14310-29-3

Basic information

• Product Name: 1-nitro-4-phenethyl-benzene
• Synonyms: 1-nitro-4-phenethyl-benzene;1-(4-Nitrophenyl)-2-phenylethane;4-Nitrobibenzyl
• CAS NO: 14310-29-3
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 0
• Mol File: 14310-29-3.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 347.4°Cat760mmHg
• Flash Point: 155°C
• Appearance: /
• Density: 1.166g/cm³
• Vapor Pressure: 0.000108mmHg at 25°C
• Refractive Index: 1.602
• CAS DataBase Reference: 1-nitro-4-phenethyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-nitro-4-phenethyl-benzene(14310-29-3)
• EPA Substance Registry System: 1-nitro-4-phenethyl-benzene(14310-29-3)

Safety Data

• Hazardous Substances Data: 14310-29-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO2/c16-15(17)14-10-8-13(9-11-14)7-6-12-4-2-1-3-5-12/h1-5,8-11H,6-7H2

Upstream product

• 34420-17-2 (2-phenylethyl)boronic acid 
• 586-78-7 para-nitrophenyl bromide 
• 1942-30-9 4-(phenylethynyl)nitrobenzene 
• 636-98-6 p-nitrobenzene iodide 
• 17376-04-4 2-phenethyl iodide 
• 165904-22-3 4,4,5,5-tetramethyl-2-phenethyl-1,3,2-dioxaborolane 
• 100-39-0 benzyl bromide 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 1694-20-8 4-nitrostilbene 
• 1311408-19-1 2-phenethyl-2,3-dihydro-1H-1,3,2-benzodiazaborole 
• 622-24-2 2-phenylethyl chloride 
• 791020-40-1 N-benzyl-N-4-nitrobenzylhydrazine 
• 100-14-1 4-nitrobenzyl chloride 
• 17763-80-3 para-nitrophenyl triflate 

Downstream Products

• 13024-49-2 4-aminodibenzyl 

Relevant articles and documents

Wilkinson's catalyst catalyzed selective hydrogenation of olefin in the presence of an aromatic nitro function: A remarkable solvent effect

Optimal conditions for chlorotris(triphenylphosphine)rhodium(I) (Wilkinson's catalyst) catalyzed selective saturation of a double bond in the presence of a nitro function are developed. Aryl iodide and benzyl ether are also tolerated under these hydrogenation conditions.

Copper(II)-catalyzed preparation of alkylindium compounds and applications in cross-coupling reactions both in aqueous media

An efficient water-based method for the synthesis of alkylindium compound in the presence of a catalytic amount of cheap and readily available CuSO4·5H2O (10 mol%) was developed. The thus-generated alkylindium compounds effectively underwent palladium-catalyzed cross-coupling reactions with a myriad of aryl halides in aqueous media, leading to the cross-coupled products in modest to high yields. The mildness of the formed alkyl organometallics allowed the tolerance to various important functional groups incorporated in both substrates of alkyl iodides and aryl halides.

Alkene hydroboration with pinacolborane catalysed by lithium diisobutyl-: Tert-butoxyaluminum hydride

Here we developed a highly efficient alkene hydroboration protocol, showing that various alkyl boronates can be smoothly obtained in good yields by reacting alkenes with pinacolborane (HBpin) in the presence of 5 mol% lithium diisobutyl-tert-butoxyaluminum hydride. The coordination of aluminate ions with lithium cations allowed for effective hydride transfer during hydroboration, and the obtained boronate ester was further used for C-C coupling, trifluoroboronate salt formation, and oxidation to alcohol.