13820-46-7 Usage
Uses
Used in Organic Synthesis:
Tetraammineplatinum(II) tetrachloro is employed as a catalyst in various organic synthesis processes. Its unique coordination chemistry allows it to facilitate complex reactions, enhancing the efficiency and selectivity of the synthesis.
Used in Cancer Treatment Research:
TETRAAMMINEPLATINUM(II) TETRACHLOROhas been extensively studied for its potential use in cancer treatment. Platinum compounds, including tetraammineplatinum(II) tetrachloro, are known for their cytotoxic effects on cancer cells, making them promising candidates for the development of anticancer drugs. However, their toxicity to healthy cells and potential side effects require further research and development to optimize their therapeutic potential.
Used in the Production of Platinum Compounds:
Tetraammineplatinum(II) tetrachloro serves as a precursor to other platinum compounds, which find applications in various industries, including automotive catalysts, electronics, and pharmaceuticals. Its ability to form stable complexes with a wide range of ligands makes it a versatile starting material for the synthesis of novel platinum-based compounds.
Used in Environmental Remediation:
Due to its water solubility and chemical reactivity, tetraammineplatinum(II) tetrachloro has potential applications in environmental remediation, particularly in the treatment of wastewater containing heavy metal ions. Its ability to form stable complexes with various metal ions can be exploited to remove contaminants from water systems.
Check Digit Verification of cas no
The CAS Registry Mumber 13820-46-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,2 and 0 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13820-46:
(7*1)+(6*3)+(5*8)+(4*2)+(3*0)+(2*4)+(1*6)=87
87 % 10 = 7
So 13820-46-7 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.4H2N.2Pt/h4*1H;4*1H2;;/q;;;;4*-1;2*+2/p-4/rCl4Pt.4H2N.Pt/c1-5(2,3)4;;;;;/h;4*1H2;/q-2;4*-1;+2
13820-46-7Relevant academic research and scientific papers
Unravelling the structure of Magnus' pink salt
Lucier, Bryan E. G.,Johnston, Karen E.,Xu, Wenqian,Hanson, Jonathan C.,Senanayake, Sanjaya D.,Yao, Siyu,Bourassa, Megan W.,Srebro, Monika,Autschbach, Jochen,Schurko, Robert W.
, p. 1333 - 1351 (2014/02/14)
A combination of multinuclear ultra-wideline solid-state NMR, powder X-ray diffraction (pXRD), X-ray absorption fine structure experiments, and first principles calculations of platinum magnetic shielding tensors has been employed to reveal the previously unknown crystal structure of Magnus' pink salt (MPS), [Pt(NH3)4][PtCl4], study the isomeric Magnus' green salt (MGS), [Pt(NH3)4][PtCl4], and examine their synthetic precursors K2PtCl4 and Pt(NH 3)4Cl2·H2O. A simple synthesis of MPS is detailed which produces relatively pure product in good yield. Broad 195Pt, 14N, and 35Cl SSNMR powder patterns have been acquired using the WURST-CPMG and BRAIN-CP/WURST-CPMG pulse sequences. Experimentally measured and theoretically calculated platinum magnetic shielding tensors are shown to be very sensitive to the types and arrangements of coordinating ligands as well as intermolecular Pt-Pt metallophilic interactions. High-resolution 195Pt NMR spectra of select regions of the broad 195Pt powder patterns, in conjunction with an array of 14N and 35Cl spectra, reveal clear structural differences between all compounds. Rietveld refinements of synchrotron pXRD patterns, guided by first principles geometry optimization calculations, yield the space group, unit cell parameters, and atomic positions of MPS. The crystal structure has P-1 symmetry and resides in a pseudotetragonal unit cell with a distance of >5.5 A between Pt sites in the square-planar Pt units. The long Pt-Pt distances and nonparallel orientation of Pt square planes prohibit metallophilic interactions within MPS. The combination of ultra-wideline NMR, pXRD, and computational methods offers much promise for future investigation and characterization of Pt-containing systems.
