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13820-46-7

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13820-46-7 Usage

General Description

Tetraammineplatinum(II) tetrachloro is a chemical compound that consists of a platinum atom coordinated with four ammonia molecules and four chloride ions. It is commonly used as a catalyst in organic synthesis and as a precursor to other platinum compounds. It is a solid with a yellow-green color and is highly water-soluble. TETRAAMMINEPLATINUM(II) TETRACHLORO- has been studied for its potential uses in cancer treatment, as platinum compounds are known for their cytotoxic effects on cancer cells. However, it is also toxic to healthy cells and has potential environmental hazards, so it must be handled with care.

Check Digit Verification of cas no

The CAS Registry Mumber 13820-46-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,2 and 0 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13820-46:
(7*1)+(6*3)+(5*8)+(4*2)+(3*0)+(2*4)+(1*6)=87
87 % 10 = 7
So 13820-46-7 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.4H2N.2Pt/h4*1H;4*1H2;;/q;;;;4*-1;2*+2/p-4/rCl4Pt.4H2N.Pt/c1-5(2,3)4;;;;;/h;4*1H2;/q-2;4*-1;+2

13820-46-7 Well-known Company Product Price

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  • Alfa Aesar

  • (39444)  Tetraammineplatinum(II) tetrachloroplatinate(II)   

  • 13820-46-7

  • 1g

  • 1592.0CNY

  • Detail

13820-46-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name TETRAAMMINEPLATINUM(II) TETRACHLORO-

1.2 Other means of identification

Product number -
Other names Platinum(2+),tetraammine-,(sp-4-1)-,(sp-4-1)-tetrachloroplatinate(2-) (1:1)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13820-46-7 SDS

13820-46-7Relevant articles and documents

Unravelling the structure of Magnus' pink salt

Lucier, Bryan E. G.,Johnston, Karen E.,Xu, Wenqian,Hanson, Jonathan C.,Senanayake, Sanjaya D.,Yao, Siyu,Bourassa, Megan W.,Srebro, Monika,Autschbach, Jochen,Schurko, Robert W.

, p. 1333 - 1351 (2014/02/14)

A combination of multinuclear ultra-wideline solid-state NMR, powder X-ray diffraction (pXRD), X-ray absorption fine structure experiments, and first principles calculations of platinum magnetic shielding tensors has been employed to reveal the previously unknown crystal structure of Magnus' pink salt (MPS), [Pt(NH3)4][PtCl4], study the isomeric Magnus' green salt (MGS), [Pt(NH3)4][PtCl4], and examine their synthetic precursors K2PtCl4 and Pt(NH 3)4Cl2·H2O. A simple synthesis of MPS is detailed which produces relatively pure product in good yield. Broad 195Pt, 14N, and 35Cl SSNMR powder patterns have been acquired using the WURST-CPMG and BRAIN-CP/WURST-CPMG pulse sequences. Experimentally measured and theoretically calculated platinum magnetic shielding tensors are shown to be very sensitive to the types and arrangements of coordinating ligands as well as intermolecular Pt-Pt metallophilic interactions. High-resolution 195Pt NMR spectra of select regions of the broad 195Pt powder patterns, in conjunction with an array of 14N and 35Cl spectra, reveal clear structural differences between all compounds. Rietveld refinements of synchrotron pXRD patterns, guided by first principles geometry optimization calculations, yield the space group, unit cell parameters, and atomic positions of MPS. The crystal structure has P-1 symmetry and resides in a pseudotetragonal unit cell with a distance of >5.5 A between Pt sites in the square-planar Pt units. The long Pt-Pt distances and nonparallel orientation of Pt square planes prohibit metallophilic interactions within MPS. The combination of ultra-wideline NMR, pXRD, and computational methods offers much promise for future investigation and characterization of Pt-containing systems.

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