1540-04-1

Basic information

• Product Name: Phosphorane, triethoxy[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]-
• CAS NO: 1540-04-1
• Molecular Formula: C9H15F6O3P
• Molecular Weight: 316.18
• Mol File: 1540-04-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphorane, triethoxy[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphorane, triethoxy[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]-(1540-04-1)
• EPA Substance Registry System: Phosphorane, triethoxy[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]-(1540-04-1)

Safety Data

• Hazardous Substances Data: 1540-04-1(Hazardous Substances Data)

Upstream product

• 1490-33-1 hexafluorothioacetone 
• 122-52-1 triethyl phosphite 
• 791-50-4 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane 
• 788-67-0 1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane 

Downstream Products

• 353-36-6 1-fluoroethane 
• 80982-75-8 diethyl ester of pentafluoroisopropenylphosphonic acid 
• 358-74-7 diethyl fluorophosphate 
• 557-99-3 acetyl fluoride 
• 141-78-6 ethyl acetate 
• 80982-76-9 diethyl ester of α-hydrohexafluoroisopropylphosphonic acid 
• 78-40-0 triethyl phosphate 
• 356-27-4 ethyl heptafluorobutyrate 
• 75-00-3 chloroethane 
• 36319-84-3 1,1-bis(trifluoromethyl)allene 
• 455-32-3 benzoyl fluoride 
• 74-85-1 ethene 
• 74-96-4 ethyl bromide 
• 60340-27-4 perfluoro-2-methyl-3-bromo-2-butene 

Relevant articles and documents

New reactions of fluoroepoxides. Cleavage by trialkyl phosphites

Mono-, di- and tri-substituted fluorine-containing α-oxides have been shown to enter into reactions with trialkyl phosphites which proceed through cleavage of the C-C and C-O bonds in the epoxide ring.The trialkoxyphosphorus ylides II, V, VII and VIII were obtained from the epoxides I, IV, VII and XVI.Triethoxyfluorocarbonylfluorophosphorane (IIIb) has been isolated and characterized.Further conversions of IIIb have been studied and the formation of trialkoxyphosphorus ylides XXIV containing a fluorine atom in the position α to the phosphorus atom has been noted.It has been shown that when propylene oxide reacts with triethyl phosphite, vinyl ethers are obtained through the intermediate formation of tetrafluoroethylidenetriethoxyphosphorane (XX).