141058-57-3

Upstream product

• 1694-31-1 tert-butyl acetoacetate 
• 94-36-0 dibenzoyl peroxide 
• 532-32-1 sodium benzoate 
• 36082-04-9 2-bromo-3-oxobutyric acid tert-butyl ester 
• 65-85-0 benzoic acid 

Downstream Products

• 151753-83-2 Benzoic acid 1-(2-bromomethyl-3,6-dimethoxy-benzyl)-1-tert-butoxycarbonyl-2-oxo-propyl ester 
• 1155881-14-3 tert-butyl 2-benzoyloxy-2-methallyl-3-oxobutanoate 
• 1155881-04-1 tert-butyl 2-benzoyloxy-2-benzyl-3-oxobutanoate 
• 1155881-09-6 C₂₃H₂₆O₆ 
• 1155881-08-5 C₂₃H₂₆O₅ 
• 1155881-10-9 C₁₈H₂₂O₅ 
• 1155881-15-4 C₁₈H₂₀O₅ 
• 1155881-07-4 C₂₂H₂₃BrO₅ 
• 1155881-06-3 C₂₂H₂₃FO₅ 
• 1155881-13-2 C₂₀H₂₆O₅ 
• 1241794-86-4 tert-butyl (R)-2-benzoyloxy-2E-crotyl-3-oxobutanoate 
• 1241794-89-7 tert-butyl (R)-2-benzoyloxy-2-methallyl-3-oxobutanoate 
• 1155881-04-1 tert-butyl (R)-2-benzoyloxy-2-benzyl-3-oxobutanoate 
• 1241794-84-2 tert-butyl (R)-2-benzoyloxy-2-(4-methoxylbenzyl)-3-oxobutanoate 

Relevant academic research and scientific papers

METHOD FOR PRODUCING ALPHA-ACYLOXYCARBONYL COMPOUND AND NOVEL ALPHA-ACYLOXYCARBONYL COMPOUND

A method for producing an α-acyloxycarbonyl compound of the present invention includes performing an intermolecular reaction between a carboxylic acid and a carbonyl compound selected from the group consisting of ketones, aldehydes, and esters, which have

In situ generated (Hypo)iodite catalysts for the direct α-oxyacylation of carbonyl compounds with carboxylic acids

It′s the iodine: The intra- and intermolecular title reaction is catalyzed by an in situ generated ammonium (hypo)iodite species. Either H 2O2 or tert-butyl hydroperoxide (TBHP) can be used as an environmentally benign oxidant and a wide range of substrates react to give the corresponding α-acyloxycarbonyl compounds in good to excellent yields.

Phase-transfer-catalyzed asymmetric alkylation of a-benzoyloxy-b-keto esters: Stereoselective construction of congested 2, 3-dihydroxycarboxylic acid esters

Highly enantioselective phase-transfer-catalyzed alkylation of tert-butyl 2-benzoyloxy-3-oxobutanoate was realized by the use of an N-spiro chiral quaternary ammonium salt, as a complementary approach to the asymmetric hydroxylation of α-alkyl-β-keto esters. The synthetic utility of the alkylated compounds is highlighted by the diastereoselective reduction and alkylation of the remaining ketone moiety to give various enantiomerically enriched congested 2, 3-dihydroxycarboxylic acid esters.

Synthesis of a 5-deoxypyranoanthracycline: An entry into novel analogs of idarubicin

This paper describes a convergent and regioselective synthesis of 5-deoxypyranoanthracycline 2 using pyranoquinone 12 which is a versatile intermediate for the synthesis of this new class of heteroanthracyclines.