144285-04-1

Basic information

• Product Name: (1R,2S)-2-(2-hydroxybenzylideneamino)-1-indanol
• CAS NO: 144285-04-1
• Molecular Weight: 253.301
• Mol File: 144285-04-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S)-2-(2-hydroxybenzylideneamino)-1-indanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-(2-hydroxybenzylideneamino)-1-indanol(144285-04-1)
• EPA Substance Registry System: (1R,2S)-2-(2-hydroxybenzylideneamino)-1-indanol(144285-04-1)

Safety Data

• Hazardous Substances Data: 144285-04-1(Hazardous Substances Data)

Upstream product

• 94077-46-0 cis-(1S,2R)-β-amino-1-indanol 
• 90-02-8 salicylaldehyde 
• 15028-10-1 indan-1,2-dione-2-oxime 
• 23337-80-6 (±)-cis-2-amino-1-indanol 
• 32151-02-3 (1S,2S)-trans-2-amino-1-indanol 
• 13575-72-9 2-amino-1-indanol 
• 13575-72-9 (1R,2R)-trans-2-amino-1-indanol 
• 142678-92-0 (1R,2S)-amino indanol 

Relevant articles and documents

COPPER(II) IN ORGANIC SYNTHESIS. X. THE IMPORTANCE OF STERIC HINDRANCE IN THE DESIGN OF CHIRAL TRIDENTATE LIGAND COPPER(II) CATALYSTS FOR ENANTIOSELECTIVE MICHAEL REACTIONS

Several copper(II) complexes with tridentate chiral ligands derived from 2-substituted 2-aminoethanols have been tested as catalysts for enantioselective Michael reactions.The degree of enantioselection increases with the increase of the steric hindrance of the substituents and the best result (65percent e.e.) was obtained with the benzyl-substituted catalyst.A comparison of these results with those obtained with complexes derived from 2-amino-1-indanols gives useful information about the requirements for the optimization of the catalyst design.