1589-66-8

Basic information

• Product Name: BENZOIC ACID-CARBOXY-14C
• Synonyms: C6H5 14COOH;[CARBOXYL-14C]BENZOIC ACID;BENZOIC ACID-CARBOXY-14C;benzoic acid-carboxy-14C toluene*solution;BENZOIC ACID-CARBOXY-14C*ACETONE SOLUTIO N;BENZOIC ACID-CARBOXY-14C TOULENE*SOLUTIO N
• CAS NO: 1589-66-8
• Molecular Formula: C₇H₆O₂
• Molecular Weight: 124.14
• Mol File: 1589-66-8.mol
• Article Data: 6

Chemical Properties

• Appearance: /crystalline
• Storage Temp.: 2-8°C
• CAS DataBase Reference: BENZOIC ACID-CARBOXY-14C(CAS DataBase Reference)
• NIST Chemistry Reference: BENZOIC ACID-CARBOXY-14C(1589-66-8)
• EPA Substance Registry System: BENZOIC ACID-CARBOXY-14C(1589-66-8)

Safety Data

• Hazard Codes: Xn,R,F
• Statements: 22-36-42/43-20/21/22-11
• Safety Statements: 26-36-16
• RIDADR: UN 2910 7
• WGK Germany: 3
• Hazardous Substances Data: 1589-66-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 51-90-1 [14C]carbon dioxide 
• 108-86-1 bromobenzene 
• 100-59-4 phenylmagnesium chloride 
• 591-51-5 phenyllithium 

Downstream Products

• 10425-64-6 <7-(14)C>-benzoyl chloride 
• 451471-51-5 4-[1-methyl-2,4-dioxo-6-(3-phenylprop-1-yn-1-yl)-1,4-dihydro-2H-quinazolin-3-ylmethyl]benzoic acid 
• 1420878-93-8 4-[1-methyl-2,4-dioxo-6-(3-phenyl-[3-¹⁴C]prop-1-ynyl)-1,4-dihydro-2Hquinazolin-3-ylmethyl]benzoic acid 
• 1420878-92-7 [3-¹⁴C]1-triphenylsilyl-3-phenylpropyne 
• 15314-26-8 [1-¹⁴C]benzylbromide 
• 5821-66-9 acetophenone 
• 1403761-96-5 [1'-¹⁴C]-(R)-2-(2-amino-5-((S)-1-phenylethylthio)thiazolo[4,5-d]pyrimidin-7-ylamino)-4-methylpentan-1-ol 
• 1403761-95-4 [1-¹⁴C]-(1-bromoethyl)benzene 
• 1403761-94-3 [1-¹⁴C]-((R)-1-chloroethyl)benzene 
• 1403761-93-2 [1-¹⁴C]-(S)-1phenylethanol 
• 1313403-86-9 3-(methylsulfonamido)-2-phenyl[2-⁽¹⁴⁾C]quinoline-4-carboxylic acid 
• 1313403-80-3 [2-⁽¹⁴⁾C]N-(2-oxo-2-phenylethyl)methanesulfonamide 
• 1313403-83-6 [1-⁽¹⁴⁾C]2-amino-acetophenone 
• 1313403-85-8 [1-⁽¹⁴⁾C]2-nitro-acetophenone 

Relevant articles and documents

THE BIOSYNTHESIS OF THE ALKALOIDS OF STEPHANIA GLABRA (ROXB.) MIERS

Tracer experiments show that the tetrhydroprotoberberines stepholidine (14), corydalmine (15), capaurine (19) and corynoxidine (20) are stereospecifically biosynthesized from (S)-reticuline (22) whereas the bisbenzylisoquinoline alkaloids cycleanine (52),

A convenient method for [14C]Carbonylation reactions

A simple, efficient method for generation of 14CO from Ba14CO3 has been developed. Reduction of 14CO2 using LiBEt3H gave [14C]formate in good yield which was treated with conc. H2SO4 to effect dehydration to 14CO. Through direct attachment of a reaction vessel containing aryl substrate and Pd(0) catalyst, [14C]carbonylation reactions were performed without the use of a mercury transfer pump. [14C]Carbonylation reactions using 14CO generated in this manner have been shown to proceed in good yield with a variety of substrates.

Atorvastatin, an HMG-CoA reductase inhibitor and efficient lipid-regulating agent. Part I. Synthesis of ring-labeled [14C]atorvastatin

Pyrrole-ring labeled [14C]atorvastatin (Lipitor, CI-981), [R-(R(*),R(*))]-2(4-fluorophenyl)-β,γ-dihydroxy-5-(1-methylethyl)-3-phenyl -4-[(phenylamino)-carbonyl]-1H-[3-14C]pyrrole-1-heptanoic acid calcium salt (2:1), was synthesized i

Synthesis of 6-chloro 2(-ethylamino)-4-methyl-4-phenyl-[-4-14c]-4h,- 3,1-benzoxazine (etifoxine)

Carbonation of phenyl lithium with 14CO2, followed by reduction of [14CO2] benzoic acid, led to [α-14C] benzyl alcohol 3, the oxidation of which afforded the [α-14C] benzaldehyde 4. The lat

BIOSYNTHESIS OF (+)-, (-)- AND (+/-)-TETRAHYDROPALMATINES

Specific incorporation of didehydroreticuline and reticuline into (+/-)-, (+)-, and (-)-tetrahydropalmatines in Cocculus laurifolius and of (R)- and (S)-reticulines into (R)- and (S)-tetrahydropalmatines respectively has been demonstrated.Feeding of 3H,4'-methoxy-14C>reticuline suggested that reticuline was not converted in the plants into didehydroreticuline and racemisation of optically active forms of tetrahydropalmatine did not take place via dehydrotetrahydropalmatine.