147542-38-9

Basic information

• Product Name: N-(2,4-dibromophenyl)benzamide
• Synonyms: N-(2,4-dibromophenyl)benzamide
• CAS NO: 147542-38-9
• Molecular Weight: 355.029
• Mol File: 147542-38-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N-(2,4-dibromophenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2,4-dibromophenyl)benzamide(147542-38-9)
• EPA Substance Registry System: N-(2,4-dibromophenyl)benzamide(147542-38-9)

Safety Data

• Hazardous Substances Data: 147542-38-9(Hazardous Substances Data)

Upstream product

• 93-98-1 N-phenyl benzoyl amide 
• 64-19-7 acetic acid 
• 18039-42-4 5-Phenyl-1H-tetrazole 
• 615-57-6 2,4-dibromo-aniline 
• 98-88-4 benzoyl chloride 
• 35021-82-0 N-(4-bromophenyl)benzohydroxamic acid 
• 10468-46-9 N-(4-bromophenyl)hydroxylamine 
• 586-78-7 para-nitrophenyl bromide 
• 857580-87-1 N-bromo-benzanilide 
• 7702-38-7 N-(4-bromophenyl)benzamide 

Downstream Products

• 91692-55-6 benzoic acid-(4-bromo-2,6-dinitro-anilide) 
• 537025-33-5 6-bromo-2-phenylbenzo[d]oxazole 
• 81090-49-5 N-benzyl-2,4-dibromoaniline 
• 7702-38-7 N-(4-bromophenyl)benzamide 
• 70787-27-8 N-(2-bromophenyl)benzamide 

Relevant articles and documents

Practical bromination of arylhydroxylamines with SOBr2 towards ortho-bromo-anilides

A facile approach for synthesizing ortho-bromoanilides from readily available aryhydroxylamines and thionyl bromide is demonstrated in this work. Mild reaction conditions and broad scope of substrates ranging from heterocyclic structures to pharmaceutics-potential motifs are used in the reactions of this paper. Efficient bromination of ortho C–H bonds of the aryhydroxylamines has been achieved. Ortho-bromoanilide products were obtained in good to excellent yields, and model scaled-up reactions of this synthetic approach are shown in this work.

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Alkylation of 2-bromoaniline with benzyl bromide under ostensibly basic N-alkylation conditions resulted in migration of bromine from the 2- to the 4-aryl position. Herein we report our studies to elucidate the mechanism of this rearrangement with the objective of suppressing this unexpected outcome. We find that careful choice of reagents is critical, and that this behavior may be extrapolated to alkylation reactions of electron-rich bromo- and iodoanilines in general.

ORGANIC COMPOUNDS AND ORGANIC ELECTRO LUMINESCENCE DEVICE COMPRISING THE SAME

The present invention relates to novel organic compounds and an organic electroluminescent device comprising the same. According to the present invention, the compounds are used in a material for the organic electroluminescent device, desirably a host mat