1503-92-0

Basic information

• Product Name: N-hydroxy-N-(4-methylphenyl)benzamide
• Synonyms: benzamide, N-hydroxy-N-(4-methylphenyl)-; N-Hydroxy-N-(4-methylphenyl)benzamide
• CAS NO: 1503-92-0
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.2585
• Mol File: 1503-92-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 399.284°C at 760 mmHg
• Flash Point: 195.28°C
• Density: 1.234g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.651
• CAS DataBase Reference: N-hydroxy-N-(4-methylphenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-hydroxy-N-(4-methylphenyl)benzamide(1503-92-0)
• EPA Substance Registry System: N-hydroxy-N-(4-methylphenyl)benzamide(1503-92-0)

Safety Data

• Hazardous Substances Data: 1503-92-0(Hazardous Substances Data)

Upstream product

• 623-11-0 1-methyl-4-nitrosobenzene 
• 100-52-7 benzaldehyde 
• 98-88-4 benzoyl chloride 
• 99-99-0 1-methyl-4-nitrobenzene 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 102469-55-6 N,O-dibenzoyl-N-p-tolyl-hydroxylamine 

Downstream Products

• 135308-30-4 N-(Cyclohex-1-enecarbonyloxy)-N-p-tolyl-benzamide 
• 112308-06-2 N,S-dibenzoyl-2-amino-5-methylthiophenol 
• 135308-29-1 N-(2-Phenylsulfanyl-acetoxy)-N-p-tolyl-benzamide 
• 582-78-5 N-(4-methylphenyl)benzamide 
• 112308-04-0 N-benzoyl-S-dimethylcarbamoyl-N-p-tolylthiohydroxylamine 
• 112308-03-9 N-benzoyl-S-dimethylcarbamoyl-2-amino-5-dimethylthiophenol 
• 4916-16-9 methyl N-(p-methylphenyl)aziridine-2-carboxylate 
• 623-10-9 N-(4-methylphenyl)hydroxylamine 
• 65-85-0 benzoic acid 
• 105517-62-2 OHB(C₆H₅)(OCNO(C₆H₅)(CH₃C₆H₄)) 
• 63339-04-8 diphenylbis(N-4-methylphenylbenzohydroxamato)tin(IV) 
• 86973-08-2 (C₆H₅)3SnON(CH₃C₆H₄)CO(C₆H₅) 
• 75503-59-2 [C₆H₅C(O)N(CH₃C₆H₄)OSnC₄H₉(O)]2 
• 702685-74-3 N-(2-fluoro-4-methylphenyl)benzamide 

Relevant articles and documents

Practical bromination of arylhydroxylamines with SOBr2 towards ortho-bromo-anilides

A facile approach for synthesizing ortho-bromoanilides from readily available aryhydroxylamines and thionyl bromide is demonstrated in this work. Mild reaction conditions and broad scope of substrates ranging from heterocyclic structures to pharmaceutics-potential motifs are used in the reactions of this paper. Efficient bromination of ortho C–H bonds of the aryhydroxylamines has been achieved. Ortho-bromoanilide products were obtained in good to excellent yields, and model scaled-up reactions of this synthetic approach are shown in this work.

N-heterocyclic-carbene-catalyzed one-pot synthesis of hydroxamic esters

The honey pot: The NHC-catalyzed reaction between nitrosobenzenes, aromatic/aliphatic aldehydes, and enals proceeded through an aza-benzoin-type reaction and an internal redox esterification to afford hydroxamic esters in good yields. Copyright

Facile Transfer-Reduction of Nitroarenes to N-Arylhydroksylamines with Hydrazine in the Presence of Raney Nickel

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