1613-81-6

Usage

InChI:InChI=1/C9H8N2O5/c1-6(12)16-10-9(13)7-2-4-8(5-3-7)11(14)15/h2-5H,1H3,(H,10,13)

Upstream product

• 122-04-3 4-nitro-benzoyl chloride 
• 1613-76-9 4-nitrobenzohydroxamic acid 
• 108-24-7 acetic anhydride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 1129-37-9 4-nitrobenzaldehyde oxime 
• 3235-02-7 p-methylbenzaldehyde oxime 
• 75-36-5 acetyl chloride 
• 99-77-4 ethyl 4-nitrobenzoate 
• 619-50-1 4-nitrobenzoic acid methyl ester 
• 830-03-5 4-nitrophenol acetate 
• 15119-62-7 1-acetylsulfanyl-4-nitro-benzene 

Downstream Products

• 29264-57-1 N-Acetoxy-4-nitro-N-(4-nitro-benzoyl)-benzamide 
• 6917-08-4 N-(4-methylphenyl)-4-nitrobenzamide 

Relevant academic research and scientific papers

Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

A Rh(iii)-catalyzed oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters is achieved to afford benzolactams in up to 93% yields. With the N-OAc amido moiety as a directing group, the ortho-C-H is selectively functionalized and the catalytic reaction exhibits excellent tolerance to different functional substituents. A notable rhodacyclic complex is isolated and structurally characterized, suggesting that C-H/N-H cyclometallation is a key step in the catalytic cycle. This journal is the Partner Organisations 2014.

Hypervalent iodine(III)-mediated oxidation of aldoximes to N-acetoxy or N-hydroxy amides

Treatment of various aliphatic and aromatic aldoximes with the hypervalent iodine(iii) reagents (diacetoxyiodo)benzene (DIB) or Koser's reagent [hydroxy(tosyloxy)iodo]benzene (HTIB) gave, respectively, N-acetoxy or N-hydroxy amides in good yields rather t

N-amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids

(Chemical Equation Presented) A general nonoxidative N-amidation of organostannanes and boronic acids has been developed. Under nonbasic conditions a wide variety of aryl, alkenyl, and heteroaryl organostannanes and boronic acids couple efficiently with O-acetyl hydroxamic acids in the presence of Cu(I) sources.