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16096-31-4

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Product FOB Price Min.Order Supply Ability Supplier
1,6-Hexanediol diglycidyl ether Manufacturer/High quality/Best price/In stock
Cas No: 16096-31-4
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
1,6-Hexanediol diglycidyl ether
Cas No: 16096-31-4
USD $ 5.4-5.4 / Kilogram 1000 Kilogram 5000 Metric Ton/Day Anhui Xinyuan Technology Co.,Ltd Contact Supplier
CHemwill -- 1,6-Hexanediol diglycidyl ether
Cas No: 16096-31-4
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 5 Metric Ton/Day Chemwill Asia Co., Ltd. Contact Supplier
High quality 1,6-Hexanediol Diglycidyl Ether supplier in China
Cas No: 16096-31-4
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
High Quality Oled CAS 16096-31-4 1,6-Hexanediol diglycidyl ether
Cas No: 16096-31-4
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Factory Supply 1,6-Hexanediol Diglycidyl Ether
Cas No: 16096-31-4
No Data 1 1 Ality Chemical Corporation Contact Supplier
1,6-Hexanediol diglycidyl ether
Cas No: 16096-31-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
1,6-Hexanediol diglycidyl ether
Cas No: 16096-31-4
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
1,6-Hexanedioldi Glycidyl Ether
Cas No: 16096-31-4
No Data 20 Gram 300 Metric Ton/Month Hubei Jusheng Technology Co., Ltd., Contact Supplier
1,6-Hexanediol diglycidyl ether 16096-31-4
Cas No: 16096-31-4
No Data 1 Kilogram 10 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier

16096-31-4 Usage

Contact allergens

This chemical is a reactive diluent in epoxy resins.

Uses

Its primary use is as a reactive diluent in epoxy resin systems to reduce viscosity and to allow higher filler loading.

Production Methods

The compound results from condensation of hexanediol with epichlorohydrin followed by dehydrochlorination with caustic.
InChI:InChI=1/C6H10O3.C6H14O2/c1(5-3-8-5)7-2-6-4-9-6;7-5-3-1-2-4-6-8/h5-6H,1-4H2;7-8H,1-6H2

16096-31-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,6-Hexanediol Diglycidyl Ether

1.2 Other means of identification

Product number -
Other names 1,6-Hexanediol diglycidyl ether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16096-31-4 SDS

16096-31-4Synthetic route

1,6-hexanediol
629-11-8

1,6-hexanediol

epichlorohydrin
106-89-8

epichlorohydrin

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride; sodium hydroxide In water at 40℃; for 2h;68.2%
With tetrabutylammomium bromide; sodium hydroxide In water at 40℃; for 2h;
Etherification;
tin(IV) chloride Etherification;
1,6-bis(allyloxy)hexane
81866-56-0

1,6-bis(allyloxy)hexane

A

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

B

C12H22O3
1246463-46-6

C12H22O3

Conditions
ConditionsYield
With dihydrogen peroxide; benzonitrile; triethylamine In water at 60℃; for 25h; Conversion of starting material;A 29%
B 44%
1,6-hexanediol
629-11-8

1,6-hexanediol

epichlorohydrin
106-89-8

epichlorohydrin

A

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

B

6-hydroxy hexyl glycidyl ether

6-hydroxy hexyl glycidyl ether

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran for 5h; Heating;A 14 g
B 50 g
1,6-hexanediol
629-11-8

1,6-hexanediol

1,2-Epoxy-3-bromopropane
3132-64-7

1,2-Epoxy-3-bromopropane

A

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

B

6-hydroxy hexyl glycidyl ether

6-hydroxy hexyl glycidyl ether

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran for 7h; Heating;A 35 g
B 35 g
1-chloro-3-[6-(3-chloro-2-hydroxy-propoxy)-hexyloxy]-propan-2-ol
20387-39-7

1-chloro-3-[6-(3-chloro-2-hydroxy-propoxy)-hexyloxy]-propan-2-ol

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
With sodium hydride In hexane; toluene at 20℃; for 0.0833333h; Cyclization;228 mg
1,6-hexanediol
629-11-8

1,6-hexanediol

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: SnCl4 / toluene; heptane / 3 h / 90 °C
2: 228 mg / NaH / toluene; hexane / 0.08 h / 20 °C
View Scheme
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

2-oxo-1,3-dioxolane-4-carboxylic acid
871835-30-2

2-oxo-1,3-dioxolane-4-carboxylic acid

C20H30O14

C20H30O14

Conditions
ConditionsYield
With chromium(III) acetylacetonate; triethylamine In tetrahydrofuran at 80℃; for 16h;100%
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

(2-dimethylamino-1-(4-morpholinophenyl)-2-(4-carboxyphenylmethyl)butan-1-one)

(2-dimethylamino-1-(4-morpholinophenyl)-2-(4-carboxyphenylmethyl)butan-1-one)

C60H82N4O12

C60H82N4O12

Conditions
ConditionsYield
With tetrabutylammomium bromide In acetonitrile for 10h; Reflux;88%
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

