1613-81-6

Basic information

• Product Name: N-Acetyloxy-p-nitrobenzamide
• Synonyms: N-Acetyloxy-p-nitrobenzamide
• CAS NO: 1613-81-6
• Molecular Formula: C₉H₈N₂O₅
• Molecular Weight: 224.17
• Mol File: 1613-81-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• Density: 1.387g/cm³
• Refractive Index: 1.567
• CAS DataBase Reference: N-Acetyloxy-p-nitrobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Acetyloxy-p-nitrobenzamide(1613-81-6)
• EPA Substance Registry System: N-Acetyloxy-p-nitrobenzamide(1613-81-6)

Safety Data

• Hazardous Substances Data: 1613-81-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H8N2O5/c1-6(12)16-10-9(13)7-2-4-8(5-3-7)11(14)15/h2-5H,1H3,(H,10,13)

Upstream product

• 15119-62-7 1-acetylsulfanyl-4-nitro-benzene 
• 1613-76-9 4-nitrobenzohydroxamic acid 
• 108-24-7 acetic anhydride 
• 122-04-3 4-nitro-benzoyl chloride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 1129-37-9 4-nitrobenzaldehyde oxime 
• 3235-02-7 p-methylbenzaldehyde oxime 
• 75-36-5 acetyl chloride 
• 99-77-4 ethyl 4-nitrobenzoate 
• 619-50-1 4-nitrobenzoic acid methyl ester 
• 830-03-5 4-nitrophenol acetate 

Downstream Products

• 6917-08-4 N-(4-methylphenyl)-4-nitrobenzamide 
• 29264-57-1 N-Acetoxy-4-nitro-N-(4-nitro-benzoyl)-benzamide 

Relevant articles and documents

Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

A Rh(iii)-catalyzed oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters is achieved to afford benzolactams in up to 93% yields. With the N-OAc amido moiety as a directing group, the ortho-C-H is selectively functionalized and the catalytic reaction exhibits excellent tolerance to different functional substituents. A notable rhodacyclic complex is isolated and structurally characterized, suggesting that C-H/N-H cyclometallation is a key step in the catalytic cycle. This journal is the Partner Organisations 2014.

N-amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids

(Chemical Equation Presented) A general nonoxidative N-amidation of organostannanes and boronic acids has been developed. Under nonbasic conditions a wide variety of aryl, alkenyl, and heteroaryl organostannanes and boronic acids couple efficiently with O-acetyl hydroxamic acids in the presence of Cu(I) sources.