133067-74-0

Basic information

• Product Name: phenyl nonafluorobutyl selenide
• Synonyms: phenyl nonafluorobutyl selenide
• CAS NO: 133067-74-0
• Molecular Weight: 375.095
• Mol File: 133067-74-0.mol

Chemical Properties

• CAS DataBase Reference: phenyl nonafluorobutyl selenide(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl nonafluorobutyl selenide(133067-74-0)
• EPA Substance Registry System: phenyl nonafluorobutyl selenide(133067-74-0)

Safety Data

• Hazardous Substances Data: 133067-74-0(Hazardous Substances Data)

Upstream product

• 592-41-6 1-hexene 
• 423-39-2 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane 
• 1666-13-3 diphenyl diselenide 
• 109-53-5 isobutyl vinyl ether 
• 111-66-0 oct-1-ene 
• 23974-72-3 sodium phenylselenide 
• 693-02-7 hex-1-yne 

Relevant articles and documents

Perfluoroalkylphosphines and arsines obtained by Pd-catalyzed cross-coupling reaction with organoheteroatom stannanes

Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of the groups 15 (P, As) and 16 (Se) with perfluoroalkyl iodides (RfI) was studied. Herein, a one-pot two-step reaction to form P-Rf, As-Rf/

Nucleophilic perfluoroalkylation of aldehydes, ketones, imines, disulfides, and diselenides

Using a procedure analogous to that developed for nucleophilic trifluoromethylation, the perfluoroalkyl anion reagents created by mixing C 2F5I and n-C4F9I with tetrakis(dimethylamino)ethylene (TDAE) were effective in their nucleophilic reactions with aldehydes, ketones, imines, disulfides, and diselenides. Irradiation proved beneficial in the aldehyde and ketone reactions.

A convenient access to perfluoroalkyl selenoethers selenyl chlorides

The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide chlorine, or sulfuryl chloride

Perfluoroalkyl-Chalcogenation of Alkynes

Perfluoroalkyl-telluration of alkynes has been performed by a (PhTe)2-NaBH4-RfX system at a low temperature (-40, -80, or -100 deg C) to give 2-(perfluoroalkyl)vinyl tellurides.Meanwhile, perfluoroalkyl-sulfenylation and perfluoroalkyl-selenation were les

PERFLUOROALKYL-SELENATION OF OLEFINS

Perfluoroalkyl-selenation of olefins has been performed by the reaction of diphenyl diselenide with sodium borohydride followed with perfluoroalkyl halides (RfX) and olefins where one electron transfer from phenylseleno anion to RfX occurs, generating per