3-{[6-(2,3-dihydroxypropoxy)hexyl]oxy}-1,2-propanediol

3-{[6-(2,3-dihydroxypropoxy)hexyl]oxy}-1,2-propanediol

Conditions
ConditionsYield
With water; trifluoroacetic acid Hydrolysis; ring cleavage;63%
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

n-Octylamine
111-86-4

n-Octylamine

di[(2-hydroxy-3-octylamino)propyloxy]hexamethylene
189192-11-8

di[(2-hydroxy-3-octylamino)propyloxy]hexamethylene

Conditions
ConditionsYield
In ethanol for 4h;105 g
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

acetic anhydride
108-24-7

acetic anhydride

acetic acid
64-19-7

acetic acid

acetic acid 2-acetoxy-1-[6-(2,3-diacetoxy-propoxy)-hexyloxymethyl]-ethyl ester

acetic acid 2-acetoxy-1-[6-(2,3-diacetoxy-propoxy)-hexyloxymethyl]-ethyl ester

Conditions
ConditionsYield
Acetoxylation; acetylation; ring cleavage;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

reduced [3H]glutathione
148102-19-6

reduced [3H]glutathione

A

oxidized glutathione

oxidized glutathione

B

(S)-2-Amino-4-[2-[3-(6-{3-[2-((S)-4-amino-4-carboxy-butyrylamino)-2-(carboxymethyl-carbamoyl)-ethylsulfanyl]-2-hydroxy-propoxy}-hexyloxy)-2-hydroxy-propylsulfanyl]-1-(carboxymethyl-carbamoyl)-ethylcarbamoyl]-butyric acid

(S)-2-Amino-4-[2-[3-(6-{3-[2-((S)-4-amino-4-carboxy-butyrylamino)-2-(carboxymethyl-carbamoyl)-ethylsulfanyl]-2-hydroxy-propoxy}-hexyloxy)-2-hydroxy-propylsulfanyl]-1-(carboxymethyl-carbamoyl)-ethylcarbamoyl]-butyric acid

Conditions
ConditionsYield
In phosphate buffer; dimethyl sulfoxide at 20℃; for 18h; pH=7.4; Enzyme kinetics; Kinetics; Further Variations:; Reaction partners; Condensation;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

2-methyl-2-morpholin-4-yl-1-(4-piperazinylphenyl)propan-1-one
886463-09-8

2-methyl-2-morpholin-4-yl-1-(4-piperazinylphenyl)propan-1-one

C48H76N6O8

C48H76N6O8

Conditions
ConditionsYield
1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 10h; Heating / reflux;
2-Benzoylbenzoic acid
85-52-9

2-Benzoylbenzoic acid

1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

C40H42O10

C40H42O10

Conditions
ConditionsYield
With triphenylphosphine at 110℃; for 8h;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

1,6-bis[(γ-butyrolactone-4-yl)methyloxy]hexane

1,6-bis[(γ-butyrolactone-4-yl)methyloxy]hexane

Conditions
ConditionsYield
Stage #1: 1,6-diglycidyloxy hexamethylene; malonic acid dimethyl ester With potassium tert-butylate In tert-butyl alcohol for 16h; Reflux;
Stage #2: With sodium hydroxide In tert-butyl alcohol at 70℃; for 5h;
64 g
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

1,6-hexanediol
629-11-8

1,6-hexanediol

Octamethyltrisiloxane
107-51-7

Octamethyltrisiloxane

acrylic acid
79-10-7

acrylic acid

C84H178O36Si6

C84H178O36Si6

Conditions
ConditionsYield
Stage #1: octamethyltrisiloxabe; acrylic acid With dihydrogen hexachloroplatinate at 80℃; for 48h;
Stage #2: 1,6-diglycidyloxy hexamethylene With tetrabutylammomium bromide; hydroquinone at 100℃; for 14h;
Stage #3: 1,6-hexanediol With sulfuric acid at 140℃; for 6h;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

2,2-bis(hydroxymethyl)propionic acid
4767-03-7

2,2-bis(hydroxymethyl)propionic acid

C22H42O12

C22H42O12

Conditions
ConditionsYield
With triphenylphosphine at 140℃; for 3h;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

carbon dioxide
124-38-9

carbon dioxide

C14H22O8

C14H22O8

Conditions
ConditionsYield
With [N,N'-bis(2-pyridinylmethyl)cyclohexane-1,2-diamine]iron(II) chloride; tetrabutylammomium bromide In neat (no solvent) at 100℃; under 22502.3 Torr; for 4h; Catalytic behavior; Time; Autoclave; Glovebox; Green chemistry;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

C12H18N2

C12H18N2

C37H64N2O8

C37H64N2O8

Conditions
ConditionsYield
at 75℃; for 3h;
1,6 hexanediol diglycidyl ether
16096-31-4

1,6 hexanediol diglycidyl ether

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

C18H28N3O4(1+)

C18H28N3O4(1+)

Conditions
ConditionsYield
Stage #1: 1,6-diglycidyloxy hexamethylene; 1,2-diamino-benzene at 65℃; for 1.5h; Inert atmosphere;
Stage #2: With sulfuric acid; sodium nitrite In water at -10℃; for 3.5h;
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