor Fluorenylium and Thioxanthylium Acceptors

Casper, Larissa A.,Linseis, Michael,Demeshko, Serhiy,Azarkh, Mykhailo,Drescher, Malte,Winter, Rainer F.

, p. 10854 - 10868 (2021)

Three new electrochromic ferrocenyl triarylmethylium dyes with fluorenylium (1 a+, 1 b+) or thioxanthylium (1 c+) residues were selected in order to keep the intrinsic differences of redox potentials for ferrocene oxidation and triarylmethylium reduction small and to trigger valence tautomerism (VT). UV/Vis/NIR and quantitative EPR spectroscopy identified paramagnetic diradical isomers 1 a.+–1 c.+ alongside diamagnetic forms 1 a+–1 c+, which renders these complexes magnetochemical switches. The diradical forms 1 a.+–1 c.+ as well as the one-electron-reduced triarylmethyl forms of the complexes were found to dimerize in solution. For radical 1 a., dimerization occurs on the timescale of cyclic voltammetry; this allowed us to determine the kinetics and equilibrium constant for this process by digital simulation. M??bauer spectroscopy indicated that 1 a+ and 1 b+ retain VT even in the solid state. UV/Vis/NIR spectro-electrochemistry revealed the poly-electrochromic behaviour of these complexes by establishing the distinctly different electronic absorption profiles of the corresponding oxidized and reduced forms.

Overhauser Dynamic Nuclear Polarization with Selectively Deuterated BDPA Radicals

Delage-Laurin, Léo,Golota, Natalie,Griffin, Robert G.,Mardini, Michael,Ouyang, Yifu,Palani, Ravi Shankar,Swager, Timothy M.,Tan, Kong Ooi

supporting information, p. 20281 - 20290 (2021/12/03)

The Overhauser effect (OE), commonly observed in NMR spectra of liquids and conducting solids, was recently discovered in insulating solids doped with the radical 1,3-bisdiphenylene-2-phenylallyl (BDPA). However, the mechanism of polarization transfer in OE-DNP in insulators is yet to be established, but hyperfine coupling of the radical to protons in BDPA has been proposed. In this paper we present a study that addresses the role of hyperfine couplings via the EPR and DNP measurements on some selectively deuterated BDPA radicals synthesized for this purpose. Newly developed synthetic routes enable selective deuteration at orthogonal positions or perdeuteration of the fluorene moieties with 2H incorporation of >93%. The fluorene moieties were subsequently used to synthesize two octadeuterated BDPA radicals, 1,3-[α,γ-d8]-BDPA and 1,3-[β,δ-d8]-BDPA, and a BDPA radical with perdeuterated fluorene moieties, 1,3-[α,β,γ,δ-d16]-BDPA. In contrast to the strong positive OE enhancement observed in degassed samples of fully protonated h21-BDPA (? ~+70), perdeuteration of the fluorenes results in a negative enhancement (? ~-13), while selective deuteration of α- and γ-positions (aiso ~5.4 MHz) in BDPA results in a weak negative OE enhancement (? ~-1). Furthermore, deuteration of β- and δ-positions (aiso ~1.2 MHz) results in a positive OE enhancement (? ~+36), albeit with a reduced magnitude relative to that observed in fully protonated BDPA. Our results clearly show the role of the hyperfine coupled α and γ1H spins in the BDPA radical in determining the dominance of the zero and double-quantum cross-relaxation pathways and the polarization-transfer mechanism to the bulk matrix.

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