132950-29-9

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 133604-03-2 ethyl (4S)-5-(((tert-butyldiphenyl)silyl)oxy)-4-methyl-2(E)-pentenoate 
• 100-39-0 benzyl bromide 
• 124887-13-4 (2S,3S,4R)-5-<(tert-butyl)diphenylsilyloxy>-2,4-dimethylpentane-1,3-diol 
• 127665-68-3 (4S)-5-(tert-butyldiphenylsilyloxy)-4-methyl-2-penten-1-ol 
• 102849-23-0 (+)-(2R,3S,4S)-1,3,5-trihydroxy-2,4-dimethylpentane 3,5-acetonide 
• 81470-77-1 (2S,3R,4R)-1-(benzyloxy)-3,5-(isopropylidenedioxy)-2,4-dimethylpentane 
• 81520-11-8 (2R,3S,4S)-5-(benzyloxy)-2,4-dimethylpentane-1,3-diol 
• 105365-07-9 methyl (2R,3S,4R)-3,5-(isopropylidenedioxy)-2,4-dimethylpentanoate 
• 89329-05-5 1-methyl hydrogen (3S,2R,4S)-3-hydroxy-2,4-dimethylglutarate 
• 105365-06-8 methyl 3,5-dihydoxy-2,4-dimethylpentanoate 
• 108393-30-2 (2R,3R,4R)-5-(benzyloxy)-2,4-dimethyl-1,3-pentanediol 
• 132950-30-2 (2S,4R)-1-(benzyloxy)-5-<(tert-butyl)diphenylsilyloxy>-2,4-dimethylpentan-3-one 

Downstream Products

• 132950-32-4 2,6-dimethylphenyl (2R,3R,4S,5S,6S)-3,5,7-trihydroxy-2,4,6-trimethylheptanoate 
• 132950-31-3 2,6-dimethylphenyl (2R,3R,4R,5S,6S)-3-hydroxy-5,7-(isopropylidenedioxy)-2,4,6-trimethylheptanoate 
• 124887-13-4 (2S,3S,4R)-5-<(tert-butyl)diphenylsilyloxy>-2,4-dimethylpentane-1,3-diol 
• 132950-35-7 2,6-dimethylphenyl (2R,3R,4S,5S,6S)-7-hydroxy-3,5-(isopropylidenedioxy)-2,4,6-trimethylheptanoate 
• 132950-36-8 2,6-dimethylphenyl (2R,3R,4S,5S,6S)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-7-oxoheptanoate 
• 124887-14-5 (2R,3S,4S)-1-<(tert-butyl)diphenylsilyloxy>-3,5-(isopropylidenedioxy)-2,4-dimethylpentane 
• 132950-37-9 bis(2,6-dimethylphenyl) (2S,3S,4R,5R,6S,7R,8R)-3,5,7-trihydroxy-2,4,6,8-tetramethyl-nonane-1,9-dioate 
• 132950-33-5 2,6-dimethylphenyl (2R,3R,4S,5S,6S)-7-<(tert-butyl)diphenylsilyloxy>-3,5-dihydroxy-2,4,6-trimethylheptanoate 
• 105365-13-7 bis(2,6-dimethylphenyl) (2S,3S,4S,5S,6S,7R,8R)-5,7-(isopropylidenedioxy)-2,4,6,8-tetramethyl-nonane-1,9-dioate 
• 132950-34-6 2,6-dimethylphenyl (2R,3R,4S,5S,6S)-7-<(tert-butyl)diphenylsilyloxy>-3,5-(isopropylidenedioxy)-2,4,6-trimethylheptanoate 
• 132950-29-9 (2S,3S,4R)-1-(benzyloxy)-5-<(tert-butyl)diphenylsilyloxy>-2,4-dimethylpentan-3-ol 
• 1369677-32-6 (2R,3R,4S)-5-(benzyloxy)-3-methoxy-2,4-dimethylpentan-1-ol 
• 176444-25-0 C₁₅H₂₂O₃ 
• 1369677-36-0 C₂₃H₂₈O₃ 

Relevant academic research and scientific papers

Formal synthesis of (+)-crocacin C

The formal synthesis of (+)-crocacin C is reported. The approach described takes advantage of a highly regioselective epoxide cuprate addition and a diastereoselective Overman rearrangement. The synthesis is practical and amenable to scale up.

Total synthesis of scytophycin C. 1. Stereoselective syntheses of the C(1)-C(18) segment and the C(19)-C(31) segment

[Equation presented] Stereoselective total synthesis of scytophycin C, a marine 22-membered macrolide displaying potent activity against a variety of human carcinoma cell lines, has been reported in which the polypropionate structure bearing contiguous as