1515-88-4

Usage

Chemical Properties

Colorless liquid

InChI:InChI=1/C8H9BrO/c1-10-6-7-2-4-8(9)5-3-7/h2-5H,6H2,1H3

Upstream product

• 873-75-6 4-bromobenzenemethanol 
• 74-88-4 methyl iodide 
• 1455-13-6 deuteromethanol 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 67-56-1 methanol 
• 1122-91-4 4-bromo-benzaldehyde 
• 149-73-5 trimethyl orthoformate 
• 16881-77-9 (dimethoxy)methylsilane 
• 124-41-4 sodium methylate 
• 868-85-9 Dimethyl phosphite 

Downstream Products

• 1515-85-1 4-(methoxymethyl)benzonitrile 
• 117960-45-9 8-(4-Methoxymethyl-phenyl)-1,4-dioxa-spiro[4.5]decan-8-ol 
• 95601-80-2 6,6'-bis(4-(methoxymethyl)phenyl)-2,2'-bipyridine 
• 93825-16-2 4-(methoxymethyl)thiophenol 
• 135221-26-0 tetra(p-methoxymethyl)phenylphosphonium bromide 
• 538-86-3 benzyl methyl ether 
• 139-66-2 diphenyl sulfide 
• 94306-40-8 Phenyl-(4-phenylmercapto-benzyl)-sulfid 
• 3699-01-2 4-tolyl phenyl sulfide 
• 75954-35-7 phenyl p-bromobenzyl sulfide 
• 204505-24-8 3-{2-[1-Methoxy-meth-(Z)-ylidene]-cyclohexyl}-1-(4-methoxymethyl-phenyl)-propan-1-one 
• 75-19-4 cyclopropane 
• 95601-81-3 6,6'-bis(4-(bromomethyl)phenyl)-2,2'-bipyridine 
• 1044505-08-9 ethyl [(diphenylmethylidene)amino]{4-[(methyloxy)methyl]phenyl}acetate 

Relevant academic research and scientific papers

Recyclable, Strong, and Highly Malleable Thermosets Based on Boroxine Networks

Traditional thermoset materials have favorable material properties but are unable to reprocess and are difficult to recycle. Small molecule boroxines have been shown to undergo a reversible exchange reaction. Herein we employ boroxine as dynamic cross-lin

Metallocene supported catalyst and method for preparing polypropylene using the same

The present invention relates to a supported metallocene catalyst including a novel single metallocene compound having excellent polymerization activity, and a process for producing a polypropylene having excellent processability and broad molecular weigh

Auto-Tandem Catalysis with Frustrated Lewis Pairs for Reductive Etherification of Aldehydes and Ketones

Herein we report that a single frustrated Lewis pair (FLP) catalyst can promote the reductive etherification of aldehydes and ketones. The reaction does not require an exogenous acid catalyst, but the combined action of FLP on H2, R-OH or H2O generates the required Br?nsted acid in a reversible, “turn on” manner. The method is not only a complementary metal-free reductive etherification, but also a niche procedure for ethers that would be either synthetically inconvenient or even intractable to access by alternative synthetic protocols.

OXAZOLIDINONE HYDROXAMIC ACID COMPOUNDS FOR THE TREATMENT OF BACTERIAL INFECTIONS

This invention pertains generally to treating bacterial infections using organic compounds of Formula I. In certain aspects, the invention pertains to treating infections caused by Gram-negative bacteria. (I) wherein X, Y, R1, R2, R3, R4 and R5 and defined herein.

1,3-dicyclohexylimidazol-2-ylidene as a superior ligand for the nickel-catalyzed cross-couplings of aryl and benzyl methyl ethers with organoboron reagents

A new catalytic system has been developed involving the use of Ni(cod)2 in conjunction with 1,3-dicyclohexylimidazol-2-ylidene for the cross-coupling of aryl and benzyl methyl ethers with organoboron reagents. This method not only allows for the use of readily available methyl ethers as halide surrogates but also provides a functional group tolerant method for the late-stage derivatization of complex molecules.

2,2,2-Trichloroethyl aryldiazoacetates as robust reagents for the enantioselective C-H functionalization of methyl ethers

A new class of reagents is described for C-H functionalization by means of C-H insertion using donor/acceptor-substituted rhodium(II) carbene intermediates. The 2,2,2-trichloroethyl aryl and heteroaryl diazoacetates, together with the dirhodium triarylcyclopropane carboxylate catalyst Rh2(R-BPCP)4, enabled the enantioselective intermolecular C-H functionalization of a range of methyl ethers with high levels of site selectivity and enantioselectivity.

Eco-efficient preparation of a N-doped graphene equivalent and its application to metal free selective oxidation reaction

Here, we demonstrate that graphene oxide (GO) can be converted to N-doped reduced GO (rGO) that could become a substitute for N-doped graphene. Simultaneous doping and reduction can be accomplished for this purpose by simply mixing GO with hydrazine and then continuously sonicating the solution at 65 °C. A high level of reduction is realized, as evidenced by a carbon to oxygen ratio of 20.7 that compares with the highest value of 15.3 ever reported in solution (water + hydrazine) methods. Nitrogen doping is possible up to 6.3 wt% and the extent of doping can be increased with increasing sonication time. Notably, the simple tuning process of N-doping in GO greatly enhanced the efficiency of the carbocatalyst for various kinds of metal free oxidation reactions and hence is proposed as a suitable candidate for future industrial applications. This journal is the Partner Organisations 2014.

Reductive etherification of aldehydes photocatalyzed by dicarbonyl pentamethylcyclopentadienyl iron complexes

The reductive etherification of aldehydes can be performed by the reaction with dialkylmethylsilanes in the presence of new iron(II) piano-stool catalysts of general formula Cp*Fe(CO)2Ar (Cp * = η5-C5Me5; Ar = Ph, 4-C6H4OCH3, 4-C6H4CH 3, Fc). This transformation is promoted by UV light and affords a simple route for the preparation of unsymmetrical alkyl ethers.

GLYT1 TRANSPORTER INHIBITORS AND USES THEREOF IN TREATMENT OF NEUROLOGICAL AND NEUROPSYCHIATRIC DISORDERS

Compounds of Formula (I) or a salt thereof are provided: wherein R1, R2, R3, R4, R5, R6, R15, R7, R8 and m are as defined in the description. Uses of the co

Synthetic protocols and building blocks for molecular electronics

Simple and readily accessible aryl bromides are useful building blocks for thiol end-capped molecular wires. Thus, 4-bromophenyl tert-butyl sulfide and 1-bromo-4-(methoxymethyl)benzene serve as precursors for a variety of oligo(phenylenevinylene) and olig