3695-36-1

Basic information

• Product Name: 1-Ethylthio-2-methylbenzene
• Synonyms: 1-Ethylthio-2-methylbenzene;o-Cresyl ethyl sulfide;1-ethylsulfanyl-2-methylbenzene
• CAS NO: 3695-36-1
• Molecular Formula: C₉H₁₂S
• Molecular Weight: 152.2566
• Mol File: 3695-36-1.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 212.7°Cat760mmHg
• Flash Point: 81.4°C
• Appearance: /
• Density: 0.99g/cm³
• Vapor Pressure: 0.248mmHg at 25°C
• Refractive Index: 1.549
• CAS DataBase Reference: 1-Ethylthio-2-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Ethylthio-2-methylbenzene(3695-36-1)
• EPA Substance Registry System: 1-Ethylthio-2-methylbenzene(3695-36-1)

Safety Data

• Hazardous Substances Data: 3695-36-1(Hazardous Substances Data)

Usage

Physical state

Liquid organic compound

Uses

Flavor and fragrance additive in consumer products

Scent

Pleasant, sweet, and fruity

Natural sources

Found in onion and garlic, contributing to their characteristic aroma

Industrial application

Precursor in the production of other organic compounds

Role in chemistry

Acts as a reagent in chemical reactions

Safety concerns

Volatility and flammability

Storage and handling

Should be stored in a well-ventilated area and handled with care to prevent potential hazards

InChI:InChI=1/C9H12S/c1-3-10-9-7-5-4-6-8(9)2/h4-7H,3H2,1-2H3

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 20035-08-9 sodium ethanesulfinate 
• 93-89-0 benzoic acid ethyl ester 
• 4032-80-8 bis(2-methylphenyl)disulfide 
• 100-68-5 methyl-phenyl-thioether 
• 75-03-6 ethyl iodide 
• 4646-69-9 benzocyclopropene 
• 75-08-1 ethanethiol 
• 67-56-1 methanol 
• 14092-00-3 methyl o-tolyl sulfide 
• 74-88-4 methyl iodide 
• 74-96-4 ethyl bromide 
• 137-06-4 2-thiocresol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 74-85-1 ethene 
• 13963-35-4 2-(phenylthio)toluene 
• 91952-80-6 N-(4-Ethylmercapto-3-methyl-benzyl)-propylamin 
• 97556-11-1 <4-Aethylmercapto-3-methyl-benzyl>--sulfid 
• 92854-94-9 <4-Aethylmercapto-3-methyl-benzyl>--aether 
• 67272-96-2 3-Methyl-4-ethylmercapto-benzylchlorid 

Relevant articles and documents

Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

Copper-Catalyzed Three-Component Coupling Reaction of Aryl Iodides, a Disilathiane, and Alkyl Benzoates Leading to a One-Pot Synthesis of Alkyl Aryl Sulfides

A copper-catalyzed three-component coupling reaction of aryl iodides, hexamethyldisilathiane and alkyl benzoates leading to alkyl aryl sulfides has been demonstrated. A disilathiane acted as both a sulfur source and a promoter of the sulfidation, and the alkyl moiety of the alkyl benzoate was effectively introduced on one side of the sulfide. Moreover, we found that the protocol can be expanded to the preparation of ethyl phenyl selenide with diphenyl diselenide.

Studies in the Cycloproparene Series: Reactions with Radicals

The behaviour of 1H-cyclopropabenzene (1) and 1H-cyclopropanaphthalene (23) towards a variety of radicals results in opening of the three-membered ring to give ortho-substituted benzyl and 2-methylnaphthalene derivatives, e.g. (13) and (28), respectively.Ring expansion into the cycloheptatriene manifold by way of addition to the bridge bond and norcaradiene formation have not been observed.Analogous reactions with the methylidenecyclopropanaphthalenes (33) and (34) lead to much decomposition, and provide little evidence for the C 1 cycloproparenyl radicals (35) and (36).