1641-61-8Relevant articles and documents
Reactions of dialkyl phosphonates with hexacarbonylmolybdenum(0) and hexacarbonyltungsten(0). Structure of intermediates in the catalytic phosphorylation of alkenes
Kuramshin,Nikolaev,Cherkasov
, p. 1744 - 1749 (2004)
Reactions of dialkyl phosphonates with catalytic precursors in the phosphorylation of alkenes and aryl halides, homoligand molybdenum(0) and tungsten(0) carbonyl complexes, were studied by quantum-chemical and spectroscopic (IR and NMR) methods. Schemes w
Addition of dialkyl hydrogen phosphites to alkenes in the presence of carbonyl complexes of chromium subgroup metals and iron
Kuramshin,Kuramshina,Cherkasov
, p. 354 - 358 (2001)
Depending on the reactant ratio and order of their mixing, reactions of dialkyl hydrogen phosphite with alkenes in the presence of catalytic amounts of homoligand carbonyl complexes of iron or chromium subgroup metals yield phosphonates by two pathways: r
Probing the reactivity of H-phosphonate derivatives for the hydrophosphonylation of various alkenes and alkynes under free-radical conditions
Geant, Pierre-Yves,Mohamed, Bemba Sidi,Périgaud, Christian,Peyrottes, Suzanne,Uttaro, Jean-Pierre,Mathé, Christophe
, p. 5318 - 5324 (2016/07/06)
Hydrophosphonylation is an efficient process to create carbon-phosphorus bonds from unsaturated C-C bonds and to give rise to alkylphosphonate or vinylphosphonate derivatives. In this work, we report on the reactivity of H-phosphonate derivatives for the hydrophosphonylation of various alkenes and alkynes under photoinduced free-radical conditions. The reaction was carried out on activated, unactivated and/or disubstituted alkenes or alkynes with 2,2-dimethoxy-2-phenylacetophenone as a photoinitiator under UV irradiation.