14545-72-3Relevant articles and documents
Matrix infrared spectroscopic studies of the photo-dissociation at 266 nm of C1NO2 and of C1ONO
Coanga,Schriver-Mazzuoli,Schriver,Dahoo
, p. 309 - 320 (2008/10/08)
Detailed infrared spectroscopic studies of the photo-dissociation at 266 nm of C1NO2 trapped in argon matrices with subsequent experiments conducted with a xenon lamp at λ > 360 nm are reported. Formation of cis and trans C1ONO in equilibrium with C1NO2 is observed after irradiation at 266 nm. λ > 360 nm the transformation of trans C1ONO into cis C1ONO occurs. On prolonged photolysis at 266 nm, C1ONO dissociates into C1ON and O(1D) atom and into C10 + NO as evidenced in reactive matrices (solid oxygen and nitrogen).
Reactions of chlorine fluorides and oxyfluorides with the nitrate anion and alkali-metal fluoride catalyzed decomposition of ClF5
Christe, Karl O.,Wilson, William W.,Wilson, Richard D.
, p. 675 - 677 (2008/10/08)
The binary chlorine fluorides ClF5, ClF3, and ClF, when used in an excess, all undergo facile fluorine-oxygen exchange reactions with the nitrate anion, forming FClO2, unstable FClO, and ClONO2, respectively, as the primary products. Whereas FClO3 does not react with LiNO3 at temperatures as high as 75°C, FClO2 readily reacts with either LiNO3 or N2O5 to give ClONO2 and O2 in high yield, probably via the formation of an unstable O2ClONO2 intermediate. With an excess of ClF, chlorine nitrate undergoes a slow reaction to give FNO2 and Cl2O as the primary products, followed by Cl2O reacting with ClF to give Cl2, ClF, and FClO2. The alkali-metal fluorides CsF, RbF, and KF catalyze the decomposition of ClF5 to ClF3 and F2, which can result in the generation of substantial F2 pressures at temperatures as low as 25°C.
